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    • 1. 发明专利
    • Decorative material
    • JP2004155208A
    • 2004-06-03
    • JP2004045645
    • 2004-02-23
    • Dainippon Printing Co Ltd大日本印刷株式会社
    • TAKEUCHI GENENDO KEISUKEKITAGAWA SHOICHI
    • B32B33/00B32B27/36C09D11/00C09D201/00
    • PROBLEM TO BE SOLVED: To provide a decorative material excellent in abrasion resistance due to an intermediate resin layer having specific dynamic viscoelasticity property (it has a peak of a loss elastic modulus below room temperature). SOLUTION: The decorative material D includes the intermediate resin layer 2 composed of a coating liquid or ink, and a surface protective layer 3 composed of a crosslinked resin on a substrate 1. The temperature dependence property of the loss elastic modulus E" (measuring frequency of 10 Hz) in a dynamic viscoelasticity method of the intermediate resin layer has a peak Pa at least below room temperature Tr, and also the intermediate resin layer is arranged so as to come in contact with the surface protective layer. Further, room temperature is temperatures having width defined as 10°C to 50°C. It is preferable that a value of a storage elastic modulus E' of the intermediate resin layer is in the range of 1 x 10 7 to 2 x 10 9 Pa at the region of room temperature. It is preferable that the loss elastic modulus E" has a peak Pb at temperatures above room temperature. Paper is typically used for the substrate. COPYRIGHT: (C)2004,JPO
    • 2. 发明专利
    • Optical sheet, surface light source device, and liquid crystal display device
    • 光学片,表面光源装置和液晶显示装置
    • JP2013072940A
    • 2013-04-22
    • JP2011210572
    • 2011-09-27
    • Dainippon Printing Co Ltd大日本印刷株式会社
    • MATSUHASHI TAKESHIUSHIYAMA AKINOBUENDO KEISUKE
    • G02B5/04B32B27/30F21S2/00F21Y101/00F21Y101/02F21Y103/00G02B5/02G02F1/13357
    • PROBLEM TO BE SOLVED: To provide an optical sheet having a superior restoration property and having a rugged structure hard to be damaged, a surface light source device including the same, and a liquid crystal display device.SOLUTION: The optical sheet includes: a transparent base material; and a rugged-shaped optical function expression part that is provided on one surface side of the transparent base material and has a plurality of unit rugged structures on a surface on the other side of the transparent base material. The optical function expression part is composed of a hardened material of an active energy ray curable resin including acrylate resin and/or methacrylic resin. When the surface of the optical function expression part is observed with an atomic force microscope, the optical sheet presents the projection structure with the average diameter of 0.1-2 μm and the average height of 1 nm-100 nm.
    • 解决的问题:为了提供具有优异的恢复性能并且具有难以损坏的坚固结构的光学片,包括该光学片的表面光源装置和液晶显示装置。 光学片包括:透明基材; 以及设置在透明基材的一个表面侧上并且在透明基材的另一侧的表面上具有多个单位粗糙结构的凹凸形状的光学功能表达部分。 光学功能表达部分由包含丙烯酸酯树脂和/或甲基丙烯酸树脂的活性能量射线固化树脂的硬化材料组成。 当用原子力显微镜观察光学功能表达部分的表面时,光学片呈现平均直径为0.1-2μm,平均高度为1nm-100nm的投影结构。 版权所有(C)2013,JPO&INPIT
    • 3. 发明专利
    • Prism sheet, surface light source device and liquid crystal display device
    • PRISM表,表面光源装置和液晶显示装置
    • JP2012047912A
    • 2012-03-08
    • JP2010188809
    • 2010-08-25
    • Dainippon Printing Co Ltd大日本印刷株式会社
    • ENDO KEISUKE
    • G02B5/02F21V5/00F21V5/02G02F1/13357
    • PROBLEM TO BE SOLVED: To provide a prism sheet, which has a ridge line with a height not constant in an extending direction thereof, which has excellent restorability such that even when a unit prism having an outer contour of a polygonal line is collapsed or deformed, the prism restores into the original shape, and which can suppress optical adhesion when the sheet is assembled in a liquid crystal display device.SOLUTION: The prism sheet comprises a main body and a prism part disposed on one surface of the main body, the prism part formed of a cured product of an active energy ray-curable resin composition and comprising a plurality of unit prisms with ridge lines thereof arranged parallel to one another. The height of the unit prism from the bottom to the ridge line is not constant along an extending direction of the ridge line, and when prism part is observed in a direction parallel to the arrangement direction of the unit prisms, each unit prism has an outer contour of a polygonal line giving recesses and projections. In the prism part, a tangent (tanδ=G"/G') defined as a ratio of a loss modulus (G") to a storage modulus (G') ranges from 0.02 to 0.5 at 25°C and a frequency of 10 Hz.
