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1. 发明授权

US5320742A Gasoline upgrading process 失效
标题翻译：汽油升级过程
公开(公告)号：US5320742A
公开(公告)日：1994-06-14
申请号：US963229
申请日：1992-10-19
申请人： David L. Fletcher , Timothy L. Hilbert , David A. Pappal , David W. Rumsey , Gerald J. Teitman
发明人： David L. Fletcher , Timothy L. Hilbert , David A. Pappal , David W. Rumsey , Gerald J. Teitman
IPC分类号： C10G35/04 , C10G59/00 , C10G65/04 , C10G67/12 , C10G69/08 , C10G35/00 , C10G45/00
CPC分类号： C10G69/08 , C10G65/043 , C10G67/12
摘要： A sulfur-containing catalytically cracked naphtha is upgraded to form a low-sulfur gasoline product by a process which retains the octane contribution from the olefinic front end of the naphtha. Initially, the mercaptan sulfur in the front end of the cracked naphtha is converted to higher boiling disulfides by oxidation. The front end, which is then essentially an olefinic, high octane sulfur-free material, may be blended directly into the gasoline pool. The back end, which now contains the original higher boiling sulfur components such as thiophenes, together with the sulfur transferred from the front end as disulfides, is hydrotreated to produce a desulfurized product. This desulfurized product, which has undergone a loss in octane by saturation of olefins, is then treated in a second stage, by contact with a catalyst of acidic functionality, preferably a zeolite such as ZSM-5, under conditions which produce a product in the gasoline boiling range of higher octane value. Because this second product may contain combined organic sulfur, it may be subjected to a final desulfurization to reduce organic sulfur to acceptable levels.
摘要翻译：通过保留来自石脑油的烯烃前端的辛烷贡献的方法，将含硫催化裂化石脑油升级以形成低硫汽油产物。最初，裂化石脑油前端的硫醇硫通过氧化转化为较高沸点的二硫化物。然后，基本上为烯属，高辛烷值的无硫材料的前端可以直接混合到汽油池中。现在包含原来较高沸点的硫成分如噻吩的后端与从前端转移的硫作为二硫化物一起加氢处理以产生脱硫产物。然后在第二阶段通过与酸性官能团的催化剂（优选沸石如ZSM-5）接触，在产生烯烃的产物的条件下处理已经经历烯烃饱和的辛烷值损失的该脱硫产物汽油沸点范围较高的辛烷值。因为该第二产品可能含有组合的有机硫，所以可以对其进行最终脱硫以将有机硫降低至可接受的水平。

2. 发明授权

US5865988A Hydrocarbon upgrading process 失效
标题翻译：碳氢化合物升级过程
公开(公告)号：US5865988A
公开(公告)日：1999-02-02
申请号：US862238
申请日：1997-05-23
申请人： Nick A. Collins , Paul P. Durand , Timothy L. Hilbert , Gerald J. Teitman , Jeffrey C. Trewella
发明人： Nick A. Collins , Paul P. Durand , Timothy L. Hilbert , Gerald J. Teitman , Jeffrey C. Trewella
IPC分类号： C10G65/04 , C10G69/04 , C10G69/08
CPC分类号： C10G69/08 , C10G65/043 , C10G2400/02
摘要： Low sulfur gasoline is produced from an olefinic, cracked, sulfur-containing naphtha by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5 to crack low octane paraffins and olefins under relatively mild conditions, with limited aromatization of olefins and naphthenes. This is followed by hydrodesulfurization over a hydrotreating catalyst such as CoMo on alumina. The initial treatment over the acidic catalyst removes the olefins which would otherwise be saturated in the hydrodesulfurization, consuming hydrogen and lowering product octane, and converts them to compounds which make a positive contribution to octane. Overall liquid yield is high, typically at least 90 percent of higher. Product aromatics are typically increased by no more than 25 weight percent relative to the feed and may be lower than the feed.
摘要翻译：通过在酸性催化剂，优选中等孔径沸石如ZSM-5上处理，在相对温和的条件下裂化低辛烷值和烯烃，烯烃，裂化的含硫石脑油的烯烃，裂化的含硫石脑油的烯烃有限，和环烷烃。然后在加氢处理催化剂如氧化铝上的CoMo上进行加氢脱硫。在酸性催化剂上的初始处理除去在加氢脱硫中会饱和的烯烃，消耗氢气并降低产物辛烷值，并将它们转化成对辛烷有积极贡献的化合物。总体液体产量高，通常至少高达90％。产物芳族化合物通常相对于进料增加不超过25重量％，并且可以低于进料。

