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1. 发明授权

US06187512B1 Process for halomethylation of high performance polymers 失效
标题翻译：高性能聚合物的卤甲基化方法
公开(公告)号：US06187512B1
公开(公告)日：2001-02-13
申请号：US09313501
申请日：1999-05-17
申请人： Daniel A. Foucher , Nancy C. Stoffel , Roger T. Janezic , Thomas W. Smith , David J. Luca , Bidan Zhang
发明人： Daniel A. Foucher , Nancy C. Stoffel , Roger T. Janezic , Thomas W. Smith , David J. Luca , Bidan Zhang
IPC分类号： G03C556
CPC分类号： C08G65/48 , C08G61/12 , G03F7/038
摘要： Disclosed is a process which comprises reacting a polymer of the general formula wherein x is an integer of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, with a halomethyl alkyl ether, an acetyl halide, and methanol in the presence of a halogen-containing Lewis acid catalyst, thereby forming a halomethylated polymer.
摘要翻译：公开了一种方法，该方法包括使通式化合物的聚合物反应，x为0或1的整数，A为若干指定基团之一，例如B为若干指定基团之一，例如其混合物，n为代表在含卤素的路易斯酸催化剂的存在下，用卤代甲基烷基醚，乙酰卤和甲醇重复单体单元的数目，从而形成卤代甲基化的聚合物。

2. 发明授权

US6020119A Process for halomethylation of high performance polymers 失效
标题翻译：高性能聚合物的卤甲基化方法
公开(公告)号：US6020119A
公开(公告)日：2000-02-01
申请号：US312720
申请日：1999-05-17
申请人： Daniel A. Foucher , Nancy C. Stoffel , Roger T. Janezic , Thomas W. Smith , David J. Luca , Bidan Zhang
发明人： Daniel A. Foucher , Nancy C. Stoffel , Roger T. Janezic , Thomas W. Smith , David J. Luca , Bidan Zhang
IPC分类号： C08G61/12 , C08G65/48 , G03F7/038 , G03C1/005 , C08G8/02 , H01R43/00
CPC分类号： C08G65/48 , C08G61/12 , G03F7/038 , Y10T29/49401
摘要： Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## or ##STR2## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR3## B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, with a halomethylethyl ether, a hydrohalic acid, and acetic acid in the presence of a halogen-containing Lewis acid catalyst, thereby forming a halomethylated polymer.
摘要翻译：公开了一种方法，其包括使通式为的聚合物或其中x为0或1的整数，A是若干指定基团之一，例如B是若干指定基团之一，例如其混合物，n 是在含卤素的路易斯酸催化剂存在下，代表卤代甲基乙基醚，氢卤酸和乙酸的重复单体单元的数目的整数，从而形成卤代甲基化的聚合物。

3. 发明授权

US06906118B2 Phase change ink compositions 失效
标题翻译：相变油墨组合物
公开(公告)号：US06906118B2
公开(公告)日：2005-06-14
申请号：US09948958
申请日：2001-09-07
申请人： H. Bruce Goodbrand , Thomas W. Smith , Daniel A. Foucher , Kathleen M. McGrane , Dina Popovic
发明人： H. Bruce Goodbrand , Thomas W. Smith , Daniel A. Foucher , Kathleen M. McGrane , Dina Popovic
IPC分类号： C09D11/00 , C09D11/02 , C09D11/10
CPC分类号： C09D11/34
摘要： Disclosed is a phase change ink composition comprising a colorant and an ink vehicle, the ink being a solid at temperatures less than about 50° C. and exhibiting a viscosity of no more than about 20 centipoise at a jetting temperature of no more than about 160° C., wherein at a first temperature hydrogen bonds of sufficient strength exist between the ink vehicle molecules so that the ink vehicle forms hydrogen-bonded dimers, oligomers, or polymers, and wherein at a second temperature which is higher than the first temperature the hydrogen bonds between the ink vehicle molecules are sufficiently broken that fewer hydrogen-bonded dimers, oligomers, or polymers are present in the ink at the second temperature than are present in the ink at the first temperature, so that the viscosity of the ink at the second temperature is lower than the viscosity of the ink at the first temperature.
摘要翻译：公开了一种相变油墨组合物，其包含着色剂和油墨载体，所述油墨在低于约50℃的温度下为固体，并且在不超过约160℃的喷射温度下显示不超过约20厘泊的粘度 ℃，其中在第一温度下，在油墨载体分子之间存在足够强度的氢键，使得油墨载体形成氢键二聚体，低聚物或聚合物，并且其中在高于第一温度的第二温度下油墨载体分子之间的氢键被充分破坏，在第二温度下墨中存在较少的氢键二聚体，低聚物或聚合物比在第一温度下存在于墨中的氢键，使得在第二温度低于第一温度下墨水的粘度。

