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1. 发明申请

WO2002094752A1 PROCESS FOR VINYL CHLORIDE MANUFACTURE FROM ETHANE AND ETHYLENE WITH AIR FEED AND ALTERNATIVE HCL PROCESSING METHODS 审中-公开
标题翻译：乙烯和乙烯与空气进料和替代HCL加工方法的氯乙烯制造方法
公开(公告)号：WO2002094752A1
公开(公告)日：2002-11-28
申请号：PCT/US2002/014801
申请日：2002-05-08
申请人： DOW GLOBAL TECHNOLOGIES INC. , HAYMON, Terry, D. , HENLEY, John, P. , HICKMAN, Daniel, A. , JONES, Mark, E. , MILLER, Matt, C. , MORRIS, Thomas, E. , REED, Daniel, J. , SAMSON, Lawrence, J. , SMITH, Steve, A. , CLARKE, William, D.
发明人： HAYMON, Terry, D. , HENLEY, John, P. , HICKMAN, Daniel, A. , JONES, Mark, E. , MILLER, Matt, C. , MORRIS, Thomas, E. , REED, Daniel, J. , SAMSON, Lawrence, J. , SMITH, Steve, A. , CLARKE, William, D.
IPC分类号： C07C17/154
CPC分类号： C07C17/154 , C07C17/152 , C07C17/156 , C07C21/06
摘要： In one aspect, a process for producing vinyl chloride from ethane/ethylene involving:(a) combining ethane, ethylene, or mixtures thereof with an oxygen source and a chlorine source in a reactor containing a suitable catalyst under conditions sufficient to convert substantially all of the C2 hydrocarbon fed and to produce a product stream comprising vinyl chloride and hydrogen chloride; and (b) recycling unreacted hydrogen chloride back for use in Step (a). No C2 hydrocarbon recycle is required in this process. In another aspect, a process for producing vinyl chloride involving: (a) combining ethane, optionally ethylene, an oxygen source, and a chlorine source in a reactor containing a suitable catalyst under conditions sufficient to produce vinyl chloride and hydrogen chloride; (b) catalytically reacting said hydrogen chloride in a second reactor to provide a second reactor effluent essentially devoid of hydrogen chloride; and (c) recycling said second reactor effluent to step (a). Optionally, the second process may be run under conditions to react C2 hydrocarbons to extinction and thereby eliminate a need for C2 hydrocarbon recycle. Either process may include a hydrogenation unit for converting cis/trans -1,2-dichloroethylenes) to ethylene dichloride.
摘要翻译：一方面，一种从乙烷/乙烯生产氯乙烯的方法，包括：（a）在足以将基本上全部转化的条件下转化的条件下，在含有合适催化剂的反应器中将乙烷，乙烯或其混合物与氧源和氯源混合所述C2烃进料并产生包含氯乙烯和氯化氢的产物流; 和（b）将未反应的氯化氢回收用于步骤（a）中。在此过程中不需要碳氢化合物循环。另一方面，一种生产氯乙烯的方法，包括：（a）在足以产生氯乙烯和氯化氢的条件下，在含有合适催化剂的反应器的反应器中混合乙烷，任选的乙烯，氧源和氯源; （b）在第二反应器中催化反应所述氯化氢以提供基本上不含氯化氢的第二反应器流出物; 和（c）将所述第二反应器流出物再循环到步骤（a）。任选地，第二种方法可以在使C2烃反应消失的条件下进行，从而消除对C2烃循环的需要。任一方法可以包括用于将顺式/反式-1,2-二氯乙烯转化为二氯乙烯的氢化单元。

