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1. 发明授权

US5650536A Continuous process for production of functionalized olefins 失效
标题翻译：连续生产官能化烯烃的方法
公开(公告)号：US5650536A
公开(公告)日：1997-07-22
申请号：US261560
申请日：1994-06-17
申请人： David C. Dankworth , William H. Cross , Joseph V. Cusumano , William D. Diana , William B. Eckstrom , Jacob I. Emert , Keith R. Gorda , Robert M. Koros , Harold W. Margo , Jon E. Stanat
发明人： David C. Dankworth , William H. Cross , Joseph V. Cusumano , William D. Diana , William B. Eckstrom , Jacob I. Emert , Keith R. Gorda , Robert M. Koros , Harold W. Margo , Jon E. Stanat
IPC分类号： C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04 , C07C67/00
CPC分类号： C10M149/06 , B01J19/0066 , B01J19/2415 , B01J19/242 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/14 , C08F8/32 , C08F8/42 , C10L1/143 , C10L1/1817 , C10L1/195 , C10L1/198 , C10L1/206 , C10L1/221 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/2475 , C10L1/2493 , C10L1/2691 , C10L1/285 , C10L1/303 , C10L10/00 , C10L10/18 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M159/18 , B01J2219/00094 , C08F2800/20 , C10L1/208 , C10L1/2387 , C10L1/2683 , C10L1/30 , C10M2207/023 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/289 , C10M2209/00 , C10M2209/02 , C10M2209/082 , C10M2209/10 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/024 , C10M2217/046 , C10M2217/06 , C10M2219/062 , C10M2227/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/07 , C10N2210/08 , C10N2240/00 , C10N2240/02 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/40 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02 , Y02P20/582
摘要： A continuous process for functionalizing olefins, especially polymer olefins in a CSTR or pipe reactor. Esters are preferably produced by continuous reaction of the olefin with carbon monoxide and a nucleophilic trapping agent. The liquid-filled pipe reactor operates in plug flow with static mixers and the CSTR is operated in the substantial absence of air at constant liquid level.
摘要翻译：在CSTR或管式反应器中官能化烯烃，特别是聚合物烯烃的连续方法。酯优选通过烯烃与一氧化碳和亲核捕集剂的连续反应来制备。液体填充的管式反应器在具有静态混合器的活塞流中运行，并且CSTR在基本上不存在恒定液位的空气下操作。

2. 发明授权

US5354990A In-situ localized tracer injection/fiber optic detection for measurement of flow distributions in fixed bed reactors 失效
标题翻译：用于测量固定床反应器中流量分布的原位局部示踪剂注入/光纤检测
公开(公告)号：US5354990A
公开(公告)日：1994-10-11
申请号：US63393
申请日：1993-05-18
申请人： David C. Dankworth , Robert M. Koros
发明人： David C. Dankworth , Robert M. Koros
IPC分类号： B01J8/00 , G01F1/704 , G01F1/00 , G01F1/66
CPC分类号： G01F1/704 , B01J8/001
摘要： The distribution of fluid flowing through a packed bed reactor is determined by placing a plurality of fiber optic sensors at desired locations within the packed bed reactor. A light analyzable tracer component is injected into the fluid flowing through the reactor. Light is supplied to each of the sensors causing any tracer component in the vicinity of the sensor to emit electromagnetic radiation. The emitted electromagnetic radiation is detected at each fiber optic sensor, thereby permitting the amount of tracer in the vicinity of each sensor to be determined, and consequently providing a measure of the distribution of fluid flowing through the reactor.
摘要翻译：通过将多个光纤传感器放置在填充床反应器内的所需位置来确定流过填充床反应器的流体的分布。将可分光示踪剂组分注入流经反应器的流体中。光被提供给每个传感器，导致传感器附近的任何示踪器部件发射电磁辐射。在每个光纤传感器处检测发射的电磁辐射，从而允许确定每个传感器附近的示踪剂的量，并且因此提供流过反应器的流体分布的量度。

