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1. 发明授权

US07714055B2 Tire with component comprised of a blend of polybutadiene rubber and composite of styrene/butadiene elastomer which contains exfoliated clay platelets 失效
标题翻译：轮胎与由聚丁二烯橡胶和苯乙烯/丁二烯弹性体的混合物组成的组合物，其中含有剥离的粘土片晶
公开(公告)号：US07714055B2
公开(公告)日：2010-05-11
申请号：US10923911
申请日：2004-08-23
申请人： David John Zanzig , Xiaoping Yang , Martin Paul Cohen
发明人： David John Zanzig , Xiaoping Yang , Martin Paul Cohen
IPC分类号： B60C1/00 , C08K3/34 , C08K3/04
CPC分类号： C08K3/346 , B60C1/0016 , C08K3/013 , C08K5/548 , C08K9/04 , C08L9/00 , C08L9/06 , Y10S152/905 , C08L2666/08 , C08L21/00
摘要： Pneumatic rubber tire having at least one component of a polybutadiene-rich rubber composition comprised of a blend of a continuous phase of a specialized cis 1,4-polybutadiene rubber and a dispersed phase comprised of a composite of styrene/butadiene elastomer which contains a dispersion of at least partially exfoliated, intercalated, clay platelets, wherein said cis 1,4-polybutadiene rubber and styrene/butadiene elastomer have spatially defined glass transition temperatures, wherein said blend contains amorphous silica and carbon black reinforcement. Such tire component may be, for example, a circumferential tread having a running surface intended to be ground-contacting or a sidewall insert.
摘要翻译：气动橡胶轮胎具有至少一种含聚丁二烯的橡胶组合物的组分，其由特殊的顺式1,4-聚丁二烯橡胶的连续相的共混物和由含有分散体的苯乙烯/丁二烯弹性体的复合物组成的分散相组成的至少部分剥离的，插入的粘土片晶，其中所述顺式1,4-聚丁二烯橡胶和苯乙烯/丁二烯弹性体具有空间限定的玻璃化转变温度，其中所述共混物包含无定形二氧化硅和炭黑增强物。这种轮胎部件可以是例如具有旨在被接地的行进面或侧壁插入物的周向胎面。

2. 发明授权

US07214731B2 Tire with low hydrocarbon emission rubber combination of tread and sidewall components with compositional limitations 有权
标题翻译：轮胎与低碳氢化合物橡胶组合的胎面和侧壁组件具有组成限制
公开(公告)号：US07214731B2
公开(公告)日：2007-05-08
申请号：US10778502
申请日：2004-02-13
申请人： David John Zanzig , Martin Paul Cohen , Paul Harry Sandstrom
发明人： David John Zanzig , Martin Paul Cohen , Paul Harry Sandstrom
IPC分类号： B60C1/00
CPC分类号： C08L23/283 , B60C1/0016 , B60C1/0025 , C08K3/013 , C08K9/06 , C08L9/00 , C08L21/00 , C08L23/16 , Y10T152/10 , C08L2666/06 , C08L2666/08
摘要： The invention relates to a tire of a structural combination of tire tread and sidewall components with compositional limitations containing minimal, if any, of in situ formed alcohol and methyl isobutyl ketone byproducts. The tread component rubber composition contains pre-hydrophobated silica reinforcement. The sidewall component contains low unsaturation EPDM or brominated copolymer of isobutylene and p-methylstyrene and may contain pre-hydrophobated silica reinforcement. The silica reinforcement for said tread and sidewall components is a pre-hydrophobated precipitated silica. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or a combination of an alkoxyorganomercaptosilane and a substituted alkylsilane or with a bis-3(trialkoxysilylalkyl) polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof. The alcohol byproduct therefrom is removed from the composite prior to its introduction into the rubber composition(s). In another aspect of the invention, the connecting sidewall rubber composition, and optionally the tread composition is free of N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine antidegradant (referred herein to as 6PPD) in order to prevent in situ formation of methyl isobutyl ketone byproduct from the reaction of 6PPD with atmospheric oxygen and/or ozone.
摘要翻译：本发明涉及轮胎胎面和侧壁部件的结构组合的轮胎，其组成限制包含原位形成的醇和甲基异丁基酮副产物的最小（如果有的话）。胎面部件橡胶组合物含有预疏水化的二氧化硅增强物。侧壁组分含有低不饱和度的EPDM或异丁烯和对甲基苯乙烯的溴化共聚物，并且可以含有预疏水化的二氧化硅增强物。用于所述胎面和侧壁组分的二氧化硅增强剂是预疏水化沉淀二氧化硅。将预疏水化的二氧化硅在与弹性体混合之前通过将沉淀二氧化硅的表面上所含的羟基（例如硅烷醇基）与烷氧基有机硅烷或烷氧基有机硅氧烷和取代的烷基硅烷的组合或与在其多硫桥中含有平均2至4个连接硫原子的双-3（三烷氧基甲硅烷基烷基）多硫化物以形成其复合物。在其引入橡胶组合物之前，将其醇副产物从复合材料中除去。在本发明的另一方面，连接侧壁橡胶组合物和任选的胎面组合物不含N-（1,3-二甲基丁基）-N'-苯基对苯二胺抗降解剂（以下称为6PPD），以便防止6PPD与大气氧和/或臭氧的反应原位形成甲基异丁基酮副产物。

