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1. 发明申请

WO2010040774A2 DESTRUCTION OF AMMONIUM IONS 审中-公开
标题翻译：破坏氨离子
公开(公告)号：WO2010040774A2
公开(公告)日：2010-04-15
申请号：PCT/EP2009/063023
申请日：2009-10-07
申请人： DSM IP ASSETS B.V. , OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , LOPEZ CRUZ, Carlos , RIESTHUIS, Theodorus Friederich Maria
发明人： OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , LOPEZ CRUZ, Carlos , RIESTHUIS, Theodorus Friederich Maria
IPC分类号： C01B21/02 , C01B21/14 , C07C249/08
CPC分类号： C01B21/02 , C01B21/1418
摘要： The invention relates to a process for converting ammonium formed in a hydroxylamine phosphate oxime process into molecular nitrogen in an ammonium destruction zone, comprising - preparing a vapour stream comprising nitrogen oxide from ammonia, in an ammonia combustion zone; - bringing into contact by feeding to the ammonium destruction zone, individually and/or as pre-mixed combinations, at least part of said vapour stream, and a first liquid stream, comprising ammonium formed in the hydroxylamine phosphate oxime process, and a second liquid stream, comprising at least one acid selected from nitric acid and nitrous acid in a total nitric+nitrous acid concentration of at least 30 wt. %, thereby forming in the ammonium destruction zone a fluid mixture; and - reacting ammonium ions in the fluid mixture with nitrogen oxide under formation of molecular nitrogen, in the ammonium destruction zone. The invention further relates to an installation for converting ammonium formed in a hydroxylamine phosphate oxime process.
摘要翻译：本发明涉及将铵磷酸酯肟工艺中形成的铵转化成铵破坏区中的分子氮的方法，包括：在氨燃烧区中由氨制备包含氮氧化物的蒸气流; - 通过单独地和/或作为预混合组合，至少部分所述蒸汽流进料至铵破坏区和包含在磷酸羟胺肟方法中形成的铵的第一液体流和第二液体流，包含至少一种选自硝酸和亚硝酸的酸，其总硝酸+亚硝酸浓度为至少30重量％。％，从而在铵破坏区中形成流体混合物; 并且在铵破坏区域中使铵离子与氮氧化物在分子氮形成时在流体混合物中反应。本发明还涉及一种用于转化在磷酸羟胺肟工艺中形成的铵的装置。

2. 发明申请

WO2013053377A1 HIGH TEMPERATURE LACTAM NEUTRALISATION 审中-公开
标题翻译：高温乳酸中和
公开(公告)号：WO2013053377A1
公开(公告)日：2013-04-18
申请号：PCT/EP2011/067650
申请日：2011-10-10
申请人： DSM IP ASSETS B.V. , OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
发明人： OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
IPC分类号： C07D201/04 , C07D201/16 , C07D223/10
CPC分类号： C07D201/16 , C07D201/04 , C07D223/10
摘要： The invention relates to a method for preparing a lactam in a continuous process, comprising forming the lactam and ammonium sulphate by contacting a lactam sulphate contained in an acidic liquid with ammonia, during which forming of lactam heat of reaction is generated, which heat is partially or fully recovered, wherein ammonia is brought into contact with the acidic liquid as part of a liquid aqueous ammonia solution, and wherein the contacting takes place at a temperature of at least 120 °C, and wherein the average residence time at a temperature of at least 120 °C is at most 15 minutes, and wherein the ammonium sulphate remains dissolved in a liquid phase during said residence time.
摘要翻译：本发明涉及一种在连续方法中制备内酰胺的方法，包括通过使酸性液体中含有的内酰胺硫酸与氨接触形成内酰胺和硫酸铵，在此期间产生反应的内酰胺热量，该热量部分地或完全回收，其中氨与液体氨水溶液的一部分与酸性液体接触，并且其中接触在至少120℃的温度下进行，并且其中在温度为至少120℃至多为15分钟，其中硫酸铵在所述停留时间期间保持溶于液相。