3. 发明授权

US5403561A Mixed phase fixed bed reactor distributor 失效
标题翻译：混合式固定床反应器分配器
公开(公告)号：US5403561A
公开(公告)日：1995-04-04
申请号：US113163
申请日：1993-08-27
申请人： Robert M. Koros , Yiu W. Wong , John T. Wyatt , David C. Dankworth
发明人： Robert M. Koros , Yiu W. Wong , John T. Wyatt , David C. Dankworth
IPC分类号： B01J8/00 , B01J8/04 , B01J19/26 , B05B1/26
CPC分类号： B05B1/262 , B01J19/26 , B01J8/0492 , B01J2208/00539
摘要： The uniform distribution of mixed phase fluid stream on to the top of a contact bed in a reactor chamber is provided by a horizontal tray with a plurality of spaced-apart, vertically disposed chimneys extending through the tray. These chimneys have a first end to receive liquid and gas above the tray and a second end for distributing the liquid and gas downwardly below the tray. Importantly, the second end is provided with a spray generating device located below the tray for producing a conical downward spray of the mixed fluid phase onto the top surface of a bed of contact material positioned below the tray. The spray generating devices for producing the conical spray are located at positions so that the spray of the mixed fluid stream from one spray generating device as it impinges on the top surface of the fixed bed, will overlap the spray from an adjacent spray generating device.
摘要翻译：混合相流体流在反应器室中的接触床的顶部上的均匀分布由具有延伸穿过托盘的多个间隔开的垂直设置的烟囱的水平托盘提供。这些烟囱具有在托盘上方接收液体和气体的第一端和用于将液体和气体向下分配到托盘下方的第二端。重要的是，第二端设置有位于托盘下方的喷雾产生装置，用于产生混合流体相的锥形向下喷射到位于托盘下方的接触材料床的顶表面上。用于生产锥形喷雾器的喷雾产生装置位于使得当其撞击在固定床的顶表面上时来自一个喷雾发生装置的混合流体流的喷射将与来自相邻喷雾产生装置的喷雾重叠。

4. 发明授权

US3960508A Trough-type scale traps 失效
标题翻译：槽式尺度捕集器
公开(公告)号：US3960508A
公开(公告)日：1976-06-01
申请号：US520485
申请日：1974-11-04
申请人： Glyndwr A. R. Bessant , Paul D. Eichamer , Robert M. Koros , Steven R. Schieni
发明人： Glyndwr A. R. Bessant , Paul D. Eichamer , Robert M. Koros , Steven R. Schieni
IPC分类号： B01D46/24 , B01J8/02 , B01J8/00 , B01D50/00
CPC分类号： B01J8/0278 , B01D46/24
摘要： A trough-type scale trap for use with a refinery or chemical plant reactor having a catalyst bed subject to plugging by fine particles. Compared to prior art traps, the trough-type scale trap of the invention is characterized by a larger volumetric capacity and screen area and is substantially easier to construct and to install or remove from closed reactor vessels than conventional traps. Its typical embodiment is as a series of parallel troughs having rectangular openings and disposed chordally across the reactor normal to the direction of flow. In one embodiment, the trough is a rectangular parallelepiped; in another embodiment, the substantially rectangular opening is reduced by tapering to a bottom significantly smaller than the inlet opening.
摘要翻译：一种与炼油厂或化学工厂反应器一起使用的槽型刻度阱，其具有由细颗粒堵塞的催化剂床。与现有技术的捕集阱相比，本发明的槽型捕集阱的特征在于体积容量和筛分面积更大，并且比常规捕集阱更容易构建和安装或从封闭的反应器容器移除。其典型的实施例是一系列具有矩形开口的平行槽，并且平行地沿着流动方向平行地布置在反应堆上。在一个实施例中，槽是长方体; 在另一个实施例中，基本上矩形的开口通过锥形减小到明显小于入口开口的底部。