4. 发明授权

US06871945B2 Ink jet printing process 失效
标题翻译：喷墨打印过程
公开(公告)号：US06871945B2
公开(公告)日：2005-03-29
申请号：US10354258
申请日：2003-01-29
申请人： Thomas W. Smith , Kathleen M. McGrane , David J. Luca , William W. Limburg
发明人： Thomas W. Smith , Kathleen M. McGrane , David J. Luca , William W. Limburg
IPC分类号： B41J2/01 , B41J2/14 , B41J2/155 , B41J2/175 , B41J2/21 , B41M5/00 , C09D11/00 , B41J2/17
CPC分类号： B41M7/0018 , B41J2/14008 , B41J2/155 , B41J2/17523 , B41J2/2114 , B41J2202/20 , B41M5/0023
摘要： A process comprising incorporating into an ink jet printing apparatus a developing composition; an oxidizing composition a coloring composition; and a fixing composition; ejecting droplets of the developing composition onto the substrate; ejecting droplets of the oxidizing composition onto the substrate; ejecting droplets of the coloring composition onto the substrate; and ejecting droplets of the fixing composition onto the substrate; wherein the process results in at least some portions of the substrate bearing images comprising all four compositions, the portions forming a printed image. Specific embodiments are directed to the realization of continuous tone and gray scale in image by control of the time at which color forming reactions are quenched by controlling the lime period between deposition of the color forming liquids and deposition of the fixing liquid; or control of the extent of color forming reactions by limitation of the quantity of one of the color forming liquids.
摘要翻译：一种方法，包括将喷墨打印设备结合到显影组合物中; 氧化组合物，着色组合物; 和定影组合物; 将显影组合物的液滴喷射到基底上; 将氧化组合物的液滴喷射到基底上; 将着色组合物的液滴喷射到基底上; 并将定影组合物的液滴喷射到基底上; 其中所述工艺导致所述基材的至少一些部分承载包含所有四种组合物的图像，所述部分形成印刷图像。具体实施方案涉及通过控制成色反应淬灭的时间，通过控制成色液体的沉积和沉积定影液之间的石灰周期来实现图像中的连续色调和灰度级; 或通过限制一种成色液体的量来控制着色反应的程度。

5. 发明授权

US06547380B2 Ink jet printing process 有权
标题翻译：喷墨打印过程
公开(公告)号：US06547380B2
公开(公告)日：2003-04-15
申请号：US09911111
申请日：2001-07-23
申请人： Thomas W. Smith , Kathleen M. McGrane , David J. Luca , William W. Limburg
发明人： Thomas W. Smith , Kathleen M. McGrane , David J. Luca , William W. Limburg
IPC分类号： B41J217
CPC分类号： B41M7/0018 , B41J2/14008 , B41J2/155 , B41J2/17523 , B41J2/2114 , B41J2202/20 , B41M5/0023
摘要： A process comprising (a) incorporating into an ink jet printing apparatus (1) a developing composition comprising a liquid vehicle and a color developer; (2) an oxidizing composition comprising a liquid vehicle and an oxidizing agent; (3) a coloring composition comprising a liquid vehicle and a dye coupler; and (4) a fixing composition comprising a liquid vehicle and a fixative; (b) causing droplets of the developing composition to be ejected in an imagewise pattern onto the substrate; (c) causing droplets of the oxidizing composition to be ejected in an imagewise pattern onto the substrate; (d) causing droplets of the coloring composition to be ejected in an imagewise pattern onto the substrate; and (e) causing droplets of the fixing composition to be ejected in an imagewise pattern onto the substrate; wherein the process results in at least some portions of the substrate bearing images comprising all four of the developing composition, the oxidizing composition, the coloring composition, and the fixing composition, said portions forming a printed image. Specific embodiments of the present invention are directed to the realization of continuous tone and gray scale in images by (1) control of the time at which color forming reactions are quenched by controlling the time period between deposition of the color forming liquids and deposition of the fixing liquid; (2) control of the extent of color forming reactions by limitation of the quantity of one of the color forming liquids; or (3) control of pixel size by drop placement control over the overlap areas of drops of color forming liquids.
摘要翻译：一种方法，包括（a）将包含液体载体和彩色显影剂的显影组合物结合到喷墨打印设备（1）中; （2）包含液体载体和氧化剂的氧化组合物; （3）包含液体载体和染料偶合剂的着色组合物; 和（4）包含液体载体和固定剂的定影组合物; （b）使显影组合物的液滴以成像图案喷射到基材上; （c）使氧化组合物的液滴以成像图案喷射到基材上; （d）使着色组合物的液滴以成像图案喷射到基材上; 和（e）使定影组合物的液滴以成像图案喷射到基底上; 其中所述工艺导致所述基材的至少部分部分具有包含显影组合物全部四种，氧化组合物，着色组合物和定影组合物的图像，所述部分形成印刷图像。本发明的具体实施方案涉及通过以下方式实现图像中的连续色调和灰度级：（1）通过控制成色液体的沉积和沉积成色液体之间的时间来控制成色反应淬火的时间固定液体（2）通过限制一种成色液体的量来控制成色反应的程度; 或（3）通过在成色液滴的重叠区域上的放置位置控制来控制像素尺寸。