    • 解决的问题:为了提供一种具有在其延伸方向上不恒定的棱线的棱镜片,其具有优异的恢复性,使得即使当具有多边形线的外轮廓的单位棱镜是 折叠或变形时,棱镜恢复原来的形状,并且当将片组装在液晶显示装置中时可以抑制光学粘合。 解决方案:棱镜片包括主体和设置在主体的一个表面上的棱镜部分,棱镜部分由活性能量射线固化树脂组合物的固化产物形成,并且包括多个单位棱镜, 脊线彼此平行布置。 单元棱镜从底部到脊线的高度沿着脊线的延伸方向不是恒定的,并且当在与单位棱镜的排列方向平行的方向上观察棱镜部分时,每个单位棱镜具有外部 提供凹凸的折线的轮廓。 在棱镜部分中,定义为损耗模量(G“)与储能模量(G')的比的切线(tanδ= G”/ G')在25℃下为0.02至0.5,频率为10 赫兹。 版权所有(C)2012,JPO&INPIT
    • 4. 发明专利
    • DECORATIVE SHEET
    • JP2000103019A
    • 2000-04-11
    • JP27294498
    • 1998-09-28
    • DAINIPPON PRINTING CO LTD
    • ENDO KEISUKE
    • B32B27/18B32B27/32
    • PROBLEM TO BE SOLVED: To prevent an ultraviolet absorbent from bleeding out and thereby enhance the weatherability by forming a base material sheet of a polyolefin thermoplastic resin containing an ultraviolet absorbent with a hydroxyl group in a molecule and forming a primer layer of a resin containing an isocyanate. SOLUTION: A primer layer 13 and a surface protecting layer 14 are laminated on the surface of a base material sheet 11 in order that the surface of a wood base material, a metal base material and the like to be used as a base material for a building is coat-processed. In this base material sheet, the primer layer 13 made of a resin containing an isocyanate is formed on both faces of the base material sheet 11 manufactured of a polyolefin thermoplastic resin containing an ultraviolet absorbent 12 with a hydroxyl group in a molecule. In addition, the surface protecting layer 14 composed of a cured product of an ionizing radiation-curable resin, is formed on the surface of the base material sheet 11. Thus it is possible to obtain the base material sheet 11 which is highly weatherable and is protected against phenomena such as whitening even when the sheet 11 is exposed to ultraviolet rays for a long time. Further a pictorial pattern layer 15 is formed on the back face of the base material sheet 11.
    • 7. 发明专利
    • DECORATIVE MATERIAL WITH WEAR RESISTANCE
    • JP2000094625A
    • 2000-04-04
    • JP26923698
    • 1998-09-24
    • DAINIPPON PRINTING CO LTD
    • ENDO KEISUKE
    • B32B27/20B32B33/00
    • PROBLEM TO BE SOLVED: To hold followability to a folding, a hardness for particles and a strength against a wear itself by forming a structure of two layers in which a layer obtained by fixing fine particles with a crosslinkable resin is disposed at a lower side and a crosslinkable resin layer having higher flexibility than the previous layer is disposed at an upper side on a surface of a base material. SOLUTION: The decorative material 1 comprises a layer 6 formed of a binder 5 made of fine particles 4 and a crosslinkable resin on an overall surface of a base 2 having a pattern 3, and a layer 7 made of a crosslinkable resin having higher flexibility on the layer 6. As the base 2, any is usable if a material used for an ordinary decorative material is used. In the case of largely classifying, there are groups of various type sheets, a plastic film or sheet, a metal foil, a metal sheet or the like. No blushing or craze of a folding part occurs even by folding at 180 deg. with a coated surface disposed at an outside at an environmental temperature of 20 deg.C, and its wear resistance and folding suitability are sufficient.