3. 发明授权

US08277898B2 Camouflage tire 失效
标题翻译：迷彩轮胎
公开(公告)号：US08277898B2
公开(公告)日：2012-10-02
申请号：US11820684
申请日：2007-06-20
申请人： David John Zanzig , David Andrew Benko , James Joseph Nespo , Terry John Waibel , Michael Julian Crawford , Timothy Michael Rooney , Bina Patel Botts , George Frank Balogh
发明人： David John Zanzig , David Andrew Benko , James Joseph Nespo , Terry John Waibel , Michael Julian Crawford , Timothy Michael Rooney , Bina Patel Botts , George Frank Balogh
IPC分类号： B60C13/00
CPC分类号： B44F1/10 , B44F9/00 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C11/00 , B60C13/001 , B60C13/002 , B60C13/04 , F41H3/00 , Y10T152/10 , Y10T152/10495
摘要： The present invention is directed to a camouflage tire suitable for use in various vehicle use environments wherein it is desirable to reduce or eliminate a viewer's visual perception of the tire against the given environmental background.
摘要翻译：本发明涉及一种适用于各种车辆使用环境的伪装轮胎，其中期望根据给定的环境背景减少或消除观察者对轮胎的视觉感知。

4. 发明申请

US20100186859A1 TIRE WITH TREAD OF SPATIALLY DEFINED ELASTOMER COMPOSITION 审中-公开
标题翻译：轮胎与空间定义的弹性体组成
公开(公告)号：US20100186859A1
公开(公告)日：2010-07-29
申请号：US12639411
申请日：2009-12-16
申请人： Junling Zhao , Aaron Scott Puhala , John Joseph Andre Verthe , David John Zanzig
发明人： Junling Zhao , Aaron Scott Puhala , John Joseph Andre Verthe , David John Zanzig
IPC分类号： B60C1/00
CPC分类号： C08C19/44 , B60C1/0016 , C08C19/20 , C08C19/22 , C08C19/25 , C08K3/04 , C08K3/36 , C08L9/00 , C08L9/06 , C08L15/00 , C08L19/006 , C08L2666/08
摘要： Pneumatic rubber tire with an outer, circumferential tread comprised of a cis 1,4-polybutadiene-rich and silica-rich rubber composition which contains specified elastomers with spatially defined glass transition temperatures, in conjunction with silica and specified carbon black reinforcement.
摘要翻译：具有外圆周胎面的气动橡胶轮胎，其包含富含顺式1,4-聚丁二烯的富二氧化硅的橡胶组合物，其含有具有空间限定的玻璃化转变温度的特定弹性体，与二氧化硅和特定的炭黑增强剂结合。