2. 发明申请

WO2002094749A1 PRODUCTION OF VINYL HALIDE FROM SINGLE CARBON FEEDSTOCKS 审中-公开
标题翻译：从单碳源生产乙烯卤化物
公开(公告)号：WO2002094749A1
公开(公告)日：2002-11-28
申请号：PCT/US2002/013012
申请日：2002-04-23
申请人： DOW GLOBAL TECHNOLOGIES INC. , CLARKE, William, D. , HAYMON, Terry, D. , HENLEY, John, P. , HICKMAN, Daniel, A. , JONES, Mark, E. , MILLER, Matt, C. , MORRIS, Thomas, E. , REED, Daniel, J. , SAMSON, Lawrence, J. , SCHWEIZER, Albert, E. , SMITH, Steve, A.
发明人： CLARKE, William, D. , HAYMON, Terry, D. , HENLEY, John, P. , HICKMAN, Daniel, A. , JONES, Mark, E. , MILLER, Matt, C. , MORRIS, Thomas, E. , REED, Daniel, J. , SAMSON, Lawrence, J. , SCHWEIZER, Albert, E. , SMITH, Steve, A.
IPC分类号： C07C17/10
CPC分类号： B01J8/18 , B01J8/025 , B01J23/10 , B01J27/08 , B01J27/10 , B01J2208/00132 , B01J2208/00176 , B01J2208/00274 , B01J2219/00006 , B01J2219/0004 , C07C17/10 , C07C17/154 , C07C17/156 , C07C21/06 , C07C19/03
摘要： The preparation of vinyl halide monomer, and further to polyvinyl halide, starting from C 1 compounds, involving conversion of methane or methanol to methyl halide; condensation of methyl halide to ethylene and co-product hydrogen halide; oxidative halogenation of ethylene to vinyl halide monomer; separation of vinyl halide monomer from any methyl halide present in the vinyl halide monomer stream; optional recycling of the methyl halide recovered to the condensation step; and recovery and optional recycling of the co-product hydrogen halide. Optionally, the vinyl halide monomer may be polymerized to polyvinyl halide to facilitate separation of the monomer from methyl halide. Methyl halide may be obtained via oxidative halogenation of methane in the presence of a rare earth halide or rare earth oxyhalide catalyst. Optionally, the methyl halide may be converted to methanol.
摘要翻译：从C1化合物开始制备乙烯基卤单体，进一步由聚卤乙烯制备，涉及将甲烷或甲醇转化成甲基卤; 甲基卤化物与乙烯和副产物卤化氢的缩合; 乙烯氧化卤化成乙烯基卤单体; 乙烯基卤单体与乙烯基卤单体流中存在的任何甲基卤的分离; 回收到冷凝步骤的甲基卤的任选回收; 和副产物卤化氢的回收和可选回收。任选地，乙烯基卤单体可以聚合成聚卤乙烯以促进单体与甲基卤化物的分离。卤化甲烷可以在稀土卤化物或稀土氧化物催化剂的存在下通过甲烷的氧化卤化得到。任选地，甲基卤可以转化成甲醇。

