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1. 发明申请

WO2011056448A1 VINYL ETHER COMPOUNDS AND METHODS OF THEIR PREPARATION AND USE 审中-公开
标题翻译：乙烯化合物及其制备和使用方法
公开(公告)号：WO2011056448A1
公开(公告)日：2011-05-12
申请号：PCT/US2010/053535
申请日：2010-10-21
申请人： DOW GLOBAL TECHNOLOGIES LLC. , OBER, Matthias, S. , DAUGS, Edward, D. , YU, Wanglin , RAND, Cynthia, L.
发明人： OBER, Matthias, S. , DAUGS, Edward, D. , YU, Wanglin , RAND, Cynthia, L.
IPC分类号： C07C43/16 , C07C43/313 , C07C217/46 , C07D295/084 , C07C41/24
CPC分类号： C07D295/088 , C07C41/16 , C07C41/24 , C07C43/16 , C07C43/17 , C07C43/188 , C07C43/215 , C07C217/08 , C07C217/46 , C07C2602/42 , C07C43/192
摘要： Provided are new functionalized surfactants and methods of their preparation and use. The surfactants are compounds of formula I: wherein R 1 , R 2 , and R 3 are as defined herein.
摘要翻译：提供了新的官能化表面活性剂及其制备和使用方法。表面活性剂是式I化合物：其中R 1，R 2和R 3如本文所定义。

2. 发明申请

WO2009137282A1 PROCESS FOR OLEFIN ETHERIFICATION 审中-公开
标题翻译：烯烃加工方法
公开(公告)号：WO2009137282A1
公开(公告)日：2009-11-12
申请号：PCT/US2009/041747
申请日：2009-04-27
申请人： DOW GLOBAL TECHNOLOGIES INC. , DAUGS, Edward, D. , FLICK, Derrick, W. , RAND, Cynthia, L. , TULCHINSKY, Michael, L. , YU, Wanglin
发明人： DAUGS, Edward, D. , FLICK, Derrick, W. , RAND, Cynthia, L. , TULCHINSKY, Michael, L. , YU, Wanglin
IPC分类号： C07C41/06 , C07C43/12
CPC分类号： C07C41/06 , C07C41/42 , Y02P20/127 , C07C43/12
摘要： The invention relates to processes for the etherification of olefins with alcohols. According to one aspect, a heterogeneous etherification catalyst is used under conditions that permit limiting the contact time between the desired product and the catalyst, thereby mitigation reverse reactions. According to a second aspect, a recycling process is used that significantly increases the yield of desired product.
摘要翻译：本发明涉及烯烃与醇醚化的方法。根据一个方面，在允许限制所需产物和催化剂之间的接触时间的条件下使用异相醚化催化剂，从而减轻逆向反应。根据第二方面，使用显着增加所需产物的产率的再循环方法。

3. 发明申请

WO2011008570A2 SULFONATE SURFACTANTS AND METHODS OF PREPARATION AND USE 审中-公开
标题翻译：磺化表面活性剂及其制备和使用方法
公开(公告)号：WO2011008570A2
公开(公告)日：2011-01-20
申请号：PCT/US2010/040570
申请日：2010-06-30
申请人： DOW GLOBAL TECHNOLOGIES, INC. , YU, Wanglin , RAND, Cynthia, L. , DAUGS, Edward, D. , CHENG, Yang , GRAF, Irina, V. , ARGENTON, Andre, B. , PHILLIPSON, Kari, S.
发明人： YU, Wanglin , RAND, Cynthia, L. , DAUGS, Edward, D. , CHENG, Yang , GRAF, Irina, V. , ARGENTON, Andre, B. , PHILLIPSON, Kari, S.
IPC分类号： C07C309/10
CPC分类号： C07C309/10 , C08F2/26 , C09K8/035 , C09K8/584 , C11D1/143
摘要： Provided are new anionic surfactants and methods of their preparation and use. The surfactants are compounds of the formula I: wherein R, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are as defined herein.
摘要翻译：提供了新的阴离子表面活性剂及其制备和使用方法。表面活性剂是式I化合物：其中R，R 1，R 2，R 3，R 4，R 5和R 6如本文所定义。