5. 发明申请

US20130270483A1 CATALYTICAL GASIFIER CONFIGURATION FOR BIOMASS PYROLYSIS 审中-公开
标题翻译：用于生物质热解的催化气体配置
公开(公告)号：US20130270483A1
公开(公告)日：2013-10-17
申请号：US13551146
申请日：2012-07-17
申请人： Moshe BEN-REUVEN , Howard L. Fang , Meifang Qin , Robert M. Koros , Arie Toren
发明人： Moshe BEN-REUVEN , Howard L. Fang , Meifang Qin , Robert M. Koros , Arie Toren
IPC分类号： C01B3/02 , C01B3/38
CPC分类号： C01B3/38 , C01B2203/0233 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/1041 , C01B2203/1058 , C01B2203/1241 , C10J3/482 , C10J3/84 , C10J2300/0916 , C10J2300/0986 , C10J2300/1853 , C10K1/026 , C10K1/04 , C10K3/026 , Y02P20/145 , Y02P20/146
摘要： The invention relates to systems and methods for producing synthesis gas. In particular, the systems of the present invention include two catalytic reactors in series, a wet reformer/gasifier followed by a dry reformer. The systems produce synthesis gas with very little to no methane.
摘要翻译：本发明涉及用于生产合成气的系统和方法。特别地，本发明的系统包括串联的两个催化反应器，随后是干重整器的湿重整器/气化器。该系统产生几乎没有甲烷的合成气。

6. 发明授权

US4233269A Gas liquid distributor 失效
标题翻译：气体液体分配器
公开(公告)号：US4233269A
公开(公告)日：1980-11-11
申请号：US959306
申请日：1978-11-09
申请人： Larry A. Kaye , Robert M. Koros
发明人： Larry A. Kaye , Robert M. Koros
IPC分类号： B01F5/04 , B01J4/00 , B01J10/00 , B01J19/00 , B01F3/08 , B01J12/00 , B01J14/00
CPC分类号： B01J19/006 , B01F5/0451 , B01J4/001 , B01J2219/00063 , B01J2219/00777
摘要： A fluid flow distributor for mixing and distributing gas and liquid over the cross-section of the reactor vessel having an upward fluid flow path. The distributor comprises an inlet pipe for directing quench liquid into and through an inlet feed conduit connected with the reactor and an elliptically-shaped cover plate disposed above the outlet of said conduit, against which the flow from the conduit is directed. A relatively uniform distribution of the gas and liquid to the vessel is obtained by means of the plurality of apertures provided in the plate and the double reflection of the flow from the cover plate and the bottom of the vessel. The inlet conduit includes a plurality of baffles and orifices which aid in the thorough mixing of the quench liquid and the primary or main gas-liquid flow. This is a continuation of application Ser. No. 777,028, filed Mar. 14, 1977 now abandoned.
摘要翻译：一种流体流量分配器，用于在具有向上流体流动路径的反应器容器的横截面上混合和分配气体和液体。分配器包括入口管，用于将淬冷液体引导到通过与反应器连接的入口进料管道中，并且通过设置在所述导管出口上方的椭圆形盖板，来自导管的流动朝向该入口管。通过设置在板中的多个孔和来自盖板和容器底部的流的双反射来获得气体和液体到容器的相对均匀的分布。入口管道包括多个挡板和孔口，其有助于骤冷液体和主气体或主气体液体流的充分混合。这是应用程序的延续。 1977年3月14日提交的777,028号现已放弃。

7. 发明授权

US4212835A Method and apparatus for introducing a quench stream in upflow gas-liquid contactors 失效
标题翻译：在上流气液接触器中引入淬火流的方法和装置
公开(公告)号：US4212835A
公开(公告)日：1980-07-15
申请号：US140747
申请日：1971-05-06
申请人： Robert M. Koros
发明人： Robert M. Koros
IPC分类号： B01F5/04 , B01J4/00 , B01J10/00 , B01F3/04
CPC分类号： B01J10/00 , B01F5/0451 , B01J4/001
摘要： A mixing device for combining a quench or catalyst stream with the main fluid stream in an upflow gas-liquid contactor, such as a reactor. A gas-liquid stream is passed through a reduced size passage wherein the quench or catalyst streams are injected. The combined stream then is mixed and redistributed.
摘要翻译：一种混合装置，用于将骤冷或催化剂流与主流体流在上流气液接触器如反应器中混合。气 - 液流通过减小尺寸的通道，其中注入骤冷或催化剂流。然后将组合的流混合并重新分配。