3. 发明申请

WO2002094750A1 OXIDATIVE HALOGENATION AND OPTIONAL DEHYDROGENATION OF C3+ HYDROCARBONS 审中-公开
标题翻译： C3 +碳氢化合物的氧化反应和可选脱氢
公开(公告)号：WO2002094750A1
公开(公告)日：2002-11-28
申请号：PCT/US2002/013011
申请日：2002-04-23
申请人： DOW GLOBAL TECHNOLOGIES INC. , SCHWEIZER, Albert, E. , JONES, Mark, E. , HICKMAN, Daniel, A.
发明人： SCHWEIZER, Albert, E. , JONES, Mark, E. , HICKMAN, Daniel, A.
IPC分类号： C07C17/152
CPC分类号： C07C17/156 , B01J23/10 , B01J27/06 , B01J27/08 , B01J27/125 , C07C1/30 , C07C5/48 , C07C17/10 , C07C17/154 , C07C2527/06 , C07C2527/08 , Y02P20/52 , C07C11/02 , C07C19/01 , C07C21/067 , C07C11/06
摘要： An oxidative halogenation and optional dehydrogenation process involving contacting a reactant hydrocarbon having three or more carbon atoms, such as propane or propene, or a halogenated derivative thereof, with a source of halogen, and optionally, a source of oxygen in the presence of a rare earth halide or rare earth oxyhalide catalyst, so as to form a halogenated hydrocarbon product, such as allyl chloride, having three or more carbon atoms and having a greater number of halogen substituents as compared with the reactant hydrocarbon, and optionally, an olefinic co-product, such as propene. The less desired of the two products, that is, the halogenated hydrocarbon or the olefin as the case may be, can be recycled to the process to maximize the production of the desired product.
摘要翻译：氧化卤化和任选的脱氢方法，包括将具有三个或更多个碳原子的反应物烃如丙烷或丙烯或其卤化衍生物与卤素源和任选的氧源在罕见的存在下接触卤化物或稀土氧卤化物催化剂，以形成与反应物烃相比具有三个或更多个碳原子并且具有更多数量的卤素取代基的卤代烃产物，如烯丙基氯，以及任选地，产品，如丙烯。根据情况，两种产物，即卤代烃或烯烃的需求不太可以被再循环到该方法中，以使所需产物的产生最大化。

4. 发明申请

WO2011139334A1 PROCESS AND SYSTEM FOR PRODUCTION OF DICHLORINE 审中-公开
标题翻译：二氯生产工艺和方法
公开(公告)号：WO2011139334A1
公开(公告)日：2011-11-10
申请号：PCT/US2011/000708
申请日：2011-04-21
申请人： DOW GLOBAL TECHNOLOGIES LLC , STANGLAND, Eric, E. , HICKMAN, Daniel, A. , JONES, Mark, E. , PODKOLZIN, Simon, G. , FEIST, Shawn, D.
发明人： STANGLAND, Eric, E. , HICKMAN, Daniel, A. , JONES, Mark, E. , PODKOLZIN, Simon, G. , FEIST, Shawn, D.
IPC分类号： C01B7/04 , B01J8/26 , G01N31/10
CPC分类号： C01B7/04 , B01J8/26 , B01J2208/00212 , B01J2219/00011 , B01J2219/00038
摘要： The present disclosure provides a process and a system for producing dichlorine (C12) reacting a rare -earth metal oxy- chloride with HC1 at a first temperature during a chlorination stage of the process to form rare -earth metal chloride and H2O; removing H2O from the rare -earth metal chloride; and reacting the rare -earth metal chloride with O2 at a second temperature greater than the first temperature during an oxidation stage of the process to form C12 and the rare -earth metal oxy- chloride.
摘要翻译：本公开内容提供了在该方法的氯化阶段期间，在第一温度下使稀土金属氯化氯与HCl反应的二氯（C12）的方法和系统，以形成稀土金属氯化物和H 2 O; 从罕见的金属氯化物中除去H2O; 并且在该方法的氧化阶段期间，在大于第一温度的第二温度下使稀土金属氯化物与O 2反应，形成C12和稀土金属氧氯化物。