5. 发明申请

US20080149248A1 PNEUMATIC TIRE 有权
标题翻译：气动轮胎
公开(公告)号：US20080149248A1
公开(公告)日：2008-06-26
申请号：US11952391
申请日：2007-12-07
申请人： David John Zanzig , Uwe Emest Frank , Georges Marcel Victor Thielen , Manfred Josef Jung
发明人： David John Zanzig , Uwe Emest Frank , Georges Marcel Victor Thielen , Manfred Josef Jung
IPC分类号： B60C1/00
CPC分类号： C08L9/00 , B60C1/0025 , C08K3/36 , C08L7/00 , C08L15/00 , C08L21/00 , C08L51/04 , Y10T152/10495 , Y10T152/10513 , C08L2666/02
摘要： A pneumatic tire having a rubber sidewall including (A) 30 to 80 phr of natural rubber; (B) 20 to 70 phr of cis 1,4-polybutadiene rubber; (C) from 10 to 100 phr of silica; and (D) from 1 to 30 phr of a particulate rubber gel filler selected from the group consisting of polybutadiene gel, styrene butadiene gel, acrylonitrile-butadiene gel, chloroprene gel, natural rubber gel, and mixtures thereof.
摘要翻译：一种具有橡胶侧壁的充气轮胎，其包含（A）30〜80phr的天然橡胶; （B）20〜70phr顺式1,4-聚丁二烯橡胶; （C）10〜100phr二氧化硅; 和（D）1至30phr的选自聚丁二烯凝胶，苯乙烯丁二烯凝胶，丙烯腈 - 丁二烯凝胶，氯丁二烯凝胶，天然橡胶凝胶及其混合物的颗粒状橡胶凝胶填料。

6. 发明授权

US07163975B2 Tire with compound of rubber composition comprised of silanol and/or siloxy functionalized elastomer and silica 有权
标题翻译：由硅烷醇和/或甲硅烷氧基官能化弹性体和二氧化硅组成的橡胶组合物的轮胎
公开(公告)号：US07163975B2
公开(公告)日：2007-01-16
申请号：US10628735
申请日：2003-07-28
申请人： David John Zanzig , Georges Marcel Victor Thielen , John Joseph Andre Verthe
发明人： David John Zanzig , Georges Marcel Victor Thielen , John Joseph Andre Verthe
IPC分类号： C08L25/10 , C08F136/05 , B60C5/00
CPC分类号： C08L9/06 , B60C1/00 , B60C1/0016 , C08C19/44 , C08K5/548 , C08K9/02 , C08K9/06 , C08L3/00 , C08L15/00 , C08L21/00 , C08L2666/02
摘要： The invention relates to a tire having at least one component (e.g. tread) of a rubber composition comprised of a composite of styrene/butadiene elastomer and functionalized styrene/butadiene elastomer containing an internal silanol and/or siloxy group therein with pendent silanol and/or alkoxy groups of a polymodal (e.g. bimodal) molecular weight distribution and a dispersion therein of silica aggregates of which a portion thereof contain a plurality of hydroxyl groups on their surface in a form of geminal hydroxyl groups. In one aspect, said silica aggregates may be pre-treated to reduce said hydroxyl groups on their surface prior to blending with said silanol and/or siloxy functionalized elastomer.
摘要翻译：本发明涉及一种具有橡胶组合物的至少一种组分（例如胎面）的轮胎，其由苯乙烯/丁二烯弹性体和含有内部硅烷醇和/或甲硅烷氧基的官能化苯乙烯/丁二烯弹性体的复合材料组成，其中含有侧链硅烷醇和/或多模态（例如双峰）分子量分布的烷氧基和二氧化硅聚集体的分散体，其一部分在其表面上以偕羟基的形式含有多个羟基。在一个方面，所述二氧化硅聚集体可以在与所述硅烷醇和/或甲硅烷氧基官能化的弹性体共混之前进行预处理以减少其表面上的所述羟基。