3. 发明授权

US06261441B1 Integrated hydroprocessing scheme with segregated recycle 有权
标题翻译：具有隔离回收的综合加氢处理方案
公开(公告)号：US06261441B1
公开(公告)日：2001-07-17
申请号：US09159913
申请日：1998-09-24
申请人： Arthur R. Gentry , Kenneth W. Goebel , Timothy L. Hilbert , Michael G. Hunter , David A. Pappal , Randall D. Partridge
发明人： Arthur R. Gentry , Kenneth W. Goebel , Timothy L. Hilbert , Michael G. Hunter , David A. Pappal , Randall D. Partridge
IPC分类号： C10G4700
CPC分类号： C10G65/12
摘要： This invention relates to the refining of petroleum products, and more particularly to an integrated hydroprocessing scheme involving a hydrocracking stage and subsequent dewaxing stage. Materials boiling in the middle distillate or lube oil range may be dewaxed. The bottoms streams (and optionally, other streams) of each stage are maintained separately from one another, during processing. Dewaxing may occur using either hydroisomerization catalysts or shape-selective catalysts or both in series. One embodiment employs a baffle in the flash zone of a fractionator to separate bottoms streams from each other. Alternatively, the effluent from the hydrocracking stage may be processed separately from the effluent from the dewaxing stage. The bottoms fraction from the dewaxing stage may be recycled back to the hydrocracking stage for further processing or used as lube base stock.
摘要翻译：本发明涉及石油产品的精炼，更具体地涉及涉及加氢裂化阶段和随后脱蜡阶段的综合加氢处理方案。在中间馏分或润滑油范围沸腾的物质可能被脱蜡。在处理期间，每个阶段的底部流（和任选地，其他流）彼此分开地保持。可以使用加氢异构化催化剂或形状选择性催化剂或两者串联进行脱蜡。一个实施例在分级器的闪蒸区域中采用挡板以将底部流彼此分离。或者，来自加氢裂化阶段的流出物可以与脱蜡阶段的流出物分开处理。来自脱蜡阶段的塔底馏分可循环回加氢裂化阶段进行进一步处理或用作润滑油基料。

4. 发明授权

US5399258A Hydrocarbon upgrading process 失效
标题翻译：碳氢化合物升级过程
公开(公告)号：US5399258A
公开(公告)日：1995-03-21
申请号：US988492
申请日：1992-12-10
申请人： David L. Fletcher , Michael S. Sarli , Stuart S. Shih , Stephen J. McGovern , Douglas S. Diez , Mohsen N. Harandi , Timothy L. Hilbert
发明人： David L. Fletcher , Michael S. Sarli , Stuart S. Shih , Stephen J. McGovern , Douglas S. Diez , Mohsen N. Harandi , Timothy L. Hilbert
IPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G45/00
CPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G2300/70
摘要： Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst under endothermic conditions in a second reaction zone. Heat is added to the endothermic reaction zone to initiate and maintain octane restoring reactions. The preferred acidic catalyst is an intermediate pore size zeolite such as ZSM-5. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. The addition of heat at the second zone prolongs hydrodesulfurization catalyst life by allowing a lower hydrodesulfurization reactor temperature. The addition of heat also maximizes octane increase in the second zone.
摘要翻译：相对高辛烷值的低硫汽油由催化裂化的含硫石脑油通过加氢脱硫然后在酸性催化剂上在吸热条件下在第二反应区中进行处理。将热量加入到吸热反应区中以引发和维持辛烷恢复反应。优选的酸性催化剂是中等孔径沸石，例如ZSM-5。在第二步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失，并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。通过允许较低的加氢脱硫反应器温度，在第二区域的加热延长了加氢脱硫催化剂寿命。加热也使第二区域的辛烷值增加最大化。

