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    • 4. 发明申请
    • ELASTOMERIC COMPOSITIONS WITH IMPROVED RESISTANCE TO NECKING FOR HIGH SPEED SHEET EXTRUSION APPLICATIONS
    • 具有改善耐高压片材挤出应用的弹性组合物
    • WO2006055650A1
    • 2006-05-26
    • PCT/US2005/041562
    • 2005-11-16
    • DOW GLOBAL TECHNOLOGIES INC.HECK, Henry, G.
    • HECK, Henry, G.
    • C08L23/10C08L23/08
    • C08L23/0807C08L23/10C08L2205/02C08L2666/06
    • A composition comprising: (a) a high melt strength material, comprising a first polymer selected from the group consisting of an elastomeric ethylene/α-olefin polymer and a polypropylene polymer, and (b) a high flow material, comprising a second polymer selected from the group consisting of an elastomeric ethylene/α-olefin polymer and a polypropylene polymer. The high melt strength material has a dynamic complex viscosity greater than, or equal to, 175,000 Poise (17,500 Pa-s), measured using parallel plate rheometry at 1 radians per second and 190 degrees Centigrade, and the high flow material has a ratio, η*/td, less than 2500, where η* is the dynamic complex viscosity and td is the tan delta, both measured at 1 radian per second at 190 degrees Centigrade. The composition exhibits minimal necking when extruded at high speeds and is particularly useful for making sheets via high speed extrusion.
    • 一种组合物,其包含:(a)高熔体强度材料,其包含选自弹性体乙烯/α-烯烃聚合物和聚丙烯聚合物的第一聚合物,和(b)高流动材料,其包含选自第二聚合物 由弹性体乙烯/α-烯烃聚合物和聚丙烯聚合物组成。 高熔体强度材料具有大于或等于175,000泊(17,500帕斯卡)的动态复合粘度,采用平行板流变测量法,每秒1弧度/秒和190摄氏度,高流动材料的比例, ?* / td,小于2500,其中?*是动态复数粘度,td是tanδ,均在190摄氏度时以1弧度/秒测量。 当高速挤出时,组合物显示出最小的颈缩,并且特别适用于通过高速挤出制造片材。
    • 5. 发明申请
    • FILLED TPO COMPOSITIONS WITH GOOD LOW TEMPERATURE DUCTILITY
    • 填充的TPO组合物具有良好的低温密度
    • WO2009035850A1
    • 2009-03-19
    • PCT/US2008/074455
    • 2008-08-27
    • DOW GLOBAL TECHNOLOGIES INC.HECK, Henry, G.
    • HECK, Henry, G.
    • C08L23/00
    • C08L23/10C08L23/0815C08L23/12C08L2666/06
    • Filled, thermoplastic polyolefin (TPO) compositions having a total energy absorption during impact at -3O°C of at least 20 ft-lb-f as measured by an Instrumented Dart Impact Test (ASTM D3763) at 6.7 m/s and a peak tangent flexural modulus of >2100 MPa (305,000 psi as measured by ASTM D-790, the composition comprising based on the total weight of the TPO composition; A) 36-56 wt% of a crystalline polypropylene having a MFR of at least 1 and a melting point of at least 160°C as measured by DSC; and B) 64-44 wt% of an elastomer/filler composition comprising (1) an EAO elastomer having a (1) Tg of less than -50°C as measured by DSC, (b) tan delta between >2 and 3 as measured at 0.1 rad/s and 190°C with an Advanced Rheometrie Expansion Systems rheometer. and (c) HDT greater than or equal to the peak melting temperature of the elastomer as measured by DSC, and (2) a platy filler, e.g., talc, the elastomer and filler present at a weight ratio of elastomer to filler of 3:2 to 2:1; the crystalline polypropylene and elastomer present at a weight ratio of polypropylene to elastomer of less than 2.
    • 填充的热塑性聚烯烃(TPO)组合物,其在-3O°C冲击期间的总能量吸收为至少20ft-lb-f,通过仪器飞镖冲击试验(ASTM D3763)以6.7m / s和峰值切线 弯曲模量> 2100MPa(通过ASTM D-790测量的305,000psi,组合物基于TPO组合物的总重量包含; A)36-56重量%的MFR至少为1的结晶聚丙烯和 通过DSC测量的熔点至少为160℃; 和B)64-44重量%的弹性体/填料组合物,其包含(1)通过DSC测量的(1)Tg小于-50℃的EAO弹性体,(b)> 2和3之间的tanδ> 2 使用Advanced Rheometrie Expansion Systems流变仪测量0.1rad / s和190℃。 和(c)通过DSC测量的大于或等于弹性体的峰值熔融温度的HDT,和(2)板状填料,例如滑石,弹性体和填料以弹性体与填料的重量比3: 2至2:1; 结晶聚丙烯和弹性体以聚丙烯与弹性体的重量比存在小于2。
    • 9. 发明公开
    • ELASTOMERIC COMPOSITIONS WITH IMPROVED RESISTANCE TO NECKING FOR HIGH SPEED SHEET EXTRUSION APPLICATIONS
    • 用于高速片材挤出应用的具有改善的抗咬合性的弹性组合物
    • EP1814942A1
    • 2007-08-08
    • EP05846330.8
    • 2005-11-16
    • Dow Global Technologies Inc.
    • HECK, Henry, G.
    • C08L23/10C08L23/08
    • C08L23/0807C08L23/10C08L2205/02C08L2666/06
    • A composition comprising: (a) a high melt strength material, comprising a first polymer selected from the group consisting of an elastomeric ethylene/α-olefin polymer and a polypropylene polymer, and (b) a high flow material, comprising a second polymer selected from the group consisting of an elastomeric ethylene/α-olefin polymer and a polypropylene polymer. The high melt strength material has a dynamic complex viscosity greater than, or equal to, 175,000 Poise (17,500 Pa-s), measured using parallel plate rheometry at 1 radians per second and 190 degrees Centigrade, and the high flow material has a ratio, η*/td, less than 2500, where η* is the dynamic complex viscosity and td is the tan delta, both measured at 1 radian per second at 190 degrees Centigrade. The composition exhibits minimal necking when extruded at high speeds and is particularly useful for making sheets via high speed extrusion.
    • 一种组合物,其包含:(a)高熔体强度材料,其包含选自弹性体乙烯/α-烯烃聚合物和聚丙烯聚合物的第一聚合物,和(b)高流动性材料,其包含选自第二聚合物 选自弹性体乙烯/α-烯烃聚合物和聚丙烯聚合物。 高熔体强度材料具有大于或等于175,000泊(17,500Pa-s)的动态复数粘度,其使用平行板流变仪以1弧度每秒和190摄氏度测量,并且高流动性材料具有比率, η* / td小于2500,其中η*是动态复数粘度,td是tanδ,两者都是在190摄氏度时以1弧度每秒测量的。 该组合物在高速挤出时表现出最小的颈缩,并且特别适用于通过高速挤出制备片材。