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1. 发明授权

US5959048A Soluble anionic polymerization initiators for preparing functionalized polymer 失效
标题翻译：用于制备官能化聚合物的可溶性阴离子聚合引发剂
公开(公告)号：US5959048A
公开(公告)日：1999-09-28
申请号：US886678
申请日：1997-07-01
申请人： David F. Lawson , James E. Hall , Yoichi Ozawa
发明人： David F. Lawson , James E. Hall , Yoichi Ozawa
IPC分类号： C08F4/48 , C07D295/22 , C08C19/44 , C08F4/08 , C08F4/42 , C08F36/04 , C08F36/06 , C08F236/10 , C08K3/04
CPC分类号： C08C19/44 , C07D295/22 , C08F36/04 , Y10S152/905 , Y10T152/10495
摘要： An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.
摘要翻译：无环烷烃可溶性阴离子聚合引发剂包括约90至约10重量份的具有通式A1Li的锂二胺和约10至约90重量份的至少一种其它具有通式 A2Li。 A1和A2选自二烷基，烷基，环烷基和二环烷基胺基和环胺基。还提供了形成阴离子聚合引发剂，官能化聚合物和形成官能化聚合物的方法的混合物的方法。

2. 发明授权

US5723533A Soluble anionic polymerization initiators and products therefrom 失效
标题翻译：可溶性阴离子聚合引发剂及其产物
公开(公告)号：US5723533A
公开(公告)日：1998-03-03
申请号：US756548
申请日：1996-11-26
申请人： David F. Lawson , James E. Hall , Yoichi Ozawa
发明人： David F. Lawson , James E. Hall , Yoichi Ozawa
IPC分类号： C08F4/48 , C07D295/22 , C08C19/44 , C08F4/00 , C08F4/06 , C08F4/08 , C08F36/04 , C08F236/04 , C08K3/04
CPC分类号： C08C19/44 , C07D295/22 , C08F36/04 , Y10T152/10495
摘要： An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.
摘要翻译：无环烷烃可溶性阴离子聚合引发剂包括约90至约10重量份的具有通式A1Li的锂二胺和约10至约90重量份的至少一种其它具有通式 A2Li。 A1和A2选自二烷基，烷基，环烷基和二环烷基胺基和环胺基。还提供了形成阴离子聚合引发剂，官能化聚合物和形成官能化聚合物的方法的混合物的方法。

3. 发明授权

US5643848A Soluble anionic polymerization initiators and products therefrom 失效
标题翻译：可溶性阴离子聚合引发剂及其产物
公开(公告)号：US5643848A
公开(公告)日：1997-07-01
申请号：US433110
申请日：1995-05-03
申请人： David F. Lawson , James E. Hall , Yoichi Ozawa
发明人： David F. Lawson , James E. Hall , Yoichi Ozawa
IPC分类号： C08F4/48 , C07D295/22 , C08C19/44 , C08F4/08 , C08F4/42 , C08F36/04 , C08F36/06 , C08F236/10 , C07D295/00 , C07D487/08
CPC分类号： C08C19/44 , C07D295/22 , C08F36/04 , Y10S152/905 , Y10T152/10495
摘要： An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.
摘要翻译：无环烷烃可溶性阴离子聚合引发剂包括约90至约10重量份的具有通式A1Li的锂二胺和约10至约90重量份的至少一种其它具有通式 A2Li。 A1和A2选自二烷基，烷基，环烷基和二环烷基胺基和环胺基。还提供了形成阴离子聚合引发剂，官能化聚合物和形成官能化聚合物的方法的混合物的方法。

4. 发明授权

US5578542A Soluble anionic polymerization initiators and method of preparing same 失效
标题翻译：可溶性阴离子聚合引发剂及其制备方法
公开(公告)号：US5578542A
公开(公告)日：1996-11-26
申请号：US220629
申请日：1994-03-30
申请人： David F. Lawson , James E. Hall , Yoichi Ozawa
发明人： David F. Lawson , James E. Hall , Yoichi Ozawa
IPC分类号： C08F4/48 , C07D295/22 , C08C19/44 , C08F4/00 , C08F4/06 , C08F4/08 , C08F36/04 , C08F236/04 , C07D295/00 , C07D487/08
CPC分类号： C08C19/44 , C07D295/22 , C08F36/04 , Y10T152/10495
摘要： An acyclic alkane soluble anionic polymerization initiator includes a mixture of from about 90 to about 10 parts by weight of a lithio amine having the general formula A.sub.1 Li and from about 10 to about 90 parts by weight of at least one other lithio amine having the general formula A.sub.2 Li. A.sub.1 and A.sub.2 are selected from the dialkyl, alkyl, cycloalkyl and dicycloalkyl amine radicals and cyclic amine radicals. There is also provided a method of forming a mixture of anionic polymerization initiators, a functionalized polymer and a method of forming a functionalized polymer.
摘要翻译：无环烷烃可溶性阴离子聚合引发剂包括约90至约10重量份的具有通式A1Li的锂二胺和约10至约90重量份的至少一种其它具有通式 A2Li。 A1和A2选自二烷基，烷基，环烷基和二环烷基胺基和环胺基。还提供了形成阴离子聚合引发剂，官能化聚合物和形成官能化聚合物的方法的混合物的方法。

