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1. 发明授权

US09186617B2 Non-aqueous amine scrubbing for removal of carbon dioxide 有权
标题翻译：用于去除二氧化碳的非水胺洗涤
公开(公告)号：US09186617B2
公开(公告)日：2015-11-17
申请号：US13228652
申请日：2011-09-09
申请人： David C. Calabro , Lisa S. Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis G. Peiffer , Quanchang Li
发明人： David C. Calabro , Lisa S. Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis G. Peiffer , Quanchang Li
IPC分类号： B01D53/62 , B01D53/14 , B01D53/77 , B01D53/78 , B01D53/96
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.
摘要翻译：描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子溶剂在足以吸附至少一些CO 2的条件下进行。然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富含CO 2的吸附剂溶液，然后循环至用于解吸CO 2的再生区（有利地<100℃）。在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

2. 发明申请

US20120061614A1 NON-AQUEOUS AMINE SCRUBBING FOR REMOVAL OF CARBON DIOXIDE 有权
标题翻译：用于去除二氧化碳的非水性氨洗涤剂
公开(公告)号：US20120061614A1
公开(公告)日：2012-03-15
申请号：US13228652
申请日：2011-09-09
申请人： David C. Calabro , Lisa S. Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis G. Peiffer , Quanchang Li
发明人： David C. Calabro , Lisa S. Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis G. Peiffer , Quanchang Li
IPC分类号： B01D53/62 , C09K3/00
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.
摘要翻译：描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子溶剂在足以吸附至少一些CO 2的条件下进行。然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富含CO 2的吸附剂溶液，然后循环至用于解吸CO 2的再生区（有利地<100℃）。在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

3. 发明申请

US20160038872A1 NON-AQUEOUS AMINE SCRUBBING FOR REMOVAL OF CARBON DIOXIDE 有权
标题翻译：用于去除二氧化碳的非水性氨洗涤剂
公开(公告)号：US20160038872A1
公开(公告)日：2016-02-11
申请号：US14885214
申请日：2015-10-16
申请人： David Charles CALABRO , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
发明人： David Charles CALABRO , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
IPC分类号： B01D53/14
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.
摘要翻译：描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子溶剂在足以吸附至少一些CO 2的条件下进行。然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富CO 2的吸附溶液，然后循环至用于解吸CO 2的再生区（有利地<100℃）。在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

4. 发明授权

US09713788B2 Non-aqueous amine scrubbing for removal of carbon dioxide 有权
公开(公告)号：US09713788B2
公开(公告)日：2017-07-25
申请号：US14885214
申请日：2015-10-16
申请人： David Charles Calabro , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
发明人： David Charles Calabro , Lisa Saunders Baugh , Pavel Kortunov , Benjamin A. McCool , Michael Siskin , Dennis George Peiffer , Quanchang Li
IPC分类号： C07C215/18 , C07C215/12 , C07C215/14 , C07C211/14 , B01D53/14 , B01D53/62
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.

5. 发明授权

US08845886B2 Functionalized filters for heavy oil upgrading 有权
标题翻译：用于重油升级的功能化过滤器
公开(公告)号：US08845886B2
公开(公告)日：2014-09-30
申请号：US13472832
申请日：2012-05-16
申请人： David C. Calabro , Dennis G. Peiffer , Benjamin A. McCool , Stanley E. Jakubowicz
发明人： David C. Calabro , Dennis G. Peiffer , Benjamin A. McCool , Stanley E. Jakubowicz
IPC分类号： C10G31/09 , B01D39/00 , B01D39/14 , B01D39/20 , C08L79/08 , C08G73/10
CPC分类号： C08L79/08 , B01D39/2068 , C08G73/1082 , C08K3/22 , C10G31/09 , C10G2300/1033 , C10G2300/208
摘要： This invention relates to a process for separating a hydrocarbon stream via a filtration process to produce an upgraded permeate stream with decreased Conradson Carbon Residue (“CCR”) content. The invention involves the modification of a porous ceramic filter by functionalizing the surface of the ceramic filter with an multi-ring aromatic-diimide polymer. Preferably, the multi-ring aromatic-diimide polymer is comprised of a multi-ring aromatic monomer component. The functionalized filters of the present invention can be used in a process to selectively separate components of a hydrocarbon stream to produce an improved permeate (or “filtrate”) product stream with a lower CCR content and improved processing capabilities. The functionalized filters of the present invention are particularly beneficial in filtration processes for upgrading heavy hydrocarbon feedstreams, such as whole crudes, topped crudes, synthetic crude blends, shale oils, oils derived from bitumens, oils derived from tar sands, atmospheric resids, vacuum resids, or other heavy hydrocarbon streams.
摘要翻译：本发明涉及通过过滤方法分离烃流以产生具有降低的康拉多森碳残余物（“CCR”）含量的升级的渗透物流的方法。本发明涉及通过用多环芳族 - 二酰亚胺聚合物官能化陶瓷过滤器的表面来改性多孔陶瓷过滤器。优选地，多环芳族 - 二酰亚胺聚合物由多环芳族单体组分组成。本发明的官能化过滤器可用于选择性地分离烃流的组分以产生具有较低CCR含量和改进的处理能力的改进的渗透物（或“滤液”）产物流的方法。本发明的官能化过滤器特别有益于用于改质重烃原料流的过滤方法，例如整个原油，顶部原油，合成粗混合物，页岩油，来自沥青的油，源自沥青砂的油，常压渣油，真空渣油，或其他重质烃流。