5. 发明申请

WO2005116004A1 PROCESS FOR PREPARING EPICHLOROHYDRIN FROM ETHANE 审中-公开
标题翻译：从乙烷制备乙二胺四乙酸的方法
公开(公告)号：WO2005116004A1
公开(公告)日：2005-12-08
申请号：PCT/US2005/017192
申请日：2005-05-17
申请人： DOW GLOBAL TECHNOLOGIES INC. , MAUGHON, Bob, R. , FRYCEK, George, J. , JONES, Mark, E.
发明人： MAUGHON, Bob, R. , FRYCEK, George, J. , JONES, Mark, E.
IPC分类号： C07D301/26
CPC分类号： B01J23/462 , B01J23/468 , C07D301/26
摘要： A process for preparing epichlorohydrin comprises (1) converting ethane to 1,2-dichloroethylene (cis/trans mixture) in the presence of a catalyst; (2) producing 2,3dichloropropanal by (a) hydroformylating the 1,2- dichloroethylene in the presence of a catalyst, carbon monoxide, and hydrogen, (b) adding MeOH to the 1,2dichloroethylene, or (c) subjecting the 1,2-dichloroethylene to direct reductive hydroformylation in the presence of a reductive hydroformylation catalyst; and (3) epoxidizing the 2,3-DCH with a base to produce epichlorohydrin.
摘要翻译：制备表氯醇的方法包括（1）在催化剂存在下将乙烷转化为1,2-二氯乙烯（顺式/反式混合物）（2）通过（a）在催化剂，一氧化碳和氢气存在下，对1,2-二氯乙烯进行加氢甲酰化，（b）向1,2-二氯乙烯中加入MeOH，或（c）使在还原加氢甲酰化催化剂存在下直接还原加氢甲酰化; 和（3）用碱环氧化2,3-DCH以制备表氯醇。

6. 发明申请

WO2006020234A1 CONVERSION OF A MULTIHYDROXYLATED-ALIPHATIC HYDROCARBON OR ESTER THEREOF TO A CHLOROHYDRIN 审中-公开
标题翻译：将多羟基化二烃或其酯转化为氯仿的转化
公开(公告)号：WO2006020234A1
公开(公告)日：2006-02-23
申请号：PCT/US2005/025443
申请日：2005-07-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , SCHRECK, David, J. , KRUPER, William, J., Jr. , VARJIAN, Richard, D. , JONES, Mark, E. , CAMPBELL, Robert, M. , KEARNS, Kenneth , HOOK, Bruce, D. , BRIGGS, John, R. , HIPPLER, Jeffrey, G.
发明人： SCHRECK, David, J. , KRUPER, William, J., Jr. , VARJIAN, Richard, D. , JONES, Mark, E. , CAMPBELL, Robert, M. , KEARNS, Kenneth , HOOK, Bruce, D. , BRIGGS, John, R. , HIPPLER, Jeffrey, G.
IPC分类号： C07C29/62 , C07D303/08
CPC分类号： C07D301/24 , C07C29/62 , C07C29/82 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts. In addition, certain catalysts of the present invention may be used in the present process at superatmospheric, atmospheric and subatmospheric pressure conditions with improved results.
摘要翻译：本发明涉及将多羟基化脂肪族烃或其酯转化为氯代醇的方法，该方法是将多羟基化脂族烃或其起始原料与氯化氢的超大气压分压源接触足够的时间和足够的温度，并且其中这种收缩步骤在不显着除去水的情况下进行，以产生所需的氯代醇产物; 其中所需的产物或产物可以高产率制备而不显着形成不需要的过氯化副产物。此外，本发明的某些催化剂可以在超大气压，大气压和低于大气压的条件下用于本方法，并具有改进的结果。

7. 发明申请

WO2006118935A3 OXIDATIVE HALOGENATION OF C1 HYDROCARBONS TO HALOGENATED C1 HYDROCARBONS 审中-公开
公开(公告)号：WO2006118935A3
公开(公告)日：2006-11-09
申请号：PCT/US2006/015993
申请日：2006-04-25
申请人： DOW GLOBAL TECHNOLOGIES INC. , PODKOLZIN, Simon, G. , STANGLAND, Eric, E. , SCHWEIZER, Albert, E., Jr. , JONES, Mark, E.
发明人： PODKOLZIN, Simon, G. , STANGLAND, Eric, E. , SCHWEIZER, Albert, E., Jr. , JONES, Mark, E.
IPC分类号： C07C17/154
摘要： An oxidative halogenation process involving contacting methane, a C1 halogenated hydrocarbon, or a mixture thereof with a source of halogen and a source of oxygen, at a molar ratio of reactant hydrocarbon to source of halogen in a feed to the reactor greater than 23/1 , and/or at a molar ratio of reactant hydrocarbon to source of oxygen in a feed to the reactor greater than about 46/1; in the presence of a rare earth halide or rare earth oxyhalide catalyst, to produce a halogenated C1 product having at least one more halogen as compared with the C1 reactant hydrocarbon, preferably, methyl chloride. The process can be advantageously conducted to total conversion of source of halogen and source of oxygen. The process can be advantageously conducted with essentially no halogen in the feed to the reactor, by employing a separate catalyst halogenation step in a pulse, swing or circulating bed mode. The production of methyl halide can be integrated into downstream processes for manufacture of valuable commodity chemicals.