3. 发明申请

WO2012019674A3 HIGH TEMPERATURE LACTAM NEUTRALISATION 审中-公开
公开(公告)号：WO2012019674A3
公开(公告)日：2012-02-16
申请号：PCT/EP2011/003281
申请日：2011-07-01
申请人： DSM IP Assets B.V. , OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
发明人： OEVERING, Hendrik , GUIT, Rudolf Philippus Maria , BAUR, Henricus Anna Christiaan
IPC分类号： C07D201/16
摘要： The invention relates to a method for preparing a lactam in a continuous process, comprising forming the lactam and ammonium sulphate by contacting a lactam sulphate contained in an acidic liquid with ammonia, during which forming of lactam heat of reaction is generated, which heat is partially or fully recovered, wherein ammonia is brought into contact with the acidic liquid as part of a liquid aqueous ammonia solution, and wherein the contacting takes place at a temperature of at least 120 °C, and wherein the average residence time at a temperature of at least 120 °C is at most 15 minutes, and wherein the ammonium sulphate remains dissolved in a liquid phase during said residence time.

4. 发明申请

WO2011078668A1 THE PREPARATION OF CAPROLACTAM FROM 6-AMINO CAPROIC ACID OBTAINED IN A FERMENTATION PROCESS 审中-公开
标题翻译：在发酵过程中从6-AMINO大豆酸中制备捕获剂
公开(公告)号：WO2011078668A1
公开(公告)日：2011-06-30
申请号：PCT/NL2010/050878
申请日：2010-12-22
申请人： DSM IP Assets B.V. , GUIT, Rudolf Philippus Maria , VAN DER DOES, Thomas , RAAMSDONK, Lourina Madeleine
发明人： GUIT, Rudolf Philippus Maria , VAN DER DOES, Thomas , RAAMSDONK, Lourina Madeleine
IPC分类号： C07D201/08 , C07D223/10
CPC分类号： C07D201/08 , C07D201/16 , C07D223/10 , C08G69/16
摘要： The invention relates to a method for preparing caprolactam comprising recovering a mixture containing 6-aminocaproic acid, from a culture medium comprising biomass, and thereafter cyclising the 6-aminocaproic acid in the presence of superheated steam, thereby forming caprolactam, wherein the weight to weight ratio carbohydrate to 6-aminocaproic acid in said mixture is 0.03 or less.
摘要翻译：本发明涉及一种制备己内酰胺的方法，包括从含有生物质的培养基中回收含有6-氨基己酸的混合物，然后在过热蒸汽存在下环化6-氨基己酸，从而形成己内酰胺，其中重量所述混合物中碳水化合物与6-氨基己酸的比例为0.03以下。

5. 发明申请

WO2012143332A1 CATALYZED HYDROXYLAMINE PREPARATION 审中-公开
标题翻译：催化羟基胺的制备
公开(公告)号：WO2012143332A1
公开(公告)日：2012-10-26
申请号：PCT/EP2012/056925
申请日：2012-04-16
申请人： DSM IP Assets B.V. , GROOTHAERT, Marijke Hilde Leen , TINGE, Johan Thomas , GUIT, Rudolf Philippus Maria
发明人： GROOTHAERT, Marijke Hilde Leen , TINGE, Johan Thomas , GUIT, Rudolf Philippus Maria
IPC分类号： C01B21/14
CPC分类号： C01B21/1418 , B01J21/08 , B01J23/44 , B01J23/54
摘要： Method for preparing hydroxylamine in a continuous process, comprising hydrogenating nitrate in a reaction zone comprising a liquid phase, a gas phase and a heterogeneous hydrogenation catalyst, in which reaction zone hydroxylamine and nitrous oxide (N20) are formed, characterized in that the nitrous oxide concentration in the gas phase, is monitored and is maintained within a pre¬ determined range by means of controlled addition of a promoter for the heterogeneous hydrogenation catalyst and/or controlled addition of further amounts of heterogeneous hydrogenation catalyst to the reaction zone until the total amount of catalyst present reaches a pre-determined upper limit; and then (i) withdrawing a fraction of the heterogeneous hydrogenation catalyst from the reaction zone; and (ii) adding one or more further doses of heterogeneous hydrogenation catalyst until the total amount of catalyst present is at most at said pre-determined upper limit; and (iii) optionally repeating steps (i) and (ii); a method for producing an oxime and a method for producing a lactam comprising said process for producing hydroxylamine.
摘要翻译：在连续方法中制备羟胺的方法，包括在包含液相，气相和异相氢化催化剂的反应区中使硝酸盐氢化，其中反应区羟胺和一氧化二氮（N 2 O）形成，其特征在于一氧化二氮监测气相中的浓度，并通过控制加入非均相加氢催化剂的促进剂和/或向反应区域控制加入另外量的非均相氢化催化剂，将其保持在预定范围内，直到总量的催化剂存在达到预定的上限; 然后（i）从反应区抽出一部分异相氢化催化剂; 和（ii）加入一种或多种另外的非均相氢化催化剂剂量，直到催化剂的总量至多在所述预定的上限值为止; 和（iii）任选地重复步骤（i）和（ii）; 制备肟的方法和制备内酰胺的方法，包括所述羟胺的制备方法。