6. 发明授权

US10456747B2 Hydrocarbon reverse osmosis membranes and separations 有权
公开(公告)号：US10456747B2
公开(公告)日：2019-10-29
申请号：US15347978
申请日：2016-11-10
申请人： Benjamin A. McCool , Harry W. Deckman , Ryan P. Lively , Dong-Yeun Koh
发明人： Benjamin A. McCool , Harry W. Deckman , Ryan P. Lively , Dong-Yeun Koh
IPC分类号： B01D61/02 , C07C15/08 , C02F1/44 , C07C7/00 , B01D61/00 , B01D69/12 , B01D71/02 , B01D53/22 , B01D67/00 , B01D69/08 , C07C5/27 , C07C7/14 , C07C7/144 , C02F103/08
摘要： Asymmetric membrane structures are provided that are suitable for various types of separations, such as separations by reverse osmosis. Methods for making an asymmetric membrane structure are also provided. The membrane structure can include at least one polymer layer. Pyrolysis can be used to convert the polymer layer to a porous carbon structure with a higher ratio of carbon to hydrogen.

7. 发明申请

US20110217218A1 Systems and Methods for Acid Gas Removal 审中-公开
标题翻译：酸性气体去除系统与方法
公开(公告)号：US20110217218A1
公开(公告)日：2011-09-08
申请号：US13030576
申请日：2011-02-18
申请人： Ramesh Gupta , Krishnan Sankaranarayanan , Himanshu Gupta , Benjamin A. McCool , Robert B. Fedich , Richard D. Lenz
发明人： Ramesh Gupta , Krishnan Sankaranarayanan , Himanshu Gupta , Benjamin A. McCool , Robert B. Fedich , Richard D. Lenz
IPC分类号： B01D53/62 , B01D53/52
CPC分类号： B01D53/1462 , B01D53/1406 , B01D53/1412 , B01D53/1437 , B01D53/18 , B01D53/261 , B01D2251/30 , B01D2251/40 , B01D2251/604 , B01D2251/606 , B01D2252/10 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20484 , B01D2252/20489 , B01D2253/104 , B01D2253/106 , B01D2253/116 , B01D2256/24 , B01D2257/80 , B01D2258/0283 , B01D2258/06 , Y02C10/04 , Y02C10/06
摘要： A method and system for the selective removal of CO2 and/or H2S from a gaseous stream containing one or more acid gases. In particular, a system and method for separating CO2 and/or H2S from a gas mixture containing an acid gas using an absorbent solution and one or more ejector venturi nozzles in flow communication with one or more absorbent contactors. The method involves contacting a gas mixture containing at least one acid gas with the absorbent solution under conditions sufficient to cause absorption of at least a portion of said acid gas. The absorbent contactors operate in co-current flow and are arranged in a counter-current configuration to increase the driving force for mass transfer. Monoliths can be used that operate in a Taylor flow or slug flow regime. The absorbent solution is treated under conditions sufficient to cause desorption of at least a portion of the acid gas.
摘要翻译：一种用于从含有一种或多种酸性气体的气流中选择性地除去CO 2和/或H 2 S的方法和系统。特别是一种用于使用吸收剂溶液和一个或多个喷射文丘里管喷嘴与含有酸性气体的气体混合物分离CO 2和/或H 2 S的系统和方法，其与一个或多个吸收接触器流动连通。该方法包括在足以引起至少一部分所述酸性气体吸收的条件下使含有至少一种酸性气体的气体混合物与吸收剂溶液接触。吸收接触器以并流流动运行，并且以逆流配置布置以增加用于传质的驱动力。可以使用以泰勒流或团状流动状态运行的单片。吸收剂溶液在足以使至少一部分酸性气体解吸的条件下进行处理。

