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1. 发明申请

US20120148846A1 COLOR PLUS CLEAR COATING SYSTEMS EXHIBITING DESIRABLE APPEARANCE AND FINGERPRINT RESISTANCE PROPERTIES AND RELATED METHODS 审中-公开
标题翻译：彩色透明涂料系统展示了可视外观和指纹电阻特性及相关方法
公开(公告)号：US20120148846A1
公开(公告)日：2012-06-14
申请号：US12964822
申请日：2010-12-10
申请人： David C. Martin , Brian K. Rearick , Kurt A. Humbert , Xiangling Xu , Noel R. Vanier
发明人： David C. Martin , Brian K. Rearick , Kurt A. Humbert , Xiangling Xu , Noel R. Vanier
IPC分类号： B32B27/08 , B05D1/36
CPC分类号： C08G18/2885 , C08G18/672 , C09D175/16 , Y10T428/31504
摘要： Disclosed are methods of forming a multi-component composite coating on a substrate. The methods include applying a transparent radiation curable film-forming composition onto a colored base coat deposited upon a substrate to form a transparent top coat over the basecoat. The colored base coat includes a colorant and a film-forming resin, and the transparent radiation curable film-forming composition includes a fluorine-containing radiation curable compound.
摘要翻译：公开了在基材上形成多组分复合涂层的方法。所述方法包括将透明的可辐射固化的成膜组合物施加到沉积在基底上的着色底涂层上以在底涂层上形成透明的顶涂层。着色底涂层包括着色剂和成膜树脂，透明的可辐射固化膜形成组合物包含含氟可辐射固化的化合物。

2. 发明申请

US20120148848A1 POLYMERIC SUBSTRATES HAVING A THIN METAL FILM AND FINGERPRINT RESISTANT CLEAR COATING DEPOSITED THEREON AND RELATED METHODS 审中-公开
标题翻译：具有薄金属薄膜和指纹电阻透明涂层的聚合物基板及其相关方法
公开(公告)号：US20120148848A1
公开(公告)日：2012-06-14
申请号：US13050118
申请日：2011-03-17
申请人： David C. Martin , Kurt A. Humbert , Brian K. Rearick
发明人： David C. Martin , Kurt A. Humbert , Brian K. Rearick
IPC分类号： B05D7/00 , B32B27/28 , B05D1/36 , B32B15/00
CPC分类号： B05D5/067 , B05D5/083 , B05D2350/65 , Y10T428/3154 , Y10T428/31678
摘要： Disclosed are methods of coating a polymeric substrate. The methods include (a) depositing a thin metal film onto the polymeric substrate, and (b) depositing a transparent radiation curable film-forming composition onto a thin metal film, wherein the transparent radiation curable film-forming composition comprises a fluorine-containing radiation curable compound.
摘要翻译：公开了涂覆聚合物基材的方法。所述方法包括：（a）在所述聚合物基材上沉积薄金属膜，和（b）将透明的可辐射固化成膜组合物沉积到薄金属膜上，其中所述透明可辐射固化膜形成组合物包含含氟辐射可固化化合物。

3. 发明授权

US08901198B2 UV-curable coating compositions, multi-component composite coatings, and related coated substrates 有权
标题翻译：紫外光固化涂料组合物，多组分复合涂料和相关的涂布基材
公开(公告)号：US08901198B2
公开(公告)日：2014-12-02
申请号：US12940168
申请日：2010-11-05
申请人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
发明人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
IPC分类号： C08F2/50 , C08J3/28 , C08F2/48 , C08F2/46 , C08G18/79 , C09D175/16 , C08G18/67 , C08G18/32
CPC分类号： C08G18/792 , C08F2/48 , C08G18/3206 , C08G18/672 , C09D175/16
摘要： Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
摘要翻译：本文公开了溶剂型液体UV可固化涂料组合物，其包含：包含具有大于两个不饱和位点的丙烯酸酯封端的化合物的可辐射固化化合物，其中所述丙烯酸酯封端的化合物包含反应物的反应产物，其包含：多异氰酸酯的加合物，其中多异氰酸酯的加成物包括包含多于两个异氰酸酯基的多异氰酸酯和具有与多异氰酸酯的异氰酸酯基反应的基团的化合物的反应物的反应产物; 和含活性氢的丙烯酸酯; 以及光引发剂组合物，其包括用于提供表面固化的第一光引发剂组合物和用于通过固化所得涂层提供的第二光引发剂组合物。还公开了相关的多组分复合涂层，涂覆的基底和用于涂覆基底的方法。