7. 发明授权

US06852794B2 Rubber compound containing a polyhedral oligomeric silsesquioxanes 失效
标题翻译：含有多面体低聚倍半硅氧烷的橡胶化合物
公开(公告)号：US06852794B2
公开(公告)日：2005-02-08
申请号：US10214721
申请日：2002-08-07
申请人： Aaron Scott Puhala , David John Zanzig , Brian David Holden , Neil Arthur Maly
发明人： Aaron Scott Puhala , David John Zanzig , Brian David Holden , Neil Arthur Maly
IPC分类号： B60C1/00 , C08L21/00 , C08L83/04 , C08L83/06 , C08L83/08
CPC分类号： C08L21/00 , B60C1/00 , B60C1/0016 , C08G77/14 , C08G77/16 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/28 , C08G77/30 , C08G77/70 , C08K3/04 , C08K3/36 , C08K5/372 , C08L83/04 , C08L2666/14 , C08L2666/08 , C08L2666/04
摘要： There is disclosed a pneumatic tire having a rubberized component comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 110 phr of a polyhedral oligomeric silsesquioxanes.
摘要翻译：公开了一种具有橡胶组分的充气轮胎，包括：（a）100重量份的至少一种含有烯属不饱和的橡胶; 和（b）1至110phr的多面体低聚倍半硅氧烷。

8. 发明授权

US06686420B1 Pneumatic tire having a component containing high trans styrene-isoprene-butadiene rubber 失效
标题翻译：具有含有高反式苯乙烯 - 异戊二烯 - 丁二烯橡胶的组分的气动轮胎
公开(公告)号：US06686420B1
公开(公告)日：2004-02-03
申请号：US10324438
申请日：2002-12-19
申请人： David John Zanzig , Adel Farhan Halasa , John Robert Zuppo, III , John Joseph Andre Verthe
发明人： David John Zanzig , Adel Farhan Halasa , John Robert Zuppo, III , John Joseph Andre Verthe
IPC分类号： C08F23610
CPC分类号： C08L9/06 , C08L21/00 , C08L2666/08
摘要： The invention is directed to a pneumatic tire having at least one component comprising a vulcanizable rubber composition, wherein the vulcanizable rubber composition comprises, based on 100 parts by weight of elastomer (phr), from about 30 to 100 phr of high trans random SIBR, and from about zero to about 70 phr of at least one additional elastomer, wherein the high trans random SIBR comprises from about 3 to about 30 percent by weight of styrene.
摘要翻译：本发明涉及具有至少一种包含可硫化橡胶组合物的组分的充气轮胎，其中所述可硫化橡胶组合物基于100重量份的弹性体（phr），约30至100phr的高反式随机SIBR，和约0至约70phr的至少一种另外的弹性体，其中高反式随机SIBR包含约3至约30重量％的苯乙烯。

9. 外观设计

USD478861S1 Camouflage tire and wheel assembly 失效
公开(公告)号：USD478861S1
公开(公告)日：2003-08-26
申请号：US29161266
申请日：2002-05-24
申请人： David John Zanzig , Billy Joe Ratliff, Jr.
设计人： David John Zanzig , Billy Joe Ratliff, Jr.

10. 外观设计

USD477807S1 Camouflage tire and wheel assembly 失效
公开(公告)号：USD477807S1
公开(公告)日：2003-07-29
申请号：US29161217
申请日：2002-05-24
申请人： David John Zanzig , Mark Allen Grund , Billy Joe Ratliff, Jr.
设计人： David John Zanzig , Mark Allen Grund , Billy Joe Ratliff, Jr.

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