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    • 7. 发明申请
    • IMPROVED LITHIUM METAL OXIDE CATHODE MATERIALS AND METHOD TO MAKE THEM
    • 改进的锂金属氧化物阴极材料及其制备方法
    • WO2015061121A1
    • 2015-04-30
    • PCT/US2014/060835
    • 2014-10-16
    • DOW GLOBAL TECHNOLOGIES LLC
    • LEE, Edward L.ZHOU, Fu
    • C01G45/00C01G51/00C01G53/00H01M4/505H01M4/525
    • H01M4/505C01G53/006C01G53/44C01G53/50C01P2002/50C01P2002/54C01P2004/03C01P2004/32C01P2004/61C01P2006/11C01P2006/40H01B1/08H01M4/485H01M4/525
    • An improved method of forming a precipitated transition metal salt useful to make a lithium transition metal oxide useful for making a lithium ion battery comprises the following. A transition metal solution comprised of a dissolved transition metal salt in water and an alkali solution comprised of an alkali salt dissolved in water are introduced into a reactor having an inlet and an outlet connected by a tubular member having therein packing. The rate in which said solutions are introduced are such that the pH of the overall solution in the reactor has pH of 5 to 12 and the time of reaction (mere seconds to several minutes) in the reactor is sufficient to form a precipitated transition metal salt in an effluent liquid. The transition metal salt precipitate in the effluent is discharged from the reactor and the salt separated from the effluent, where it can be purified by washing and dried and subsequently heated with a lithium compound to form a lithium metal oxide useful for making lithium ion batteries.
    • 形成用于制造用于制备锂离子电池的锂过渡金属氧化物的沉淀过渡金属盐的改进方法包括以下。 将由溶解在水中的过渡金属盐和由溶解在水中的碱金属盐构成的碱溶液的过渡金属溶液引入反应器,该反应器具有通过其中具有填料的管状构件连接的入口和出口。 所述溶液的引入速率使得反应器中的整个溶液的pH值为5至12,并且反应器中的反应时间(仅数秒至数分钟)足以形成沉淀的过渡金属盐 在流出液体中。 流出物中的过渡金属盐沉淀物从反应器中排出,并将盐从流出物中分离出来,其中可以通过洗涤进行纯化并干燥,随后用锂化合物加热,形成用于制备锂离子电池的锂金属氧化物。