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    • 7. 发明申请
    • ORGANIC LIGHT EMITTING DIODE CONTAINING AMINIUM RADICAL CATION
    • 含有自由基阳离子的有机发光二极管
    • WO2018085056A1
    • 2018-05-11
    • PCT/US2017/057495
    • 2017-10-20
    • DOW GLOBAL TECHNOLOGIES LLC
    • GRIGG, Robert DavidSPENCER, Liam P.KRAMER, John W.DEVORE, David D.GOODFELLOW, BrianLIU, ChunMUKHOPADHYAY, SukritPETERSON, Thomas H.WOODWARD, William H. H.SOKOLOV, Anatoliy N.
    • H01L51/54
    • H01L51/5056H01L51/5088
    • Provided is an organic light-emitting diode comprising a substrate, an anode layer, optionally one or more hole injection layers, one or more hole transport layers, optionally one or more electron blocking layers, an emitting layer, optionally one or more hole blocking layers, optionally one or more electron transport layers, an electron injection layer, and a cathode, wherein either the hole injection layer, or the hole transport layer, or both of the hole injection layer and the hole transport layer, or a layer that functions as both a hole injection layer and a hole transport layer, comprises a polymer that comprises one or more triaryl aminium radical cations having the structure (S1 ) wherein each of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 is independently selected from the group consisting of hydrogen, deuterium halogens, amine groups, hydroxyl groups, sulfonate groups, nitro groups, and organic groups, wherein two or more of R 11 , R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 ; R 32 ; R 33 R 34 and R 35 are optionally connected to each other to form a ring structure; wherein one or more of R11, R 12 , R 13 , R 14 , R 15 , R 21 , R 22 , R 23 , R 24 , R 25 , R 31 , R 32 , R 33 , R 34 , and R 35 is covalently bound to the polymer, and wherein A" is an anion.
    • 提供了一种有机发光二极管,其包括衬底,阳极层,任选的一个或多个空穴注入层,一个或多个空穴传输层,任选的一个或多个电子阻挡层,发光层 ,任选的一个或多个空穴阻挡层,任选的一个或多个电子传输层,电子注入层和阴极,其中空穴注入层或空穴传输层或空穴注入层和空穴传输层 层或用作空穴注入层和空穴传输层两者的层包含聚合物,所述聚合物包含一种或多种具有结构(S1)的三芳基铵自由基阳离子,其中每个R 11, R 12,R 13,R 14,R 15,R 21, R 22,R 23,R 24,R 25,R 31, R 32,R 33,R 34和R 35独立地选自fr 在由氢,氘卤素,胺基,羟基,磺酸酯基,硝基和有机基团组成的组中,其中R 11,R 12和R 12中的两个或更多个是氢, ,R 13,R 14,R 15,R 21,R 22, ,R 23,R 24,R 25,R 31, [R 32 ; R 33,R 34和R 35任选彼此连接形成环结构; 其中R 11,R 12,R 13,R 14,R 15,R sup中的一个或多个 > 21,R 22,R 23,R 24,R 25,R sup > 31,R 32,R 33,R 34和R 35共价结合 到聚合物,并且其中A“ 是一个阴离子。