5. 发明授权

US6025450A Amine containing polymers and products therefrom 失效
标题翻译：含胺的聚合物及其产品
公开(公告)号：US6025450A
公开(公告)日：2000-02-15
申请号：US112913
申请日：1998-07-09
申请人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
发明人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
IPC分类号： B60C1/00 , B60C15/06 , C08C19/44 , C08F36/04
CPC分类号： C08C19/44 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C15/06 , C08F36/04 , Y10S152/905
摘要： A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.
摘要翻译：官能化聚合物包括携带至少一种选自具有通式的烷基，二烷基和环烷基胺基的官能团的聚合物链和具有以下通式的环胺基：其中R1是具有1至约12个碳原子的烷基，环烷基或芳烷基原子，并且R 2是具有约3至约16个亚甲基的亚烷基，取代的亚烷基，氧基或N-烷基氨基 - 亚烷基。本发明还提供了基于这样的聚合物的产品。

6. 发明授权

US5883183A Reduced hysteresis products prepared with anionic polymerization initiators 失效
标题翻译：用阴离子聚合引发剂制备的减少滞后产物
公开(公告)号：US5883183A
公开(公告)日：1999-03-16
申请号：US467363
申请日：1995-06-06
申请人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
发明人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
IPC分类号： C08F4/48 , B60C1/00 , C08F4/00 , C08F4/08 , C08F4/42 , C08F36/04 , C08F236/10 , C08K3/04 , C08L21/00 , C08F8/42
CPC分类号： C08F36/04 , B60C1/00 , B60C1/0016 , Y10T152/10495
摘要： The present invention is directed toward anionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译：本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂胺进行阴离子聚合。所述锂胺具有通式（A）Li（SOL）y，其中SOL是增溶组分，A是烷基，二烷基，环烷基或二环烷基胺基或环状胺，y是0或约0.5至本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

7. 发明授权

US5393721A Anionic polymerization initiators and reduced hysteresis products therefom 失效
标题翻译：阴离子聚合引发剂和减少的滞后产物
公开(公告)号：US5393721A
公开(公告)日：1995-02-28
申请号：US962373
申请日：1992-10-16
申请人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
发明人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
IPC分类号： C08K3/04 , B60C1/00 , C08F4/00 , C08F4/42 , C08F4/48 , C08F36/04 , C08F236/10 , C08L21/00
CPC分类号： C08F36/04 , B60C1/0016
摘要： The present invention is directed toward artionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译：本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂胺进行挥发聚合。所述锂胺具有通式（A）Li（SOL）y，其中SOL是增溶组分，A是烷基，二烷基，环烷基或二环烷基胺基或环状胺，y是0或约0.5至本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

8. 发明授权

US5552499A Process of preparing reduced hysteresis products using anionic polymerization initiators 失效
标题翻译：使用阴离子聚合引发剂制备减少滞后产物的方法
公开(公告)号：US5552499A
公开(公告)日：1996-09-03
申请号：US469151
申请日：1995-06-06
申请人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
发明人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
IPC分类号： C08F4/48 , B60C1/00 , C08F4/00 , C08F4/08 , C08F4/42 , C08F36/04 , C08F236/10 , C08K3/04 , C08L21/00 , C08F8/42
CPC分类号： C08F36/04 , B60C1/00 , B60C1/0016 , Y10T152/10495
摘要： The present invention is directed toward anionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL).sub.y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译：本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂胺进行阴离子聚合。所述锂胺具有通式（A）Li（SOL）y，其中SOL是增溶组分，A是烷基，二烷基，环烷基或二环烷基胺基或环状胺，y是0或约0.5至本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