8. 发明授权

US5384336A Bubble column, tube side slurry process and apparatus 失效
标题翻译：泡沫柱，管侧浆料工艺和装置
公开(公告)号：US5384336A
公开(公告)日：1995-01-24
申请号：US159407
申请日：1993-11-30
申请人： Robert M. Koros
发明人： Robert M. Koros
IPC分类号： B01J8/00 , B01J8/18 , B01J8/22 , B01J19/24 , C07C1/04 , C07C1/06
CPC分类号： B01J8/22 , B01J19/2425 , B01J8/006 , B01J8/1818 , B01J8/1836 , C07C1/042 , C07C1/066 , B01J2208/00061 , B01J2208/00194 , B01J2208/00212 , B01J2208/0053 , B01J2208/0061 , C07C2523/75
摘要： A reactor housing having a plurality of reaction tubes vertically disposed therein for conducting slurry phase hydrocarbon synthesis reactions under substantially plug flow conditions, and wherein provision is made for uniformly distributing gas bubbles in slurry liquid into the reaction tubes.
摘要翻译：一种反应器壳体，其具有垂直设置在其中的多个反应管，用于在基本上流动的条件下进行淤浆相烃合成反应，并且其中提供用于将淤浆液体中的气泡均匀分布到反应管中。

9. 发明授权

US5190733A High interfacial area multiphase reactor 失效
标题翻译：高界面多相反应器
公开(公告)号：US5190733A
公开(公告)日：1993-03-02
申请号：US665637
申请日：1991-02-14
申请人： Milind B. Ajinkya , Robert M. Koros , Barry L. Tarmy
发明人： Milind B. Ajinkya , Robert M. Koros , Barry L. Tarmy
IPC分类号： B01F3/04 , B01J10/00 , B01J19/24 , B01J19/26 , C07C29/06
CPC分类号： B01F3/04106 , B01J19/246 , B01J19/2465 , B01J19/26 , C07C29/06 , B01J2219/00777 , Y10S261/75
摘要： In its simplest sense, the present invention provides a method for improving the contacting of plural, distinct phases in a vertically disposed vessel containing distinct fluid phases by injecting a stream of dispersed distinct phases together into the phases contained in the vessel at a sufficient velocity to force the fluid in the vessel to circulate downwardly through a central region in the vessel and upwardly in the annular region surrounding the central region.
摘要翻译：在其最简单的意义上，本发明提供了一种用于通过将分散的不同相一起注入容纳在容器中的相的速度以提供足够的速度来改善在垂直设置的容器中含有不同流体相的多个不同相的接触的方法，迫使容器中的流体向下循环通过容器中的中心区域并且在围绕中心区域的环形区域中向上循环。

10. 发明授权

US4961882A Fine bubble generator and method 失效
标题翻译：细气泡发生器及方法
公开(公告)号：US4961882A
公开(公告)日：1990-10-09
申请号：US502380
申请日：1990-03-30
申请人： Phiroz M. Bhagat , Robert M. Koros
发明人： Phiroz M. Bhagat , Robert M. Koros
IPC分类号： B01F3/04 , B01F3/08 , B01F5/02
CPC分类号： B01F3/0876 , B01F3/04262 , B01F5/0256 , B01F2003/04326 , B01F2003/04361
摘要： In its simplest sense, the present invention provides a method for forming fine gaseous bubbles in a liquid ambient by forcing a gas through orifices located in the liquid ambient to generate a stream of gas bubbles, while simultaneously forcing a liquid through liquid orifices at a velocity sufficient to form jet streams of liquid, the liquid orifices being substantially coplanar with and equal in number to the gas orifices so that each jet stream of liquid intersects each stream of gas bubbles and creates sufficient turbulence, whereby the fine gas bubbles are formed.
摘要翻译：在其最简单的意义上，本发明提供了一种通过迫使气体通过位于液体环境中的孔而产生气泡流而在液体环境中形成细小气泡的方法，同时迫使液体以液体流速以速度足以形成液体的喷射流，液体喷嘴基本上与气体孔共面并且数量相等，使得每个喷射流与每个气泡流相交并产生足够的湍流，由此形成细小的气泡。

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