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    • 4. 发明申请
    • RESIN COMPOSITION
    • 树脂组合物
    • WO2013083630A1
    • 2013-06-13
    • PCT/EP2012/074509
    • 2012-12-05
    • DSM IP ASSETS B.V.
    • JANSEN, Johan, Franz, Gradus, AntoniusHILKER, IrisHENSEN, Guido, Joseph, ElisabethSILVESTRE, DI, Silvana Rensina Antonnietta
    • C09F9/00C09D167/06C08G63/82
    • C08F283/01C08L67/06
    • This invention relates to an unsaturated polyester resin composition characterized in that the resin composition comprises a. An unsaturated polyester resin comprising fumaric, maleic and/or itaconic building blocks, b. At least one vinyl ester as reactive diluent, c. An iron complex and/or salt, and d. A ligand according to the following formula (1) wherein each R 1 , R 2 , R 3 and R 4 are independently selected from hydrogen, C1-C12 alkyl, C3-C8 cycloalkyl, C6-C12 aryl and C5-C12 heteroaryl; X is selected from C=0 and -[C(R) 2 ] Z - wherein z is from 1 to 3 and each R is independently selected from hydrogen, hydroxyl, C1-C4 alkoxy and C1-C4 alkyl; each Rx and Ry are independently selected from hydrogen, C1-C8 alkyl, (C1-C8)alkyl-0-(C1-C8)alkyl, (C1-C8)alkyl-O-(C6-C10)aryl, C6-C10-aryl, C1-C8-hydroxyalkyl, and (CH 2 ) n C(O)OR 5 wherein n is from 0 to 4 and R 5 is hydrogen, C1-C12 alkyl or an amide; Ra is a 2-pyridyl group or an alkylidene-2-pyridyl group; Rb is selected from C1-C24 alkyl, C6-C10 aryl and a group containing a heteroatom.
    • 本发明涉及一种不饱和聚酯树脂组合物,其特征在于该树脂组合物包含a。 包含富马酸,马来酸和/或衣康酸结构单元的不饱和聚酯树脂,b。 至少一种乙烯基酯作为反应性稀释剂,c。 铁复合物和/或盐,和d。 根据下式(1)的配体,其中每个R 1,R 2,R 3和R 4独立地选自氢,C 1 -C 12烷基,C 3 -C 8环烷基,C 6 -C 12芳基和C 5 -C 12杂芳基; X选自C = O和 - [C(R)2] Z-,其中z为1至3,并且每个R独立地选自氢,羟基,C 1 -C 4烷氧基和C 1 -C 4烷基; 每个Rx和Ry独立地选自氢,C1-C8烷基,(C1-C8)烷基-O-(C1-C8)烷基,(C1-C8)烷基-O-(C6-C10)芳基,C6-C10 芳基,C 1 -C 8羟基烷基和(CH 2)n C(O)OR 5,其中n为0至4,R 5为氢,C 1 -C 12烷基或酰胺; Ra是2-吡啶基或亚烷基-2-吡啶基; R b选自C 1 -C 24烷基,C 6 -C 10芳基和含杂原子的基团。
    • 6. 发明公开
    • RESIN COMPOSITION
    • 树脂组合物
    • EP2788443A1
    • 2014-10-15
    • EP12795002.0
    • 2012-12-05
    • DSM IP Assets B.V.
    • JANSEN, Johan, Franz, Gradus, AntoniusHILKER, IrisHENSEN, Guido, Joseph, ElisabethSILVESTRE, DI, Silvana Rensina Antonnietta
    • C09F9/00C09D167/06C08G63/82
    • C08F283/01C08L67/06
    • This invention relates to an unsaturated polyester resin composition characterized in that the resin composition comprises a. An unsaturated polyester resin comprising fumaric, maleic and/or itaconic building blocks, b. At least one vinyl ester as reactive diluent, c. An iron complex and/or salt, and d. A ligand according to the following formula (1) wherein each R
      1 , R
      2 , R
      3 and R
      4 are independently selected from hydrogen, C1-C12 alkyl, C3-C8 cycloalkyl, C6-C12 aryl and C5-C12 heteroaryl; X is selected from C=0 and -[C(R)
      2 ]
      Z - wherein z is from 1 to 3 and each R is independently selected from hydrogen, hydroxyl, C1-C4 alkoxy and C1-C4 alkyl; each Rx and Ry are independently selected from hydrogen, C1-C8 alkyl, (C1-C8)alkyl-0-(C1-C8)alkyl, (C1-C8)alkyl-O-(C6-C10)aryl, C6-C10-aryl, C1-C8-hydroxyalkyl, and (CH
      2 )
      n C(O)OR
      5 wherein n is from 0 to 4 and R
      5 is hydrogen, C1-C12 alkyl or an amide; Ra is a 2-pyridyl group or an alkylidene-2-pyridyl group; Rb is selected from C1-C24 alkyl, C6-C10 aryl and a group containing a heteroatom.
    • 本发明涉及一种不饱和聚酯树脂组合物,其特征在于该树脂组合物包含a。 包含富马酸,马来酸和/或衣康性结构单元的不饱和聚酯树脂,b。 至少一种乙烯基酯作为反应性稀释剂,c。 铁复合物和/或盐,和d。 根据下式(1)的配体,其中每个R 1,R 2,R 3和R 4独立地选自氢,C 1 -C 12烷基,C 3 -C 8环烷基,C 6 -C 12芳基和C 5 -C 12杂芳基; X选自C = O和 - [C(R)2] Z-,其中z为1至3并且每个R独立地选自氢,羟基,C 1 -C 4烷氧基和C 1 -C 4烷基; 每个Rx和Ry独立地选自氢,C1-C8烷基,(C1-C8)烷基-O-(C1-C8)烷基,(C1-C8)烷基-O-(C6-C10)芳基,C6-C10 - 芳基,C 1 -C 8 - 羟烷基和(CH 2)n C(O)OR 5,其中n为0-4,R 5为氢,C 1 -C 12烷基或酰胺; Ra是2-吡啶基或亚烷基-2-吡啶基; Rb选自C 1 -C 24烷基,C 6 -C 10芳基和含有杂原子的基团。