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1. 发明授权

US06248264B1 Neutral coloring photochromic 2H-naphtho[1,2-b] pyrans and heterocyclic pyrans 有权
标题翻译：中性着色光致变色2H-萘并[1,2-b]吡喃和杂环吡喃
公开(公告)号：US06248264B1
公开(公告)日：2001-06-19
申请号：US09381809
申请日：1999-11-01
申请人： David A. Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
发明人： David A. Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
IPC分类号： G02B523
CPC分类号： C07D491/04 , C07D311/92 , C07D495/04
摘要： Compositions comprising a naphtho [1,2-b]pyran of formula (I): wherein R7 and/or R9 is hydrogen or an amino group provided that R7 and R9 are not both hydrogen, and the other substituents are as defined in the specifcation.
摘要翻译：包含式（I）的萘并[1,2-b]吡喃的组合物：其中R 7和/或R 9为氢或氨基，条件是R 7和R 9不同时为氢，其它取代基如本说明书中所定义。

2. 发明授权

US06303673B1 Photochromic compounds 失效
标题翻译：光致变色化合物
公开(公告)号：US06303673B1
公开(公告)日：2001-10-16
申请号：US09529704
申请日：2000-06-19
申请人： David A. Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
发明人： David A. Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
IPC分类号： C07D49810
CPC分类号： C07D295/135 , C07C251/44 , G03C1/685
摘要： A photochromic compound has the formula (I) wherein R1 is selected from the group including substituted amino aryl moieties, substituted cyclic amino aryl moieties and substituted N-indolinoaryl or N-tetrahydroquinolino aryl groups, R3 is selected from the group including linear or branched C1-C20 alkyl, linear or branched C2-C20 alkenyl or polyalkenyl, C2-C20 alkynyl or polyalkynyl, aryl, heteroaryl, linear or branched C1-C20 alkyl aryl, linear or branched C1-C20 alkyl-cycloalkyl or -bicycloalkyl or -tricycloalkyl or substituted -cycloalkyl or -bicycloalkyl or -tricycloalkyl, linear or branched C1-C20 haloalkyl or perhaloalkyl, linear or branched C1-C20 alkoxyalkyl or peralkoxyalkyl, linear or branched C1-C20 alkylthioalkyl or peralkylthioalkyl, linear or branched C1-C20 amino alkyl or peraminoalkyl, C3-C20 cycloalkyl or substituted cycloalkyl, C4-C20 bicycloalkyl or substituted bicycloalkyl, C6-C20 tricycloalkyl or substituted tricycloalkl or linear or branched C1-C20 hydroxyalkyl or perhydroxyalkyl; R4 and R5 which may be the same or different are R3 or R4 and R5 are conjoined to form a spiro linked C3-C20 cyclic system or substituted cyclic system; and wherein R2 and R6 are each selected from R3 or hydrogen, halogen, nitro, nitroso, amino, acetamido, C2-C10 N-alkylamido, alkoxycarbonyl, nitrile, carboxy, hydroxy, aryloxy, C1-C10 alkoxy, a heteroatom which is O or N or S or P which in turn can be bonded either singly or multiply to carbon, oxygen, sulphur or nitrogen, C1-C5 alkoxy or alkylthio or aryl or aryloxy or multiples thereof.
摘要翻译：光致变色化合物具有式（I），其中R 1选自包括取代的氨基芳基部分，取代的环氨基芳基部分和取代的N-二吲哚酰基芳基或N-四氢喹啉基芳基，R3选自直链或支链C1 -C 20烷基，直链或支链C 2 -C 20烯基或聚烯基，C 2 -C 20炔基或多炔基，芳基，杂芳基，直链或支链C 1 -C 20烷基芳基，直链或支链C 1 -C 20烷基 - 环烷基或 - 双环烷基或 - 三环烷基或直链或支链C 1 -C 20卤代烷基或全卤代烷基，直链或支链C 1 -C 20烷氧基烷基或全烷氧基烷基，直链或支链C 1 -C 20烷硫基烷基或全烷硫基烷基，直链或支链C 1 -C 20氨基烷基或全氨基烷基 C 3 -C 20环烷基或取代的环烷基，C 4 -C 20双环烷基或取代的双环烷基，C 6 -C 20三环烷基或取代的三环烷基或直链或支链的C 1 -C 20羟基烷基或全羟基烷基; 可以相同或不同的R 4和R 5是R 3或R 4和R 5结合形成螺连接的C 3 -C 20环状体系或取代的环状体系; 并且其中R 2和R 6各自选自R 3或氢，卤素，硝基，亚硝基，氨基，乙酰氨基，C 2 -C 10 N-烷基酰氨基，烷氧基羰基，腈，羧基，羟基，芳氧基，C 1 -C 10烷氧基，或N或S或P，其又可以单独或多重与碳，氧，硫或氮键合，C 1 -C 5烷氧基或烷硫基或芳基或芳氧基或其多个重复键。