4. 发明申请

US20120115975A1 UV-Curable Coating Compositions, Multi-Component Composite Coatings, and Related Coated Substrates 有权
标题翻译： UV可固化涂料组合物，多组分复合涂料和相关涂层基材
公开(公告)号：US20120115975A1
公开(公告)日：2012-05-10
申请号：US12940168
申请日：2010-11-05
申请人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
发明人： Charles M. Kania , Kenneth T. Phelps , Kurt A. Humbert , Todd M. Roper , Jiping Shao , David C. Martin
IPC分类号： C09D175/00 , C08F2/46
CPC分类号： C08G18/792 , C08F2/48 , C08G18/3206 , C08G18/672 , C09D175/16
摘要： Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
摘要翻译：本文公开了溶剂型液体UV可固化涂料组合物，其包含：包含具有大于两个不饱和位点的丙烯酸酯封端的化合物的可辐射固化化合物，其中所述丙烯酸酯封端的化合物包含反应物的反应产物，其包含：多异氰酸酯的加合物，其中多异氰酸酯的加成物包括包含多于两个异氰酸酯基的多异氰酸酯和具有与多异氰酸酯的异氰酸酯基反应的基团的化合物的反应物的反应产物; 和含活性氢的丙烯酸酯; 以及光引发剂组合物，其包括用于提供表面固化的第一光引发剂组合物和用于通过固化所得涂层提供的第二光引发剂组合物。还公开了相关的多组分复合涂层，涂覆的基底和用于涂覆基底的方法。

5. 发明授权

US06265489B1 Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization 失效
标题翻译：含有通过原子转移自由基聚合制备的羧酸官能聚合物的热固性组合物
公开(公告)号：US06265489B1
公开(公告)日：2001-07-24
申请号：US09375017
申请日：1999-08-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08L3302
CPC分类号： C09D133/02 , C08L63/00 , C09D133/064 , C08L2666/14
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxide functional crosslinking agent having at least two epoxide groups, e.g., triglycidyl isocyanurate (TGIC), is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.0. The thermosetting compositions of the present invention have utility as powder coatings compositions.
摘要翻译：描述了包含（a）多元羧酸官能聚合物和（b）具有至少两个环氧基团的环氧官能交联剂例如三缩水甘油基异氰脲酸酯（TGIC）的共反应固体，颗粒混合物的热固性组合物。聚羧酸官能聚合物通过原子转移自由基聚合制备，并且具有良好的聚合物链结构和小于2.0的多分散指数。本发明的热固性组合物可用作粉末涂料组合物。

6. 发明授权

US07132477B2 Powder coating compositions 失效
标题翻译：粉末涂料组合物
公开(公告)号：US07132477B2
公开(公告)日：2006-11-07
申请号：US10928902
申请日：2004-08-27
申请人： Kurt A. Humbert , Karen S. Rechenberg , Edward R. Coleridge , Charles M. Kania , Paul H. Lamers
发明人： Kurt A. Humbert , Karen S. Rechenberg , Edward R. Coleridge , Charles M. Kania , Paul H. Lamers
IPC分类号： C08F8/00
CPC分类号： C09D5/033 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , B05D7/57 , C08F8/00 , C08F210/10 , C08F220/06 , C08F220/10 , C08F220/32 , C08F290/046 , C08G18/6229 , C08G18/6254 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G59/4261 , C08G2150/20 , C08L33/02 , C08L33/04 , C08L33/068 , C08L2312/00 , C09D123/22 , C09D133/062 , C09D133/068 , C09D133/08 , C09D163/00 , Y10T428/31855 , C08L2666/04 , C08F220/00 , C08F2500/26 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F212/00 , C08F222/00 , C08F214/18 , C08F2500/03 , C08F2500/02
摘要： A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material, and a monocarboxylic acid. Multi-component composite coatings, coated substrates, and related methods are also provided.
摘要翻译：一种热固性组合物，其包含可共反应的固体，具有官能团的成膜材料的颗粒混合物，具有至少两个与成膜材料中的官能团反应的官能团的交联剂和一元羧酸。还提供了多组分复合涂层，涂覆的基材和相关方法。

