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1. 发明专利

JP2011012272A Composition containing cross-linkable matrix precursor and poragen, and porous matrix prepared therefrom 有权
标题翻译：包含可交联矩阵前缀和PORAGEN的组合物，以及其中制备的多孔矩阵
公开(公告)号：JP2011012272A
公开(公告)日：2011-01-20
申请号：JP2010181420
申请日：2010-08-13
申请人： Dow Global Technologies Inc , ダウグローバルテクノロジーズインコーポレイティド
发明人： BRUZA KENNETH J , GODSCHALX JAMES P , SHAFFER EDWARD O II , SMITH DENNIS W JR , TOWNSEND PAUL H III , BOUCK KEVIN J , NIU QING SHAN J
IPC分类号： C08J9/26 , G02F1/1333 , C08F32/04 , C08F36/22 , C08F38/00 , C08L25/06 , C08L65/00 , H01L21/312
CPC分类号： C08J9/26 , C08J2365/00 , C08L25/06 , C08L65/00 , H01L21/02118 , H01L21/02126 , H01L21/02203 , H01L21/02282 , H01L21/312 , C08L2666/04 , C08L25/00 , C08L2666/06
摘要： PROBLEM TO BE SOLVED: To provide an ultra-low dielectric material that is stable to the severe processing conditions required in fabricating semiconductors.SOLUTION: The invention provides a composition comprising (a) a hydrocarbon-containing matrix precursor and (b) a poragen; wherein the matrix precursor is selected to form upon curing a cross-linked, hydrocarbon-containing material having a Tg of greater than 300°C.
摘要翻译：要解决的问题：提供对制造半导体所需的苛刻加工条件稳定的超低介电材料。解决方案：本发明提供一种组合物，其包含（a）含烃基质前体和（b）成孔剂; 其中所述基体前体被选择为在固化Tg高于300℃的交联的含烃材料时形成。

2. 发明申请

WO2005036666A3 METHOD OF PREPARING AN INSOLUBLE POLYMER FILM ON A SUBSTRATE FROM A SOLUBLE POLYMER CONTAINING LABILE SOLUBILIZING GROUPS 审中-公开
标题翻译：从含有可溶性溶解组合的可溶性聚合物制备基底上的不溶性聚合物膜的方法
公开(公告)号：WO2005036666A3
公开(公告)日：2005-07-07
申请号：PCT/US2004029154
申请日：2004-09-08
申请人： DOW GLOBAL TECHNOLOGIES INC , DIBBS MITCHELL G , INBASEKARAN MICHAEL , TOWNSEND PAUL H III , FOSTER KENNETH L , FENG SHAOGUANG , BRENNAN DAVID J , NIU Q JASON , GODSCHALX JAMES P , WELSH DEAN M , DRUMRIGHT RAY E
发明人： DIBBS MITCHELL G , INBASEKARAN MICHAEL , TOWNSEND PAUL H III , FOSTER KENNETH L , FENG SHAOGUANG , BRENNAN DAVID J , NIU Q JASON , GODSCHALX JAMES P , WELSH DEAN M , DRUMRIGHT RAY E
IPC分类号： H01L51/30 , H01L51/40
CPC分类号： H01L51/0043 , H01L51/0003 , H01L51/0035 , H01L51/0039 , H01L51/0059
摘要： The present invention relates to a method for preparing polymeric films, preferably electroactive films, with enhanced physical properties by the steps of applying to a substrate a solution of a polymer containing pendant labile solubilizing groups, then removing the solvent and a sufficient concentration of the labile solubilizing groups render the polymer less soluble in the solvent than before the labile groups were removed. It is believed that the removal of pendant soluble groups a) permits optimization of the semiconducting backbone for charge transport performance, b) allows direct control of microstructure in the final film, and c) renders the final film more robust during subsequent process steps needed to construct multilayer devices.
摘要翻译：本发明涉及通过以下步骤制备具有增强的物理性能的聚合物薄膜，优选电活性薄膜的方法：向基材施加含有不稳定增溶基团的聚合物溶液，然后除去溶剂和足够浓度的不稳定增溶基团使得聚合物在除去不稳定基团之前较不溶于溶剂。据信去除侧链可溶性基团a）允许优化用于电荷传输性能的半导电骨架，b）允许直接控制最终膜中的微结构，以及c）使后续工艺步骤中的最终膜更坚固，构建多层设备。