6. 发明授权

US6142618A System for depositing image enhancing fluid and ink jet printing process employing said system 失效
标题翻译：使用所述系统的用于沉积图像增强液体和喷墨印刷方法的系统
公开(公告)号：US6142618A
公开(公告)日：2000-11-07
申请号：US69110
申请日：1998-04-29
申请人： Thomas W. Smith , Samuel Kaplan , Kathleen M. McGrane , David J. Luca , John S. Facci , Michael J. Levy
发明人： Thomas W. Smith , Samuel Kaplan , Kathleen M. McGrane , David J. Luca , John S. Facci , Michael J. Levy
IPC分类号： B41J2/175 , B41J2/21
CPC分类号： B41J2/17513 , B41J2/2114
摘要： Disclosed is a fluid deposition apparatus comprising (a) a fluid supply, (b) a porous fluid distribution member in operative connection with the fluid supply, enabling wetting of the fluid distribution member with a fluid, and (c) a porous metering membrane situated on the fluid distribution member, whereby the metering membrane enables uniform metering of the fluid from the fluid distribution member onto a substrate.
摘要翻译：公开了一种流体沉积设备，包括（a）流体供应，（b）与流体供应器可操作地连接的多孔流体分配构件，使得可以用流体润湿流体分配构件，以及（c）位于在流体分配构件上，由此计量膜能够使流体从流体分配构件均匀地计量到基底上。

7. 发明授权

US6022095A Curable compositions 有权
标题翻译：可固化组合物
公开(公告)号：US6022095A
公开(公告)日：2000-02-08
申请号：US221024
申请日：1998-12-23
申请人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
发明人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
IPC分类号： B41J2/16 , C08F2/46 , C08F299/02 , C08L71/00 , C08L71/08 , C08L81/06 , G03F7/038 , H01L21/027 , B41J2/015 , B41J2/04 , G01D15/18 , G03C1/72
CPC分类号： B41J2/1628 , B41J2/1604 , B41J2/1623 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , G03F7/038 , G03F7/0388 , Y10S522/904 , Y10S522/905
摘要： Disclosed is an improved composition comprising a photopatternable polymer containing at least some monomer repeat units with photosensitivity-imparting substituents, said photopatternable polymer being of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer and a thermal ink jet printhead containing therein a layer of a crosslinked or chain extended polymer of the above formula.
摘要翻译：公开了一种改进的组合物，其包含含有至少一些具有赋予光敏性的取代基的单体重复单元的光图案化聚合物，所述光致图案化聚合物具有以下通式：其中x为0或1的整数，A为若干指定基团之一，例如 B是若干指定基团之一，例如其混合物，n为代表重复单体单元数的整数。还公开了一种用上述聚合物和热喷墨打印头制备具有上述式的交联或链延长聚合物层的热喷墨打印头的方法。