7. 发明授权

US06313224B1 Coating of film-forming resin and functional flow control copolymer 失效
标题翻译：成膜树脂和功能流动控制共聚物的涂层
公开(公告)号：US06313224B1
公开(公告)日：2001-11-06
申请号：US09437891
申请日：1999-11-09
申请人： Debra L. Singer , Kurt G. Olson , Kurt A. Humbert , Karen A. Barkac , Mark E. Wozniak
发明人： Debra L. Singer , Kurt G. Olson , Kurt A. Humbert , Karen A. Barkac , Mark E. Wozniak
IPC分类号： C08L2304
CPC分类号： C09D201/00 , C09D7/47 , Y10T428/31692 , C08L2666/04
摘要： Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer. Comonomer (iii) can be present in the copolymer in an effective amount to give the copolymer a hydroxyl number is in the range of about 0 to 100.
摘要翻译：可固化的涂料组合物包括液体或颗粒状可固化成膜树脂材料，流动控制剂，其是共聚物和任选的液体树脂材料的载体。该共聚物来自烷基中至少一个含有1-20个碳原子的非氨基，非羟基和非酸官能的丙烯酸酯或甲基丙烯酸烷基酯，和（i）氨基官能的丙烯酸酯和甲基丙烯酸酯的官能单体有效量使得共聚物的胺值在2-70范围内，或（ii）酸官能丙烯酸酯和甲基丙烯酸酯有效量，以使共聚物的酸值在10至30的范围内。另外，在丙烯酸羟烷基酯和/或甲基丙烯酸羟烷基酯和/或己内酯多元醇单体的共聚物中可以存在官能单体（i）或（ii）另一功能性共聚单体（iii）。共聚单体（iii）可以以有效的量存在于共聚物中，得到共聚物，羟值在约0-100范围内。

8. 发明授权

US06251999B1 Tin carboxylate catalysts for epoxy-acid coating compositions 失效
标题翻译：用于环氧酸涂料组合物的羧酸锡催化剂
公开(公告)号：US06251999B1
公开(公告)日：2001-06-26
申请号：US09339394
申请日：1999-06-23
申请人： Daniel E. Rardon , Kurt A. Humbert , Karen A. Barkac , Peter Kamarchik, Jr. , Mark E. Wozniak
发明人： Daniel E. Rardon , Kurt A. Humbert , Karen A. Barkac , Peter Kamarchik, Jr. , Mark E. Wozniak
IPC分类号： C08F800
CPC分类号： C09D163/00 , C07F7/2224 , C08G59/42 , C08G59/685 , C08L2666/04 , C08L2666/18
摘要： A catalytic tin carboxylate adduct, which is useful as a catalyst in epoxy-acid coating compositions, is the reaction product of (A) a mono-, di-, or poly-carboxylic acid functional compound and (B) an organotin compound containing one to three aryl groups and at least one halogen or hydroxyl group attached to the tin atom. There is also provided an epoxy-acid coating composition, which incorporates this catalytic tin carboxylate adduct. The epoxy-acid coating composition is advantageous as an automotive topcoat, particularly as a clear coat composition because it exhibits good appearance, durability, stability and generates no, or extremely low levels of benzene during the curing process.
摘要翻译：可用作环氧 - 酸性涂料组合物中的催化剂的催化锡羧酸盐加合物是（A）单羧酸官能化合物，二羧酸或多羧酸官能化合物与（B）含有一个或多个羧酸官能化合物的有机锡化合物的反应产物至三个芳基和至少一个与锡原子连接的卤素或羟基。还提供了一种环氧酸涂料组合物，其包含该催化性羧酸锡加合物。环氧酸涂料组合物作为汽车面漆是特别有利的，特别是作为透明涂料组合物，因为它在固化过程中表现出良好的外观，耐久性，稳定性和不产生或极低的苯含量。

9. 发明授权

US06670043B2 Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization 失效
公开(公告)号：US06670043B2
公开(公告)日：2003-12-30
申请号：US09992038
申请日：2001-11-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： B32B2708
CPC分类号： C09D133/02 , C09D133/064 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , C08L2666/36
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) beta-hydroxyalkylamide crosslinking agent, e.g., bis(N,N-di-2-hydroxyethyl)adipamide, and (b) polycarboxylic acid functional polymer, is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.

10. 发明授权

US06638578B2 Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization 失效
公开(公告)号：US06638578B2
公开(公告)日：2003-10-28
申请号：US09992037
申请日：2001-11-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08J712
CPC分类号： C09D133/02 , C09D133/064 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , C08L2666/36
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) beta-hydroxyalkylamide crosslinking agent, e.g., bis(N,N-di-2-hydroxyethyl)adipamide, and (b) polycarboxylic acid functional polymer, is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.

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