8. 发明授权

US08119006B2 Ethanol stable epoxy amine based membrane for aromatics separation 有权
标题翻译：乙醇稳定的环氧胺基膜用于芳烃分离
公开(公告)号：US08119006B2
公开(公告)日：2012-02-21
申请号：US12583487
申请日：2009-08-21
申请人： Abhimanyu O. Patil , Timothy D. Shaffer , David T. Ferrughelli , Beth A. Winsett , Benjamin A. McCool , Randall D. Partridge
发明人： Abhimanyu O. Patil , Timothy D. Shaffer , David T. Ferrughelli , Beth A. Winsett , Benjamin A. McCool , Randall D. Partridge
IPC分类号： B01D61/36 , B01D71/52 , B01D71/46 , B01D71/00 , B01D61/00
CPC分类号： C10G31/11 , B01D61/246 , B01D61/362 , B01D69/02 , B01D71/52 , B01D71/60 , B01D71/80 , B01D2325/20 , B01D2325/30 , C10G2300/104 , C10G2300/1044 , C10G2400/02 , C10G2400/30
摘要： The present invention is directed to a membrane for aromatics separation that is stable in an alcohol containing environment. The polymeric membrane is a epoxy amine based membrane.
摘要翻译：本发明涉及一种在含醇环境中稳定的芳烃分离膜。聚合物膜是基于环氧胺的膜。

9. 发明申请

US20100108605A1 Ethanol stable polyether imide membrane for aromatics separation 审中-公开
标题翻译：乙醇稳定的聚醚酰亚胺膜用于芳烃分离
公开(公告)号：US20100108605A1
公开(公告)日：2010-05-06
申请号：US12589676
申请日：2009-10-27
申请人： Abhimanyu O. Patil , Timothy D. Shaffer , Satish Bodige , David C. Dalrymple , Benjamin A. McCool , Randall D. Partridge
发明人： Abhimanyu O. Patil , Timothy D. Shaffer , Satish Bodige , David C. Dalrymple , Benjamin A. McCool , Randall D. Partridge
IPC分类号： B01D61/02 , B01D61/36
CPC分类号： B01D71/64 , B01D61/362 , B01D71/80
摘要： The present invention relates to a polymeric aromatic selective membrane comprising an cross linked polyether imide membrane that comprise the reaction of a polyether amine with an dianhydride, and that may be utilized in a process for selectively separating aromatics from a hydrocarbon feedstream comprised of aromatic and aliphatic hydrocarbons and at least one alcohol, typically ethanol.
摘要翻译：本发明涉及包含交联聚醚酰亚胺膜的聚合物芳族选择性膜，其包括聚醚胺与二酐的反应，并且可用于选择性地将芳烃与芳烃和脂族烃组成的烃进料流分离的方法烃和至少一种醇，通常为乙醇。

10. 发明申请

US20100059441A1 Ethanol stable epoxy amine based membrane for aromatics separation 有权
标题翻译：乙醇稳定的环氧胺基膜用于芳烃分离
公开(公告)号：US20100059441A1
公开(公告)日：2010-03-11
申请号：US12583487
申请日：2009-08-21
申请人： Abhimanyu O. Pattil , Timothy D. Shaffer , David T. Ferrughelli , Beth A. Winsett , Benjamin A. McCool , Randall D. Partridge
发明人： Abhimanyu O. Pattil , Timothy D. Shaffer , David T. Ferrughelli , Beth A. Winsett , Benjamin A. McCool , Randall D. Partridge
IPC分类号： B01D61/02 , B01D61/08 , B01D61/36
CPC分类号： C10G31/11 , B01D61/246 , B01D61/362 , B01D69/02 , B01D71/52 , B01D71/60 , B01D71/80 , B01D2325/20 , B01D2325/30 , C10G2300/104 , C10G2300/1044 , C10G2400/02 , C10G2400/30
摘要： The present invention is directed to a membrane for aromatics separation that is stable in an alcohol containing environment. The polymeric membrane is a epoxy amine based membrane.
摘要翻译：本发明涉及一种在含醇环境中稳定的芳烃分离膜。聚合物膜是基于环氧胺的膜。

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