3. 发明授权

US06294112B1 Red coloring hyperchromic 3H-naphtho[2,1-B]pyrans 失效
标题翻译：红色着色超色3H-萘并[2,1-B]吡喃
公开(公告)号：US06294112B1
公开(公告)日：2001-09-25
申请号：US09402355
申请日：1999-12-16
申请人： David A. Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
发明人： David A. Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
IPC分类号： G02B523
CPC分类号： C07D405/10 , C07D311/92
摘要： Red coloring hyperchromic compounds have the formula: where R1 is H, NR2R3, OR4, SR4 or R7 wherein R2 and R3 are alkyl or carbocyclic groups or together with the nitrogen to which they are attached form a heterocyclic ring; R4 is the same as R1 or is alkyl, perhaloallyl, aryl or heteroaryl; R7 is alkyl, haloalkyl, alkylthio, aryl, arylthio, heteroaryl, halogen, nitrile, carboxylate, ester, nitro, or a carbocyclic or heterocyclic ring fused to faces f, gh, i, j or k; and R5 is a cyclic aminoaryl group, an indolinoaryl group, a tricyclic nitrogen heterocycle, or an unsaturated cyclic aminoaryl group.
摘要翻译：红色着色增色化合物具有下式：其中R 1是H，NR 2 R 3，OR 4，SR 4或R 7，其中R 2和R 3是烷基或碳环基或与它们所连接的氮一起形成杂环; R4与R1相同或为烷基，全卤代烯丙基，芳基或杂芳基; R 7为与f，gh，i，j或k面融合的烷基，卤代烷基，烷硫基，芳基，芳硫基，杂芳基，卤素，腈，羧酸酯，酯，硝基或碳环或杂环; 并且R 5是环状氨基芳基，二氢吲哚基，三环氮杂环或不饱和环氨基芳基。

4. 发明授权

US06387512B1 Grey coloring photochromic fused pyrans 失效
标题翻译：灰色着色光致变色融合pyrans
公开(公告)号：US06387512B1
公开(公告)日：2002-05-14
申请号：US09787362
申请日：2001-03-16
申请人： David Allan Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
发明人： David Allan Clarke , Bernard Mark Heron , Christopher David Gabbutt , John David Hepworth , Steven Michael Partington , Stephen Nigel Corns
IPC分类号： C07D31182
CPC分类号： C07D491/04 , C07D311/78 , C07D311/92 , C07D493/04 , C07D495/04 , Y10S428/913 , Y10T428/31855
摘要： A photochromic grey coloring 2H-naphtho[1,2-b]pyran of formula (1) wherein R1 is selected from mono-, di- or poly-substituted aryl groups, mono-, di- or poly-substituted naphthyl groups and mono-, di- or poly-substituted heteroaryl groups, wherein at least one substituent is a nitrogen containing group, including amino, C1-C20 and C6-C20 alkylamino, C1-C20 and C6-C20 dialkylamino, C2-C20 dialkenylamino, C2-C20 or C4-C20 di(polyalkenyl)amino, arylamino, diarylamino, C1-C20 alkylarylamino, tetra (C1-C10 linear or branched alkyl) guanidino and cyclic-amino groups and at least one of R7 and R9, which may be the same or different, is selected from C1-C20 N alkylamino C1-C20 N-alkylamido, C1-C20 N,N-dialkylamido, amido, nitro, amino, C1-C20 alkylamino, C1-C20 dialkylamino, C2-C20 dialkenylamino, C4-C20 di(polyalkenyl)amino, arylamino, diarylamino, C1-C20 alkylarylamino, or cyclicamino groups. The compounds may be combined with a polymeric host material such as plastic or glass to make a sunglass lens, an ophthalmic lens or a window. The compounds may also be included in an ink or a fuel.
摘要翻译：式（1）的光致变色灰色着色2H-萘并[1,2-b]吡喃，其中R1选自单取代，二取代或多取代的芳基，单取代，二取代或多取代的萘基和单其中至少一个取代基是含氮基团，包括氨基，C 1 -C 20和C 6 -C 20烷基氨基，C 1 -C 20和C 6 -C 20二烷基氨基，C 2 -C 20二烯基氨基，C 2 -C 20烷基氨基， C20或C4-C20二（聚链烯基）氨基，芳基氨基，二芳基氨基，C1-C20烷基芳基氨基，四（C1-C10直链或支链烷基）胍基和环氨基以及R7和R9中至少一个可以相同选自C 1 -C 20 N烷基氨基C 1 -C 20 N-烷基酰氨基，C 1 -C 20 N，N-二烷基酰氨基，酰氨基，硝基，氨基，C 1 -C 20烷基氨基，C 1 -C 20二烷基氨基，C 2 -C 20二烯基氨基， C20二（多烯基）氨基，芳基氨基，二芳基氨基，C 1 -C 20烷基芳基氨基或环氨基。化合物可以与诸如塑料或玻璃的聚合物主体材料组合以制备太阳镜，眼镜或窗。化合物也可以包括在油墨或燃料中。

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