8. 发明申请

WO2002094751A2 OXIDATIVE HALOGENATION OF C1 HYDROCARBONS TO HALOGENATED C1 HYDROCARBONS AND INTEGRATED PROCESSES RELATED THERETO 审中-公开
标题翻译：碳氢化合物对氢化碳氢化合物的氧化反应和与之相关的一体化方法
公开(公告)号：WO2002094751A2
公开(公告)日：2002-11-28
申请号：PCT/US2002/011778
申请日：2002-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC.
发明人： SCHWEIZER, Albert, E. , JONES, Mark, E. , HICKMAN, Daniel, A.
IPC分类号： C07C17/154
CPC分类号： C07C17/156 , C07C1/26 , C07C17/10 , C07C17/154 , C07C17/158 , C07C21/06 , C07C29/124 , C07C2529/70 , Y02P20/125 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C19/075 , C07C19/03 , C07C31/04
摘要： An oxidative halogenation process involving contacting a reactant hydrocarbon selected from methane, a halogenated C 1 hydrocarbon, or a mixture thereof with a source of halogen and, preferably, a source of oxygen in the presence of a rare earth halide or rare earth oxyhalide catalyst, so as to form a halogenated C 1 hydrocarbon having a greater number of halogen substituents as compared with the reactant hydrocarbon. Preferably, the product is a monohalogenated methane, more preferably, methyl chloride. The oxidative halogenation process to form methyl halide can be integrated with downstream processes to produce valuable commodity chemicals, for example, methyl alcohol and/or dimethyl ether; light olefins, including ethylene, propylene, and butenes; higher hydrocarbons, including gasolines; vinyl halide monomer, and acetic acid. Hydrogen halide, which is a co-product of these downstream processes, can be recycled to the oxidative halogenation process.
摘要翻译：一种氧化卤化方法，包括在稀土卤化物或稀土氧化物催化剂的存在下使选自甲烷，卤代C1烃或其混合物的反应物烃与卤素源，优选氧源接触，因此以形成与反应物烃相比具有更多卤素取代基的卤代C1烃。优选地，产物是单卤代甲烷，更优选氯甲烷。形成甲基卤化物的氧化卤化方法可与下游方法结合，生产有价值的商品化学品，例如甲醇和/或二甲醚; 轻质烯烃，包括乙烯，丙烯和丁烯; 高级烃类，包括汽油; 乙烯基卤单体和乙酸。作为这些下游方法的共同产物的卤化氢可以再循环到氧化卤化过程中。