5. 发明授权

US5352354A Gasoline upgrading process 失效
标题翻译：汽油升级过程
公开(公告)号：US5352354A
公开(公告)日：1994-10-04
申请号：US891134
申请日：1992-06-01
申请人： David L. Fletcher , Timothy L. Hilbert , Stephen J. McGovern , Michael S. Sarli , Stuart S. Shih
发明人： David L. Fletcher , Timothy L. Hilbert , Stephen J. McGovern , Michael S. Sarli , Stuart S. Shih
IPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G69/02
CPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G2300/70
摘要： Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst defined by its x-ray diffraction pattern and preferably comprising the synthetic zeolite MCM-22. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.
摘要翻译：相对高辛烷值的低硫汽油由催化裂化的含硫石脑油通过加氢脱硫然后在由其X射线衍射图定义的酸性催化剂上处理，优选包含合成沸石MCM-22制备。在第二步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失，并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。在有利的情况下，使用延伸终点的原料如重质石脑油，高于约380°F（约193℃）为95％，可以获得相对于进料的产品辛烷值和产率的改善。

6. 发明授权

US5318690A Gasoline upgrading process 失效
标题翻译：汽油升级过程
公开(公告)号：US5318690A
公开(公告)日：1994-06-07
申请号：US1681
申请日：1993-01-07
申请人： David L. Fletcher , Timothy L. Hilbert , Stephen J. McGovern , John E. Sauer
发明人： David L. Fletcher , Timothy L. Hilbert , Stephen J. McGovern , John E. Sauer
IPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G35/00 , C10G45/00
CPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G2300/70
摘要： Low sulfur gasoline is produced from a catalytically cracked, sulfur-containing naphtha by fractionating the naphtha feed into a low boiling fraction in which the majority of the sulfur is present in the form of mercaptans and a high-boiling fraction in which the sulfur is predominantly in non-mercaptan form such as thiophenes. The low boiling fraction is desulfurized by a non-hydrogenatile mercaptan extraction process which retains the olefins present in this fraction. The second fraction is desulfurized by hydrodesulfurization, which results in some saturation of olefins and loss of octane. The octane loss is restored by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5, to form a low sulfur gasoline product with an octane number comparable to that of the feed naphtha but which contains some recombined sulfur in the form or mercaptans which are removed in a final hydrotreatment.
摘要翻译：通过将石脑油进料分馏成低沸点馏分，其中大部分硫以硫醇和高沸点馏分的形式存在，低硫汽油由催化裂解的含硫石脑油生产，其中硫主要是在非硫醇形式如噻吩中。低沸点馏分通过非挥发性硫醇萃取方法进行脱硫，该方法保留存在于该馏分中的烯烃。第二部分通过加氢脱硫脱硫，导致烯烃的一些饱和和辛烷值的损失。通过在酸性催化剂，优选中等孔径的沸石如ZSM-5上处理来恢复辛烷值损失，以形成辛烷值与供应石脑油相当的低硫汽油产物，但其中含有一些重组硫形式或硫醇，其在最终加氢处理中被除去。

7. 发明授权

US5413696A Gasoline upgrading process 失效
标题翻译：汽油升级过程
公开(公告)号：US5413696A
公开(公告)日：1995-05-09
申请号：US891124
申请日：1992-06-01
申请人： David L. Fletcher , Timothy L. Hilbert , Stephen J. McGovern , Michel S. Sarli , Stuart S. Shih
发明人： David L. Fletcher , Timothy L. Hilbert , Stephen J. McGovern , Michel S. Sarli , Stuart S. Shih
IPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G69/02
CPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G2300/70
摘要： Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst comprising zeolite beta. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.
摘要翻译：相对高辛烷值的低硫汽油通过加氢脱硫然后在包含β沸石的酸性催化剂上处理由催化裂解的含硫石脑油生产。在第二步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失，并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。在有利的情况下，使用延伸终点的原料如重质石脑油，高于约380°F（约193℃）为95％，可以获得相对于进料的产品辛烷值和产率的改善。