    • 8. 发明专利
    • DECORATIVE MATERIAL
    • JP2000062126A
    • 2000-02-29
    • JP23057698
    • 1998-08-17
    • DAINIPPON PRINTING CO LTD
    • ENDO KEISUKE
    • B32B33/00
    • PROBLEM TO BE SOLVED: To enable aqueous wax to be applied smoothly during maintenance services by structuring a decorative material of a slip agent with such a nature as to adsorb moisture, added to the top face of a decorative material of a filmlike, a sheetlike or a platelike shape. SOLUTION: This decorative material is of such a constitution that a slip agent with such a nature as to adsorb moisture is added to the top face of a decorative material of a filmlike, a sheetlike or a platelike shape. The slip agent with such a nature as to adsorb moisture to be used is a polyether- modified silicone oil which has a dimethylsiloxane skeleton in which one methyl group is present or has polyether such as polyethyoxide or polypropylene oxide introduced into both terminals. Thus it is possible to prevent an aqueous wax from being repelled when the aqueous wax is applied and also prevent partial smears from being promoted or partial scratches from being easily inflicted because the aqueous wax is not applied, by using the slip agent.
    • 9. 发明专利
    • DECORATIVE SHEET
    • JP2000103018A
    • 2000-04-11
    • JP27288598
    • 1998-09-28
    • DAINIPPON PRINTING CO LTD
    • ENDO KEISUKE
    • B32B27/18B32B27/32
    • PROBLEM TO BE SOLVED: To improve weatherability and to improve adhesive strength between an ionized radiation-curable resin layer and a primer layer (the adhesive strength at the initial time and after exposure to ultraviolet light) by preventing an ultraviolet light absorber added in a polyolefin resin sheet from bleeding out. SOLUTION: A primer layer 13 consisting of a mixture of a two part curable urethane resin and a butyral resin is formed on both faces of a PO sheet 11 (a polyolefin resin sheet) contg. an ultraviolet light absorber with a hydroxyl group in the molecule and the surface of the PO sheet 11 is coated with an ionized radiation-curable resin and this is irradiated with ionized radiation to cure the ionized radiation-curable resin and to form a surface protective layer 14 and in addition, a picture pattern layer 15 is formed on the back by printing, etc., to prepare a decorative sheet 1.
    • 10. 发明专利
    • DECORATIVE MATERIAL AND ITS PRODUCTION
    • JP2000024589A
    • 2000-01-25
    • JP19385898
    • 1998-07-09
    • DAINIPPON PRINTING CO LTD
    • ENDO KEISUKE
    • B05D1/36B05D7/24B32B27/04B32B33/00
    • PROBLEM TO BE SOLVED: To enhance the bonding strength between a surface layer and a base material by impregnating a decorative base material with an ionizing radiation curable resin compsn. to semi-cure the impregnated base material and applying the ionizing radiation curable resin compsn. to this semi-cured base material to cure the same by the irradiation with ionizing radiation. SOLUTION: A decorative base material 1 having impregnation properties is impregnated with an ionizing radiation curable resin compsn. 4 to be cured and an ionizing radiation curable resin compsn. 5 is applied to the entire surface of the base material 1 and cured to provide a surface protective layer 3 and printing 2 is applied to the base material 1 by an ionizing radiation curable resin compsn. 6. As the decorative base material 1, various papers, nonwoven fabrics or fabrics can be adapted but even a plastic sheet can be adapted if it is porous or contains a large amt. of a filler. As the ionizing radiation curable resin compsns. 4-6, a compsn. prepared by appropriately mixing a prepolymer, an oligomer or the like having a polymerizable unsaturated bond or an epoxy group in a molecule thereof is used.