9. 发明申请

WO2006055395A2 OPTICAL DEVICE FOR MEASURING OPTICAL PROPERTIES OF A SAMPLE AND METHOD RELATING THERETO 审中-公开
标题翻译：用于测量样品的光学性质的光学装置和与之相关的方法
公开(公告)号：WO2006055395A2
公开(公告)日：2006-05-26
申请号：PCT/US2005/040796
申请日：2005-11-14
申请人： LUNA INNOVATIONS INCORPORATED , HULL, Matthew, S. , AVERETT, Joshua, P. , JONES, Mark, E. , KLEMER, Daniel, R.
发明人： HULL, Matthew, S. , AVERETT, Joshua, P. , JONES, Mark, E. , KLEMER, Daniel, R.
IPC分类号： G01J3/30
CPC分类号： G01N21/6428 , G01J3/0218 , G01J3/42 , G01J3/4406 , G01N21/05 , G01N21/645 , G01N2021/6482
摘要： A device and method for measuring optical properties of a sample are provided. The device comprises a housing surrounding a flow-through flow-cell. The flow-cell has a sample inlet positioned proximate to a first end of the flow-cell and a sample outlet positioned proximate to a second end of the flow-cell. A sample chamber is positioned between the sample inlet and the sample outlet. A plurality of excitation sources are positioned on the housing in an operable relationship to the sample chamber. At least one excitation source has a wavelength that is different from the other excitation sources. Each excitation source is incident on a sample in the flow-cell. At least one fluorescence emission detector is positioned in an operable relationship to the flow-cell. The fluorescence emission detector detects a continuous broadband spectrum of emission wavelengths emitted from the sample upon excitation by each excitation source. At least one signal interrogation system is positioned in an operable relationship with each detector. The signal interrogation system interprets a continuous fluorescence emission spectrum. The device may also incorporate at least one absorbance detector for measuring transmitted power that is spectrally dependent on the absorbance characteristics of the sample.
摘要翻译：提供了一种用于测量样品的光学性质的装置和方法。该装置包括围绕流通流动池的壳体。流动池具有靠近流动池的第一端定位的样品入口和靠近流动池的第二端定位的样品出口。样品室位于样品入口和样品出口之间。多个激发源以与样品室可操作的关系定位在壳体上。至少一个激发源具有与其它激发源不同的波长。每个激发源入射在流动池中的样品上。至少一个荧光发射检测器被定位成与流通池可操作的关系。荧光发射检测器检测由每个激发源激发时从样品发射的发射波长的连续宽带谱。至少一个信号询问系统被定位成与每个检测器可操作的关系。信号询问系统解释连续的荧光发射光谱。该装置还可以结合至少一个吸光度检测器，用于测量在光谱上依赖于样品的吸收特性的透射功率。

10. 发明授权

EP1235772B1 A PROCESS FOR THE CONVERSION OF ETHYLENE TO VINYL CHLORIDE, AND NOVEL CATALYST COMPOSITIONS USEFUL FOR SUCH PROCESS 有权
标题翻译：工艺用于乙烯氯乙烯者和催化剂的转化物适于这样的方法
公开(公告)号：EP1235772B1
公开(公告)日：2005-01-19
申请号：EP00968627.0
申请日：2000-10-03
申请人： Dow Global Technologies, Inc.
发明人： JONES, Mark, E. , OLKEN, Michael, M. , HICKMAN, Daniel, A.
IPC分类号： C07C17/156 , C07C17/154 , C07C17/152 , C07C21/06 , C07C17/25 , B01J27/06 , B01J27/10 , B01J27/125 , C07C1/30
CPC分类号： C07C17/25 , B01J23/10 , B01J23/72 , B01J23/83 , B01J27/10 , B01J27/122 , B01J35/10 , B01J37/03 , B01J37/031 , B01J37/036 , B01J37/22 , C07C17/15 , C07C17/152 , C07C17/154 , C07C17/156 , C07C17/158 , C07C21/06 , C07C19/045 , C07C21/073 , C07C21/067 , C07C21/04
摘要： This invention is a process for producing vinyl chloride from an ethylene-containing feed, oxygen, and a chlorine source in the presence of a catalyst. The process permits direct production of vinyl chloride in a single reactor system, and further permits ethane to be used as the C2 hydrocarbon feed with recycle of ethylene from the product stream to constitute the ethylene specified for the feed. This invention in another aspect concerns also a composition of matter, and a method for making the composition, wherein the composition is useful as a catalyst for the vinyl chloride process. The composition comprises a rare earth-containing material, with the proviso that the catalyst prepared therefrom is substantially free of iron and copper and with the further proviso that when cerium is present the catalyst further comprises at least one more rare earth element other than cerium.

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