9. 发明授权

US5329005A Soluble anionic polymerization initiators and preparation thereof 失效
标题翻译：可溶性阴离子聚合引发剂及其制备方法
公开(公告)号：US5329005A
公开(公告)日：1994-07-12
申请号：US955582
申请日：1992-10-02
申请人： David F. Lawson , Koichi Morita , Yoichi Ozawa , Mark L. Stayer, Jr. , Ryota Fujio
发明人： David F. Lawson , Koichi Morita , Yoichi Ozawa , Mark L. Stayer, Jr. , Ryota Fujio
IPC分类号： B60C1/00 , C07F1/02 , C08F4/00 , C08F4/08 , C08F4/42 , C08F4/48 , C08F36/00 , C08F36/04 , C08K3/04 , C08L9/00 , C08L21/00 , C07D487/08 , C07D295/00
CPC分类号： C08F36/04
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in hydrocarbon solvents. The initiators include a lithio amine having the general formula ALi. The component A is a dialkyl or dicycloalkyl amine radical or a cyclic amine. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译：本发明涉及可溶于烃溶剂的阴离子聚合引发剂。引发剂包括具有通式ALi的锂胺。组分A是二烷基或二环烷基胺基或环胺。本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

10. 发明授权

US6084025A Reduced hysteresis products prepared with anionic polymerization initiators 有权
标题翻译：用阴离子聚合引发剂制备的减少滞后产物
公开(公告)号：US6084025A
公开(公告)日：2000-07-04
申请号：US267724
申请日：1999-03-15
申请人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
发明人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
IPC分类号： C08F4/48 , B60C1/00 , C08F4/00 , C08F4/08 , C08F4/42 , C08F36/04 , C08F236/10 , C08K3/04 , C08L21/00 , C08F8/42
CPC分类号： C08F36/04 , B60C1/00 , B60C1/0016 , Y10T152/10495
摘要： A functionalized polymer prepared by a process comprising the steps of preparing a solution of a cyclic amine compound, an organolithium compound, and from 3 to about 300 equivalents, based upon one equivalent of lithium, of a monomer selected from the group including diene monomers, vinyl aromatic monomers, and mixtures thereof, where the cyclic amine compound is defined by the formula where R.sub.2 is selected from the group consisting of an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups, N is a nitrogen atom, and H is a hydrogen atom, thereby forming a polymerization initiator having the formula where Li is a lithium atom, SOL is a divalent hydrocarbon group having from 3 to about 300 polymerized monomeric units, y is from 0.5 to about 3, and A is a cyclic amine radical derived from the cyclic amine, charging the solution containing (A)Li(SOL)y with from about 0.01 to about 2 equivalents per equivalent of lithium of a chelating agent, and an organic alkali metal compound selected from the group consisting of compounds having the formula R.sub.4 OM, R.sub.5 C(O)OM, R.sub.6 R.sub.7 NM, and R.sub.8 SO.sub.3 M, where R.sub.4, R.sub.5, R.sub.6 R.sub.7, and R.sub.8 are each selected from the group consisting of alkyls, cycloalkyls, alkenyls, aryls, and phenyls, having from 1 to about 12 carbon atoms; and where M is selected from the group consisting of Na, K, Rb and Cs, and sufficient monomer to form a living polymeric structure, and quenching the living polymeric structure.
摘要翻译：一种官能化聚合物，其通过以下步骤制备：包括以下步骤：以基于一当量的锂制备环胺化合物，有机锂化合物和约3至约300当量的选自以下的单体的溶液：包括二烯单体，乙烯基芳族单体及其混合物，其中环胺化合物由下式定义：其中R2选自具有约3至约16个亚甲基的亚烷基，取代的亚烷基，氧基或N-烷基氨基 - 亚烷基基团，N是氮原子，H是氢原子，由此形成具有下式的聚合引发剂，其中Li是锂原子，SOL是具有3-约300个聚合单体单元的二价烃基，y是0.5 A为来自环状胺的环状胺基，将含有（A）Li（SOL）y的溶液与约0.01〜约2当量/当量的锂螯合剂和选自具有式R4OM，R5C（O）OM，R6R7NM和R8SO3M的化合物的有机碱金属化合物，其中R4，R5，R6 R7和R8各自选自：具有1至约12个碳原子的烷基，环烷基，烯基，芳基和苯基; 并且其中M选自Na，K，Rb和Cs，以及足够的单体以形成活性聚合物结构，并淬灭活性聚合物结构。

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