8. 发明授权

US6124372A High performance polymer compositions having photosensitivity-imparting substituents and thermal sensitivity-imparting substituents 失效
标题翻译：具有赋予感光性的取代基和赋予热敏感性的取代基的高性能聚合物组合物
公开(公告)号：US6124372A
公开(公告)日：2000-09-26
申请号：US705488
申请日：1996-08-29
申请人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
发明人： Thomas W. Smith , Timothy J. Fuller , Ram S. Narang , David J. Luca
IPC分类号： B41J2/14 , C08F2/46 , C08F2/50 , C08L101/02 , G03F7/038 , H01L21/027 , B41J2/015 , G03F7/004
CPC分类号： B41J2/14032 , B41J2/14129 , G03F7/038 , G03F7/0388 , B41J2202/03 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a composition comprising a polymer with a weight average molecular weight of from about 1,000 to about 100,000, said polymer containing at least some monomer repeat units with a first, photosensitivity-imparting substituent which enables crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer also containing a second, thermal sensitivity-imparting substituent which enables further crosslinking or chain extension of the polymer upon exposure to temperatures of about 140.degree. C. and higher, wherein the first substituent is not the same as the second substituent, said polymer being selected from the group consisting of polysulfones, polyphenylenes, polyether sulfones, polyimides, polyamide imides, polyarylene ethers, polyphenylene sulfides, polyarylene ether ketones, phenoxy resins, polycarbonates, polyether imides, polyquinoxalines, polyquinolines, polybenzimidazoles, polybenzoxazoles, polybenzothiazoles, polyoxadiazoles, copolymers thereof, and mixtures thereof.
摘要翻译：公开了一种组合物，其包含重均分子量为约1,000至约100,000的聚合物，所述聚合物含有至少一些单体重复单元，其具有第一，赋予光敏性的取代基，其能够在暴露于聚合物时交联或延伸聚合物所述聚合物还含有第二个赋予热敏感度的第二取代基，其在暴露于约140℃以上的温度下能够进一步交联或链延伸聚合物，其中第一取代基与第二取代基不相同所述聚合物选自聚砜，聚苯醚，聚醚砜，聚酰亚胺，聚酰胺酰亚胺，聚亚芳基醚，聚苯硫醚，聚芳醚酮，苯氧基树脂，聚碳酸酯，聚醚酰亚胺，聚喹喔啉，聚喹啉，聚苯并咪唑，聚苯并恶唑，聚苯并噻唑，聚唑，共聚物 reof，及其混合物。

9. 发明授权

US6087414A Process for direct substitution of high performance polymers with unsaturated ester groups 失效
标题翻译：用不饱和酯基直接取代高性能聚合物的方法
公开(公告)号：US6087414A
公开(公告)日：2000-07-11
申请号：US221278
申请日：1998-12-23
申请人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
发明人： Timothy J. Fuller , Ram S. Narang , Thomas W. Smith , David J. Luca , Raymond K. Crandall
IPC分类号： B41J2/16 , C08G65/40 , C08G65/48 , C08G75/23 , C08L71/00 , C08L71/10 , G03F7/038 , H01L21/027 , C08J3/28 , C08G65/38 , C08G73/06 , C08G85/00
CPC分类号： G03F7/038 , B41J2/1604 , B41J2/1623 , B41J2/1628 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , C08G65/4012 , C08G65/4018 , C08G65/48 , C08G75/23 , G03F7/0388 , C08G2650/20 , C08G2650/64 , C08L2312/00 , Y10S522/904 , Y10S522/905
摘要： Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3##
摘要翻译：公开了一种方法，其包括使通式为的聚合物其中x为0或1的整数，A为若干指定基团之一，例如B为若干指定基团之一，例如

10. 发明授权

US5994425A Curable compositions containing photosensitive high performance aromatic ether polymers 失效
标题翻译：含有光敏高性能芳香族醚聚合物的固化组合物
公开(公告)号：US5994425A
公开(公告)日：1999-11-30
申请号：US705375
申请日：1996-08-29
申请人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
发明人： Ram S. Narang , Timothy J. Fuller , Thomas W. Smith , David J. Luca , Ralph A. Mosher
IPC分类号： B41J2/16 , C08F2/46 , C08F299/02 , C08L71/00 , C08L71/08 , C08L81/06 , G03F7/038 , H01L21/027 , C08L63/00 , C08L71/12 , G03F7/004
CPC分类号： B41J2/1628 , B41J2/1604 , B41J2/1623 , B41J2/1629 , B41J2/1631 , B41J2/1632 , B41J2/1635 , B41J2/1642 , B41J2/1645 , G03F7/038 , G03F7/0388 , Y10S522/904 , Y10S522/905
摘要： Disclosed is an improved composition comprising a photopatternable polymer containing at least some monomer repeat units with photosensitivity-imparting substituents, said photopatternable polymer being of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer and a thermal ink jet printhead containing therein a layer of a crosslinked or chain extended polymer of the above formula.
摘要翻译：公开了一种改进的组合物，其包含含有至少一些具有赋予光敏性的取代基的单体重复单元的光图案化聚合物，所述光致图案化聚合物具有以下通式：其中x为0或1的整数，A为若干指定基团之一，例如 B是若干指定基团之一，例如其混合物，n为代表重复单体单元数的整数。还公开了一种用上述聚合物和热喷墨打印头制备具有上述式的交联或链延长聚合物层的热喷墨打印头的方法。

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