8. 发明授权

US5326463A Gasoline upgrading process 失效
标题翻译：汽油升级过程
公开(公告)号：US5326463A
公开(公告)日：1994-07-05
申请号：US967322
申请日：1992-10-28
申请人： David L. Fletcher , Timothy L. Hilbert , Michael S. Sarli , Stuart S. Shih
发明人： David L. Fletcher , Timothy L. Hilbert , Michael S. Sarli , Stuart S. Shih
IPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G45/00
CPC分类号： C10G35/095 , C10G53/16 , C10G67/00 , C10G67/16 , C10G69/08 , C10G2300/70
摘要： Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization and treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5 in an octane restoration step, followed by separation of a C.sub.9 -containing fraction, and recycling the C.sub.9 -containing fraction to the octane restoration step. A hydrocarbon fraction comprising C.sub.1 to C.sub.3 hydrocarbons may also be separated from the octane restored product and recycled for purposes of alkylating aromatic hydrocarbons and for this purpose, it may be advantageous to introduce a benzene-rich feed, such as a reformate, to the process. The treatment over the acidic catalyst in the octane restoration step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha.
摘要翻译：相对高辛烷值的低硫汽油通过加氢脱硫和在酸性催化剂，优选中等孔径的沸石如ZSM-5在辛烷值恢复步骤中进行加氢脱硫和处理，由催化裂解的含硫石脑油生产，然后分离含有C9的级分，并将含C9馏分再循环至辛烷还原步骤。包含C 1至C 3烃的烃馏分也可与正辛烷烃还原产物分离并再循环用于烷基化芳族烃的目的，为此，将富含苯的进料如重整产物引入该方法可能是有利的。在辛烷维持步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失，并导致辛烷值与进料石脑油相当的辛烷值的低硫汽油产物。

9. 发明授权

US5290427A Gasoline upgrading process 失效
标题翻译：汽油升级过程
公开(公告)号：US5290427A
公开(公告)日：1994-03-01
申请号：US925007
申请日：1992-08-05
申请人： David L. Fletcher , Timothy L. Hilbert , Michael S. Sarli , Stuart S. Shih
发明人： David L. Fletcher , Timothy L. Hilbert , Michael S. Sarli , Stuart S. Shih
IPC分类号： C10G69/08 , C10G45/00
CPC分类号： C10G69/08
摘要： Low sulfur gasoline is produced from a catalytically cracked, sulfur-containing naphtha by fractionating the naphtha feed into a number of fractions of differing boiling range and hydrodesulfurizing them by by feeding them into a hydrodesulfurization reactor at spaced locations along the length of the reactor in order of descending boiling range, with the highest boiling fraction first. Staged introduction of the feed into the hydrodesulfurization reactor in this way promotes desulfurization of the sulfur-rich, olefin poor back end of the feed while reducing the saturation of the high octane olefins in the olefin-rich, sulfur-poor front end, so preserving octane while achieving the desired desulfurization. The hydrodesulfurization is followed by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5. The treatment over the acidic catalyst in the second step restores octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha.
摘要翻译：通过将石脑油进料分馏成不同沸程的多个馏分并将其加氢脱硫，通过将其按照反应器长度的间隔位置依次送入加氢脱硫反应器中，由催化裂化的含硫石脑油生产低硫汽油沸点下降，沸点最高。以这种方式将进料分阶段引入加氢脱硫反应器促进了进料中富含硫的烯烃不良后端的脱硫，同时降低了烯烃富含硫贫的前端中的高辛烷值烯烃的饱和度，从而保持辛烷值，同时达到理想的脱硫效果。加氢脱硫之后，通过酸性催化剂，优选中等孔径的沸石如ZSM-5处理。在第二步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失，并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。

10. 发明授权

US09267084B2 Hydroprocessing of high nitrogen feed using bulk catalyst 有权
公开(公告)号：US09267084B2
公开(公告)日：2016-02-23
申请号：US14058803
申请日：2013-10-21
申请人： William J. Novak , Kathryn Y. Cole , Patrick L. Hanks , Timothy L. Hilbert
发明人： William J. Novak , Kathryn Y. Cole , Patrick L. Hanks , Timothy L. Hilbert
IPC分类号： C10G65/16 , B01J23/00 , B01J23/888 , C10G3/00 , C10G65/04 , C10G65/08
CPC分类号： C10G65/16 , B01J23/002 , B01J23/8885 , B01J37/031 , C10G3/46 , C10G3/48 , C10G3/50 , C10G65/04 , C10G65/08 , C10G2300/1014 , C10G2300/1018 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/202 , C10G2300/301 , C10G2300/308 , C10G2300/4018 , C10G2400/04 , Y02P30/20
摘要： Methods are provided for hydrotreating high nitrogen feeds with improved results for nitrogen removal, aromatic saturation, and/or sulfur removal. The method includes hydrotreating the feed with a supported hydrotreating catalyst followed by a bulk metal catalyst, the hydrotreated effluent of which can be suitable for use as a feed to an FCC reactor.

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