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    • 1. 发明专利
    • Epoxidized thermoplastic polymers and processes for their production
    • 环氧化的热塑性聚合物及其生产方法
    • JP2007332389A
    • 2007-12-27
    • JP2007243378
    • 2007-09-20
    • Daicel Chem Ind Ltdダイセル化学工業株式会社
    • YABUI AKIHIROOTSUKA YOSHIHIRO
    • C08F8/08
    • PROBLEM TO BE SOLVED: To conquer the stickiness of epoxidized thermoplastic polymers and the troublesome handling by blocking nature or the like and to provide epoxidized thermoplastic polymers excellent in workability and processes for their production. SOLUTION: An epoxidized granular thermoplastic polymer comprises a shell-like surface layer insoluble in toluene at 25°C formed on the polymer. The process for the production of the epoxidized granular thermoplastic polymer comprises: the first step of epoxidizing a granular thermoplastic polymer in a water medium in the presence of an epoxidizing agent or the epoxidizing agent and a solvent for accelerating an epoxidation reaction and a phosphoric acid series compound; the second step of the washing with water, or the neutralization and washing with water of the epoxidized granular thermoplastic polymer; and the third step, if necessary, of removing the solvent for accelerating epoxidation reaction which may be used in the first step. COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:解决环氧化热塑性聚合物的粘性和通过阻断性质等麻烦的处理,并提供可加工性优异的环氧化热塑性聚合物及其制备方法。 解决方案:环氧化颗粒状热塑性聚合物包含在聚合物上形成的25℃不溶于甲苯的壳状表面层。 生产环氧化颗粒状热塑性聚合物的方法包括:在环氧化剂或环氧化剂和用于加速环氧化反应和磷酸系的溶剂的存在下,在水介质中环氧化粒状热塑性聚合物的第一步骤 复合; 用水洗涤的第二步骤,或环氧化颗粒状热塑性聚合物用水中和和洗涤; 如果需要,可以在第一步骤中除去用于加速环氧化反应的溶剂的第三步骤。 版权所有(C)2008,JPO&INPIT