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    • 9. 发明授权
    • Size press coating method
    • 尺寸压力涂布法
    • US5800870A
    • 1998-09-01
    • US811130
    • 1997-03-03
    • Gary LuebkeEdward P. Pauley
    • Gary LuebkeEdward P. Pauley
    • D21H19/10D21H19/12D21H19/20D21H19/22D21H19/54D21H19/58D21H19/82D21H23/32B05D7/04D21F7/00
    • D21H19/54D21H19/12D21H19/20D21H19/58D21H19/82D21H23/32
    • The invention provides an improved method of coating mediumweight and heavyweight papers in a size press by applying a paper coating composition comprising a binder wherein the binder comprises a stable aqueous dispersion comprising a water insoluble component and a water soluble component such that the water insoluble component comprises coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size less than 1 micron; and the water soluble component comprises a water soluble polymer capable of inhibiting coalescence of said polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of said polymer particles; and wherein said water insoluble component comprises greater that 3% and less than 75% by weight of the binder solids and said water soluble component comprises greater than 25% and less than about 97% of said solids.
    • 本发明提供了一种通过应用包含粘合剂的纸张涂料组合物在施胶机中涂布中等重量和重磅纸的改进方法,其中粘合剂包含包含水不溶性组分和水溶性组分的稳定的水分散体,使得水不溶性组分包含 可聚结聚合物颗粒,其Tg小于55℃,其中大部分具有小于1微米的粒度; 并且所述水溶性成分包含能够抑制所述聚合物颗粒的聚结的水溶性聚合物,或水溶性聚合物和能够抑制所述聚合物颗粒聚结的成分; 并且其中所述水不溶性组分包含大于粘合剂固体重量的3%和小于75%,并且所述水溶性组分包含大于25%且小于约97%的所述固体。
    • 10. 发明授权
    • Starch copolymer products and process
    • 淀粉共聚物产品及工艺
    • US6040379A
    • 2000-03-21
    • US133625
    • 1998-08-13
    • Gary LuebkeKenneth Curtis BentonYakov A. Letuchy
    • Gary LuebkeKenneth Curtis BentonYakov A. Letuchy
    • C08B31/00C08F251/00C08L3/04
    • C08B31/00C08F251/00
    • The invention provides methods for the preparation of a starch copolymer product which is the reaction product of starch and one or more synthetic monomers capable of undergoing free radical polymerization wherein the reaction product is in the form of an emulsion or dispersion having weight-average particle sizes less than 180 nm as measured by Capillary Hydrodynamic Fractionation. The method includes the steps of: (a) dissolving or colloidally dispersing starch in an aqueous solvent to form a starch solution or dispersion; (b) heating the starch solution or dispersion to a specified temperature range; (c) adding to the starch solution or dispersion a first portion of the synthetic monomer and a free radical initiator for initiation of polymerization of the starch member and the synthetic monomer; and (d) after free radical polymerization of the synthetic monomers has been initiated in the presence of the starch, adding additional portions of synthetic monomers capable of undergoing free radical polymerization to the starch solution or dispersion. The invention also provides improved methods for the preparation of starch copolymer products utilizing wet adhesion monomers and improved industrial and architectural coatings containing the resulting starch copolymer products.
    • 本发明提供了制备淀粉共聚物产物的方法,淀粉共聚物产物是能够进行自由基聚合的淀粉和一种或多种合成单体的反应产物,其中反应产物是具有重均粒径的乳液或分散体的形式 通过毛细管流体动力学分级测量小于180nm。 该方法包括以下步骤:(a)将淀粉溶解或胶体分散在水性溶剂中以形成淀粉溶液或分散体; (b)将淀粉溶液或分散体加热至规定的温度范围; (c)向淀粉溶液或分散体中加入合成单体的第一部分和用于引发淀粉组分和合成单体聚合的自由基引发剂; 和(d)在淀粉存在下开始合成单体的自由基聚合之后,向淀粉溶液或分散体中加入另外部分能够进行自由基聚合的合成单体。 本发明还提供了使用湿粘合单体和改进的含有所得淀粉共聚物产物的工业和建筑涂料来制备淀粉共聚物产物的改进方法。