4. 发明申请

WO2013062679A1 SURFACTANTS DERIVED FROM OLIGOLYCEROLS 审中-公开
标题翻译：来自低聚糖的表面活性剂
公开(公告)号：WO2013062679A1
公开(公告)日：2013-05-02
申请号：PCT/US2012/054639
申请日：2012-09-11
申请人： DOW GLOBAL TECHNOLOGIES LLC , TULCHINSKY, Michael, L. , YU, Wanglin , NG, Sze Sze , RAND, Cynthia, L.
发明人： TULCHINSKY, Michael, L. , YU, Wanglin , NG, Sze Sze , RAND, Cynthia, L.
IPC分类号： C11D1/72
CPC分类号： C11D7/263 , C11D1/72 , C11D7/06 , C11D7/3218
摘要： Provided is a surfactant composition comprising an oligoglycerol compound of formula I, wherein R and m are as defined above. The compounds exhibit favorable surfactancy properties. Advantageously, the compounds may be prepared from renewable materials.
摘要翻译：提供了包含式I的低聚甘油化合物的表面活性剂组合物，其中R和m如上所定义。该化合物表现出有利的表面活性。有利地，化合物可以由可再生材料制备。

5. 发明申请

WO2012005899A1 COMPATIBLE MIXTURES OF ANIONIC AND CATIONIC SURFACTANTS 审中-公开
标题翻译：阴离子和阳离子表面活性剂的兼容混合物
公开(公告)号：WO2012005899A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/040428
申请日：2011-06-15
申请人： DOW GLOBAL TECHNOLOGIES LLC , WU, Yongfu , RAND, Cynthia, L. , YU, Wanglin , GRAF, Irina, V.
发明人： WU, Yongfu , RAND, Cynthia, L. , YU, Wanglin , GRAF, Irina, V.
IPC分类号： C11D1/65 , B01F17/00 , A61K8/00 , C09D7/00 , C09K8/584 , D06M13/256 , D06M13/46
CPC分类号： C11D1/65 , A61K8/416 , A61K8/466 , A61K2800/596 , A61Q19/10 , C09D5/027 , C09D7/63 , C09K2208/00 , C11D1/143 , C11D1/62 , D06M13/256 , D21H17/03 , D21H17/72
摘要： Provided are compositions containing a compatible mixture of a cationic surfactant and an anionic surfactant. A composition according to the invention comprises: (a) a first surfactant of formula (I) wherein R, R 1 , R 2 , and R 3 Y, X, and n are as defined below; (b) a second surfactant that is oppositely charged to the first surfactant. R is linear or branched C 2 -C 22 alkyl; R 1 , R 2 , and R 3 are independently H or linear or branched C 1 -C 18 alkyl; Y is SO 3 - or N + R 4 R 5 R 6 ; R 4 , R 5 , and R 6 are independently C 1 -C 4 alkyl. aryl-C 1 -C 4 alkyl, or R 4 and R 5 , together with the nitrogen to which they are attached, form a ring containing 3-9 carbon atoms; X is a monovalent or divalent ion; n is an integer such that the total ionic charge provided by X n is 2.
摘要翻译：提供含有阳离子表面活性剂和阴离子表面活性剂的相容混合物的组合物。根据本发明的组合物包含：（a）式（I）的第一表面活性剂，其中R，R 1，R 2和R 3 Y，X和n如下所定义; （b）与第一表面活性剂相反地加入的第二表面活性剂。 R是直链或支链C 2 -C 22烷基; R 1，R 2和R 3独立地为H或直链或支链C 1 -C 18烷基; Y是SO 3 - 或N + R 4 R 5 R 6; R4，R5和R6独立地是C1-C4烷基。芳基-C 1 -C 4烷基或R 4和R 5与它们所连接的氮一起形成含有3-9个碳原子的环; X是一价或二价离子; n是使由Xn提供的总离子电荷为2的整数。