6. 发明申请

WO2010041943A2 METHOD FOR PREPARING ε-CAPROLACTAM FROM N-ACYL-6-AMINOCAPROIC ACID 审中-公开
标题翻译：从N-亚氨基-6-氨基己酸制备电子捕获物的方法
公开(公告)号：WO2010041943A2
公开(公告)日：2010-04-15
申请号：PCT/NL2009/050610
申请日：2009-10-09
申请人： DSM IP ASSETS B.V. , MINK, Daniel , GUIT, Rudolf Philippus Maria , MÜLLER, Monika , RAEMAKERS-FRANKEN, Petronella Catharina
发明人： MINK, Daniel , GUIT, Rudolf Philippus Maria , MÜLLER, Monika , RAEMAKERS-FRANKEN, Petronella Catharina
IPC分类号： C07D201/08 , C07D223/10 , C12P17/10
CPC分类号： C07D201/08 , C07D223/10 , C12P17/10
摘要： The invention relates to a method for preparing ε-caprolactam comprising deacylating N-acyl-6-aminocaproic acid and forming ε-caprolactam. The deacylation may be carried out chemically or biocatalytically. The invention further relates to a host cell, 5 comprising a recombinant vector comprising a nucleic acid sequence encoding an enzyme capable of catalysing the formation of 6-aminocaproic acid from N-acyl-6- aminocaproic acid.
摘要翻译：本发明涉及一种制备ε-己内酰胺的方法，其包括使N-酰基-6-氨基己酸脱酰并形成ε-己内酰胺。脱酰基化可以化学或生物催化进行。本发明还涉及宿主细胞，其包含重组载体，其包含编码能够从N-酰基-6-氨基己酸催化形成6-氨基己酸的酶的核酸序列。

7. 发明申请

WO2013098174A1 PROCESS FOR THE CONTINUOUS PREPARATION OF HYDROXYLAMINE 审中-公开
标题翻译：连续制备羟基胺的方法
公开(公告)号：WO2013098174A1
公开(公告)日：2013-07-04
申请号：PCT/EP2012/076289
申请日：2012-12-20
申请人： DSM IP ASSETS B.V.
发明人： TINGE, Johan Thomas , GUIT, Rudolf Philippus Maria , RIESTHUIS, Theodorus Friederich Maria
IPC分类号： C01B21/14 , B01J19/02
CPC分类号： C01B21/1418 , B01J19/02 , B01J2219/0286
摘要： A method for preparing hydroxylammonium in a reaction zone in a continuous process, comprising optionally directly introducing nitric acid comprising
摘要翻译：一种在连续方法中在反应区中制备羟基铵的方法，包括任选地将包含<0.1ppm Mo的硝酸直接引入反应区; 其中引入的硝酸被输送，储存，转移到容器和包含钢的管道中; 其中反应在容器和连接管的壁包括钢的容器中进行; 其中所述钢包含0至0.08重量％的C和0至0.03重量％的Mo。

