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    • 4. 发明公开
    • METHOD FOR PRODUCING AQUEOUS DISPERSION OF FLUORINE-CONTAINING SEED POLYMER PARTICLES, AQUEOUS COATING COMPOSITION, AND COATED ARTICLE
    • 用于生产氟的水分散液含种子聚合物颗粒,水性涂料组合物及涂覆制品
    • EP2407490A1
    • 2012-01-18
    • EP10750895.4
    • 2010-03-11
    • Daikin Industries, Ltd.
    • IMOTO, KatsuhikoNISHII, ShumiFUKUHARA, Yoshinari
    • C08F2/24C08F214/00C09D5/02C09D127/12C09D129/10
    • C08F214/18C08F14/18C08F214/186C09D5/02C09D127/12C09D127/16C08F2/16
    • There is provided a method for producing an aqueous dispersion of fluorine-containing seed polymer (B) particles, comprising a step for preparing an aqueous dispersion of fluorine-containing polymer (A) particles by polymerizing monomer comprising at least one fluoroolefin in an aqueous dispersion in the presence of a compound (1) represented by the formula: CH 2 =CHCH 2 -O-R, wherein R is a hydrocarbon group which may have an oxygen atom, a nitrogen atom and/or a polar group, and (II) a step for seed-polymerizing ethylenically unsaturated monomer with the fluorine-containing polymer (A) particles in the aqueous dispersion of the fluorine-containing polymer (A) particles. The production method is the method for producing an aqueous dispersion of fluorine-containing seed polymer particles and assures a low foamability and gives an excellent gloss of an obtained coating film and excellent adhesion to a substrate when the fluorine-containing seed polymer particles are used as a coating film forming component of a coating composition.
    • 提供了一种方法,用于在含氟种子聚合物(B)粒子的wässrige分散生产,包括:用于通过聚合单体在水性分散体,其包含至少一种氟代烯烃的制备向wässrige含氟聚合物的分散体(A)的颗粒的步骤 (II)CH 2 = CHCH 2 -OR,worin R是可以具有氧原子,氮原子和/或极性基团的烃基,和a:在化合物存在下(1)由下式表示 步骤,用于与含氟聚合物(A)中的含氟聚合物(A)粒子的wässrige分散颗粒种子聚合烯属不饱和单体。 该制造方法是在含氟种子聚合物颗粒的wässrige分散制备方法,并保证低的起泡性和给出了一个得到的涂膜和优良的粘合性的基材的优异的光泽。当含氟种子聚合物颗粒用作 涂料组合物的涂膜形成成分。
    • 8. 发明公开
    • METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER
    • 生产含氟聚合物的方法
    • EP2471825A1
    • 2012-07-04
    • EP10811906.6
    • 2010-08-25
    • Daikin Industries, Ltd.
    • IMOTO, KatsuhikoNISHII, ShumiFUKUHARA, Yoshinari
    • C08F2/24C08F214/18
    • C08F214/18C08F2/22C08F14/24C08F214/22C08F2220/286C08F2/24C08F2/26
    • An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH 2 =CR 1 -R 2 -O-(AO) p -X (in the formula, R 1 is hydrogen or an alkyl group; R 2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO 3 Y wherein Y is NH 4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.)
    • 本发明的目的在于提供一种使用具有表面活性剂能力的特定的非氟化合物来制造大量粒径小的粒子的含氟聚合物的制造方法。 含氟聚合物的制造方法包括在由式:CH 2 = CR 1 -R 2 -O-(AO)pX表示的化合物(1)存在下的包含至少一种氟烯烃的单体的水分散体聚合(式中,R 1 是氢或烷基; R 2是具有两个或更多个碳原子的亚烷基; AO是具有2至4个碳原子的直链或支链氧化烯基; p是正整数; X是H或SO 3 Y,其中Y是NH 4或 碱金属;和AO可以相同或不同,并且如果存在多于一个AO,则可以形成两个或更多个嵌段。)