6. 发明申请

WO2005110986A1 HYDROFORMYLATION PROCESS FOR PHARMACEUTICAL INTERMEDIATE 审中-公开
标题翻译：药物中间体的水解过程
公开(公告)号：WO2005110986A1
公开(公告)日：2005-11-24
申请号：PCT/US2005/014349
申请日：2005-04-26
申请人： DOW GLOBAL TECHNOLOGIES INC. , DAUGS, Edward, D. , PENG, Wei-Jun , RAND, Cynthia, L.
发明人： DAUGS, Edward, D. , PENG, Wei-Jun , RAND, Cynthia, L.
IPC分类号： C07D209/48
CPC分类号： C07D401/06 , C07D209/48 , C07D471/04
摘要： The invention relates to an improved process for the preparation of an advanced synthetic intermediate of ACE inhibitors. In one aspect, the present invention is based on a novel process for the preparation of an aldehyde of formula (I), wherein (N) PrG is a protected amino group, R is an alkyl or aralkyl group and X 1-4 are each independently H or a non-reacting substituent, which comprises hydroformylation of an α-olefin of formula (II), by reaction with syngas (CO/H 2 ) in the presence of, as catalyst, a group VIII transition metal complex of a phosphorus-containing ligand. Aldehyde (I), the product of linear hydroformylation, is formed in preference to aldehyde (III). In another aspect of the invention, α-olefin (II) is a novel composition. The process to convert (II) to (I) enables an efficient manufacturing route to MDL 28,726 and analogues.
摘要翻译：本发明涉及用于制备ACE抑制剂的高级合成中间体的改进方法。一方面，本发明是基于制备式（I）的醛的新方法，其中（N）PrG是被保护的氨基，R是烷基或芳烷基，X <1-4> 各自独立地是H或非反应性取代基，其包括式（II）的α-烯烃的羰基化，通过在作为催化剂的催化剂存在下与合成气（CO / H 2）反应的第VIII族过渡金属络合物含磷配体。醛（I）是线性加氢甲酰化的产物，优选醛（III）。在本发明的另一方面，α-烯烃（II）是一种新的组合物。将（II）转化为（I）的过程能够实现MDL 28,726和类似物的有效制造路线。

7. 发明申请

WO2007084545A1 PROCESS FOR MAKING AMINO ACIDS 审中-公开
标题翻译：制备氨基酸的方法
公开(公告)号：WO2007084545A1
公开(公告)日：2007-07-26
申请号：PCT/US2007/001207
申请日：2007-01-17
申请人： DOW GLOBAL TECHNOLOGIES INC. , LLOYD, Michael, C. , DAUGS, Edward, D. , RAND, Cynthia, L. , PENG, Wei-jun
发明人： LLOYD, Michael, C. , DAUGS, Edward, D. , RAND, Cynthia, L. , PENG, Wei-jun
IPC分类号： C07C227/32 , C07D317/30 , C12P41/00
CPC分类号： C07C227/32 , C07D317/30 , C12P13/04 , C12P41/006
摘要： A process for making an amino acid by the steps of: (a) contacting a compound of formula I with a hydroformylation catalyst and synthesis gas to produce a mixture of aldehyde compounds comprising the formulas IIa, IIb and IIc; (b) reacting the mixture of aldehyde compounds from step (a) to produce a mixture of derivative compounds comprising a masked amino acid derivative which may be selected from the group consisting of amino nitrile, N-acyl amino acid, amino amide, hydantoin and amino ester; (c) contacting the mixture of derivative compounds from step (b) with an enantioselective hydrolase enzyme in the presence of water to produce an L-amino acid having the formula IV; (d) isolating the amino acid having the formula IV in substantially pure form, wherein in formulas I, IIa, IIb, IIc, IIIa, IIIb, IIIc and IV, R is H, alkyl or aryl and R 1 and R 2 are the same or different alkyl groups and wherein R 1 and R 2 may be fused.
摘要翻译：通过以下步骤制备氨基酸的方法：（a）使式I化合物与加氢甲酰化催化剂和合成气接触以产生包含式IIa，IIb和IIc的醛化合物的混合物; （b）使来自步骤（a）的醛化合物的混合物反应以产生包含可以选自氨基腈，N-酰基氨基酸，氨基酰胺，乙内酰脲和氨基酯; （c）在水存在下将来自步骤（b）的衍生化合物的混合物与对映选择性水解酶接触以产生具有式IV的L-氨基酸; （d）以基本上纯的形式分离具有式IV的氨基酸，其中在式I，IIa，IIb，IIc，IIIa，IIIb，IIIc和IV中，R是H，烷基或芳基，R 1， SO 2和R 2是相同或不同的烷基，其中R 1和R 2和R 2可以是稠合的。