8. 发明申请

WO2016135009A1 PROCESS FOR THE PREPARATION OF GAMMA VALEROLACTONE FROM LEVULINIC ACID 审中-公开
标题翻译：从精氨酸制备游离胆固醇酯的方法
公开(公告)号：WO2016135009A1
公开(公告)日：2016-09-01
申请号：PCT/EP2016/053267
申请日：2016-02-16
申请人： DSM IP ASSETS B.V.
发明人： GUIT, Rudolf Philippus Maria , VARELA FERNÁNDEZ, Alejandro
IPC分类号： C07D307/33
CPC分类号： C07D307/33
摘要： The invention relates to process for the preparation of gamma valerolactone (GVL) from levulinic acid (LA), said process comprising a) subjecting LA to a hydrogenation reaction comprising hydrogen and a solid catalyst system comprising a metal and a support in the liquid phase, to yield a first reaction mixture comprising GVL, hydroxypentanoic acid (4HPA), and water; b) removing water from said first reaction mixture; and c) subjecting the mixture obtained in step b) to a further reaction under conditions suitable to convert said 4-HPA to GVL, to yield a further reaction mixture. Steps b) and c) can be integrated. Optionally, water can be removed from the further reaction mixture. The process may include recycling the – optionally at least partially dewatered - further reaction mixture back to to step (b). This is particarly advantageous when the first reaction mixture is low in, or even free of levulinic acid. Alternatively, the further reaction mixture or at least partially dewatered further reaction mixture can be submitted to a distillation step, whereby the distillate can be collected to recover GVL.
摘要翻译：本发明涉及从乙酰丙酸（LA）制备γ-戊内酯（GVL）的方法，所述方法包括a）使LA进行包含氢的氢化反应和包含液相中的金属和载体的固体催化剂体系，得到包含GVL，羟基戊酸（4HPA）和水的第一反应混合物; b）从所述第一反应混合物中除去水; 和c）使步骤b）中获得的混合物在适于将所述4-HPA转化为GVL的条件下进一步反应，得到另外的反应混合物。步骤b）和c）可以集成。任选地，可以从另外的反应混合物中除去水。该方法可以包括将任选地至少部分脱水的另外的反应混合物再循环回到步骤（b）。当第一反应混合物低或甚至不含乙酰丙酸时，这是非常有利的。或者，进一步的反应混合物或至少部分脱水的另外的反应混合物可以进行蒸馏步骤，由此可以收集馏出物以回收GVL。

9. 发明公开

EP2334641A2 METHOD FOR PREPARING EPSILON-CAPROLACTAM FROM N-ACYL-6-AMINOCAPROIC ACID 审中-公开
标题翻译：用于生产ε-己内酰胺OFF N-酰基-6-氨基己
公开(公告)号：EP2334641A2
公开(公告)日：2011-06-22
申请号：EP09737180.1
申请日：2009-10-09
申请人： DSM IP Assets B.V.
发明人： MINK, Daniel , GUIT, Rudolf Philippus Maria , MÜLLER, Monika , RAEMAKERS-FRANKEN, Petronella Catharina
IPC分类号： C07D201/08 , C07D223/10 , C12P17/10 , C12P13/00 , C12N9/88
CPC分类号： C07D201/08 , C07D223/10 , C12P17/10
摘要： The invention relates to a method for preparing ε-caprolactam comprising deacylating N-acyl-6-aminocaproic acid and forming ε-caprolactam. The deacylation may be carried out chemically or biocatalytically. The invention further relates to a host cell, 5 comprising a recombinant vector comprising a nucleic acid sequence encoding an enzyme capable of catalysing the formation of 6-aminocaproic acid from N-acyl-6- aminocaproic acid.

10. 发明公开

EP3262032A1 PROCESS FOR THE PREPARATION OF GAMMA VALEROLACTONE FROM LEVULINIC ACID 无效
标题翻译：从乙酰丙酸制备γ-戊内酯的方法
公开(公告)号：EP3262032A1
公开(公告)日：2018-01-03
申请号：EP16705116.8
申请日：2016-02-16
申请人： DSM IP Assets B.V.
发明人： GUIT, Rudolf Philippus Maria , VARELA FERNÁNDEZ, Alejandro
IPC分类号： C07D307/33
CPC分类号： C07D307/33 , Y02P20/582
摘要： The invention relates to process for the preparation of gamma valerolactone (GVL) from levulinic acid (LA), said process comprising a) subjecting LA to a hydrogenation reaction comprising hydrogen and a solid catalyst system comprising a metal and a support in the liquid phase, to yield a first reaction mixture comprising GVL, hydroxypentanoic acid (4HPA), and water; b) removing water from said first reaction mixture; and c) subjecting the mixture obtained in step b) to a further reaction under conditions suitable to convert said 4-HPA to GVL, to yield a further reaction mixture. Steps b) and c) can be integrated. Optionally, water can be removed from the further reaction mixture. The process may include recycling the—optionally at least partially dewatered—further reaction mixture back to step (b). This is particularly advantageous when the first reaction mixture is low in, or even free of levulinic acid. Alternatively, the further reaction mixture or at least partially dewatered further reaction mixture can be submitted to a distillation step, whereby the distillate can be collected to recover GVL.

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