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    • 10. 发明授权
    • Hydrogen sensing process
    • 氢感测过程
    • US06638416B2
    • 2003-10-28
    • US09961661
    • 2001-09-24
    • Da Yu WangDavid K. ChenKaius K. PolikarpusWalter T. Symons
    • Da Yu WangDavid K. ChenKaius K. PolikarpusWalter T. Symons
    • G01N27407
    • G01N27/4072G01N33/005
    • A hydrogen sensor and process for measuring hydrogen gas concentrations includes a pump cell and a measuring cell. The pump cell includes a first conducting electrolyte layer having a top and a bottom surface, and an electrode disposed on the top and bottom surfaces, wherein the top electrode is in communication with an unknown concentration of hydrogen gas. The measuring cell includes a second conducting electrolyte layer having a top and a bottom surface, and an electrode disposed on the top and bottom surfaces, wherein the bottom electrode is in communication with a reference gas source. A diffusion-limiting barrier is disposed between the pump cell bottom electrode and the measuring cell top electrode, wherein hydrogen diffusion through the diffusion-limiting barrier is controlled by a Knudsen diffusion mechanism at hydrogen concentrations greater than about 40%.
    • 氢传感器和用于测量氢气浓度的方法包括泵浦单元和测量单元。 泵电池包括具有顶表面和底表面的第一导电电解质层和设置在顶表面和底表面上的电极,其中顶电极与未知浓度的氢气连通。 测量单元包括具有顶表面和底表面的第二导电电解质层和设置在顶表面和底表面上的电极,其中底电极与参考气体源连通。 扩散限制屏障设置在泵电池底部电极和测量池顶部电极之间,其中通过扩散限制屏障的氢气扩散通过克氏扩散机构在大于约40%的氢浓度下控制。