8. 发明申请

WO2013024363A1 BIORENEWABLE BIODEGRADABLE SURFACTANTS 审中-公开
标题翻译：可生物降解的表面活性剂
公开(公告)号：WO2013024363A1
公开(公告)日：2013-02-21
申请号：PCT/IB2012/002120
申请日：2012-08-16
申请人： DOW GLOBAL TECHNOLOGIES LLC , BAILEY, Brad, C. , NG, Sze-Sze , PIERRE, Cynthia , RAND, Cynthia, L.
发明人： BAILEY, Brad, C. , NG, Sze-Sze , PIERRE, Cynthia , RAND, Cynthia, L.
IPC分类号： C07C69/753 , C07D209/58 , C11D1/74
CPC分类号： C08G65/48 , C07C69/753 , C07C2603/26 , C07D209/58 , C08G65/14 , C08G65/2612 , C08G65/33396 , C11D1/526 , C11D1/74
摘要： Disclosed are compounds of formula (I) and salts, hydrates, or solvates thereof, where R 1 and R 2 are defined herein, compositions containing these compounds, and methods of using these compounds in a variety of applications, such as a surfactant or performance additive.
摘要翻译：公开了式（I）化合物及其盐，水合物或溶剂化物，其中R 1和R 2在本文中定义，含有这些化合物的组合物，以及在各种应用中使用这些化合物的方法，例如表面活性剂或性能添加剂。

9. 发明申请

WO2011156208A3 ETHER POLYSULFIDES AND POLYETHER POLYSULFIDES, THEIR PREPARATION AND USE 审中-公开
公开(公告)号：WO2011156208A3
公开(公告)日：2011-12-15
申请号：PCT/US2011/038981
申请日：2011-06-03
申请人： DOW GLOBAL TECHNOLOGIES LLC , CHENG, Yang , RAND, Cynthia, L. , CUTHBERT, John, B.
发明人： CHENG, Yang , RAND, Cynthia, L. , CUTHBERT, John, B.
IPC分类号： C08G65/08 , C08G65/326 , C08G65/334 , C10M107/00
摘要： Novel sulfur-containing compositions comprise a polyether polysulfide or an ether polysulfide. The polyether polysulfide may be based upon an alkoxylate (an alcohol or glycol-initiated compound) that is a copolymer of at least two of ethylene oxide, propylene oxide and butylene oxide. The polyether polysulfide may alternatively be based upon a homopolymer of ethylene oxide, propylene oxide or butylene oxide. The ether polysulfide may be based upon a methoxy-capped poly glycol or an alkyl ether of 1,3-dichloro-2-propanol.

10. 发明申请

WO2012177415A1 ENERGY EFFICIENT POLYALKYLENE GLYCOLS AND LUBRICANT COMPOSITION CONTAINING SAME 审中-公开
标题翻译：能量有效的聚亚烷基甘油和含有其的润滑剂组合物
公开(公告)号：WO2012177415A1
公开(公告)日：2012-12-27
申请号：PCT/US2012/041449
申请日：2012-06-08
申请人： DOW GLOBAL TECHNOLOGIES LLC , GREAVES, Martin, R. , VAN VOORST, Ronald , RAND, Cynthia, L. , MEERTENS, Marinus , VINCI, Daniele
发明人： GREAVES, Martin, R. , VAN VOORST, Ronald , RAND, Cynthia, L. , MEERTENS, Marinus , VINCI, Daniele
IPC分类号： C10M107/34 , C10N30/02 , C08G65/04
CPC分类号： C10M169/042 , C08G65/2606 , C08G2650/24 , C10M107/34 , C10M2209/1033 , C10M2209/1045 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2230/06 , C10N2230/66 , C10M2209/1055 , C10M2209/1065
摘要： A polyalkylene glycol comprising: a random copolymer comprising units derived from EO and units derived from PO initiated with polytetrahydrofuran; wherein the polyalkylene glycol has a pour point of less than or equal to -30°C as measured using ASTM D97 and a traction value of less than 0.0165 at a contact pressure of 1.25 GPa, speed = 2 m/s, SRR of 100% and temperature of 80 °C is provided. Also provided are lubricant compositions containing such polyalkylene glycol.
摘要翻译：一种聚亚烷基二醇，其包含：包含衍生自EO的单元的无规共聚物和由聚四氢呋喃引发的源自PO的单元; 其中聚亚烷基二醇的倾点小于或等于-30℃，使用ASTM D97测定，牵引值小于0.0165，接触压力为1.25GPa，速度= 2m / s，SRR为100％并提供80℃的温度。还提供含有这种聚亚烷基二醇的润滑剂组合物。

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