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    • 1. 发明专利
    • ACTIVATOR-NUCLEATOR FORMULATIONS
    • CA3102426A1
    • 2019-12-19
    • CA3102426
    • 2019-06-07
    • DOW GLOBAL TECHNOLOGIES LLC
    • BORSE NITINLIU ZHENSHUOMUNRO IAN MCHANDAK SWAPNIL B
    • C08F2/44
    • An activator-nucleator formulation comprising an activating effective amount of (A) an alkylaluminum(chloride) compound (compound (A)); and a nucleating effective amount of a compound (B) selected from at least one of compounds (B1) to (B3): (B1) calcium (1R,2S)-cis-cyclohexane-1,2-dicarboxylate (1:1); (B2) calcium stearate (1:2), and (B3) zinc stearate (1:2); wherein the compound (A) is effective for activating a Ziegler-Natta procatalyst to give a Ziegler-Natta catalyst; and wherein the compound (B) is effective for lowering isothermal crystallization peak time period of a semicrystalline polyethylene polymer made in a polymerization process by the Ziegler-Natta catalyst. A method of polymerizing ethylene, and optionally 0, 1, or more alpha-olefin comonomers, in a polymerization process conducted in a polymerization reactor, the method comprising contacting ethylene, and optionally 0, 1, or more alpha-olefin comonomers, with the Ziegler-Natta catalyst system to give a semicrystalline polyethylene polymer. The semicrystalline polyethylene polymer made by the method of polymerizing.
    • 3. 发明专利
    • ACTIVATOR-NUCLEATOR FORMULATIONS
    • SG11202011823SA
    • 2020-12-30
    • SG11202011823S
    • 2019-06-07
    • DOW GLOBAL TECHNOLOGIES LLC
    • BORSE NITINLIU ZHENSHUOMUNRO IAN MCHANDAK SWAPNIL B
    • C08F2/44
    • An activator-nucleator formulation comprising an activating effective amount of (A) an alkylaluminum(chloride) compound (compound (A)); and a nucleating effective amount of a compound (B) selected from at least one of compounds (B1) to (B3): (B1) calcium (1R,2S)-cis-cyclohexane-1,2-dicarboxylate (1:1); (B2) calcium stearate (1:2), and (B3) zinc stearate (1:2); wherein the compound (A) is effective for activating a Ziegler-Naha procatalyst to give a Ziegler-Natta catalyst; and wherein the compound (B) is effective for lowering isothermal crystallization peak time period of a semicrystalline polyethylene polymer made in a polymerization process by the Ziegler-Natta catalyst. A method of polymerizing ethylene, and optionally 0, 1, or more alpha-olefin comonomers, in a polymerization process conducted in a polymerization reactor, the method comprising contacting ethylene, and optionally 0, 1, or more alpha-olefin comonomers, with the Ziegler-Naha catalyst system to give a semicrystalline polyethylene polymer. The semicrystalline polyethylene polymer made by the method of polymerizing.