3. 发明申请

WO2004073824A3 METHOD OF SYNTHESIS OF POLYARYLENES AND THE POLYARYLENES MADE BY SUCH METHOD 审中-公开
标题翻译：合成聚烯烃的方法和用这种方法制备的聚烯烃
公开(公告)号：WO2004073824A3
公开(公告)日：2004-10-14
申请号：PCT/US2004004986
申请日：2004-02-19
申请人： DOW GLOBAL TECHNOLOGIES INC , GODSCHALX JAMES P , PECHACEK JAMES P , ARNDT KIM E
发明人： GODSCHALX JAMES P , PECHACEK JAMES P , ARNDT KIM E
IPC分类号： C08G61/12 , C08G61/10
CPC分类号： C07D307/89 , C07D309/38 , C08G61/122 , C08G61/125 , C08G61/126
摘要： The present invention is a method of making cross-linked or cross-linkable polyarylenes comprising providing a reaction mixture comprising (a) a first monomer comprising at least two cyclic functional groups (b) a second monomer comprising at least two dienophile functional groups, and heating the reaction mixture to form a polymerized or partially polymerized polyarylene material, wherein at least one of the first or second monomers must comprise at least three functional groups. The cyclic groups in the first monomer are characterized by the presence of two conjugated carbon to carbon double bonds and a leaving group, L, selected from -0-, -S-, -(SO2)-, -N=N-, or -O(CO)-. The present invention is also the partially polymerized reaction product of the above method. Finally, the present invention is also specific difunctional diene monomers useful in such a method.
摘要翻译：本发明是制备交联或可交联聚亚芳基的方法，其包括提供反应混合物，所述反应混合物包含（a）包含至少两个环状官能团的第一单体（b）包含至少两个亲双烯体官能团的第二单体，和加热反应混合物以形成聚合或部分聚合的聚亚芳基材料，其中第一或第二单体中的至少一个必须包含至少三个官能团。第一单体中的环状基团的特征在于存在两个共轭碳 - 碳双键和离去基团L，其选自-O - ， - S - ， - （SO 2） - ， - N = N-或 -O（CO） - 。本发明也是上述方法的部分聚合反应产物。最后，本发明也是用于这种方法的特定双官能二烯单体。

4. 发明申请

WO03068825A2 MULTIFUNCTIONAL MONOMERS AND THEIR USE IN MAKING CROSS-LINKED POLYMERS AND POROUS FILMS 审中-公开
标题翻译：多功能单体及其在制造交联聚合物和多孔膜中的用途
公开(公告)号：WO03068825A2
公开(公告)日：2003-08-21
申请号：PCT/US0304221
申请日：2003-02-12
申请人： DOW GLOBAL TECHNOLOGIES INC , NIU QING SHAN J , HEFNER ROBERT E JR , GODSCHALX JAMES P
发明人： NIU QING SHAN J , HEFNER ROBERT E JR , GODSCHALX JAMES P
IPC分类号： C07D309/38 , C07C45/30 , C07C45/46 , C07C45/48 , C07C45/65 , C07C45/66 , C07C45/68 , C07C45/81 , C07C49/683 , C07C49/753 , C07C49/84 , C08G61/00 , C08J9/26 , H01L23/532 , C08F
CPC分类号： C07C49/753 , C07C45/30 , C07C45/46 , C07C45/48 , C07C45/65 , C07C45/66 , C07C45/68 , C07C45/81 , C07C49/683 , C07C49/84 , C07D309/38 , H01L23/5329 , H01L2924/0002 , C07C49/233 , H01L2924/00
摘要： This invention is a monomer comprising at least two dienophile groups and at least two ring structures which ring structures are characterized by the presence of two conjugated carbon-to-carbon double bonds and the presence of a leaving group L, wherein L is characterized that when the ring structure reacts with a dienophile in the presence of heat or other energy sources, L is removed to form an aromatic ring structure. This invention is also curable oligomers and polymers and highly cross-linked polymers made with such monomers. Moreover, this invention is a method of making porous films by combining such monomers or their oligomers with a porogen, curing the polymer and removing the porogen.
摘要翻译：本发明是包含至少两个亲双烯体基团和至少两个环结构的单体，所述环结构的特征在于存在两个共轭碳 - 碳双键和存在离去基团L，其中L表征为在热或其他能量源的存在下，环结构与亲二烯体反应，除去L形成芳环结构。本发明也是可固化的低聚物和聚合物以及用这些单体制成的高度交联的聚合物。此外，本发明是通过将这些单体或其低聚物与致孔剂结合，固化聚合物并除去致孔剂来制造多孔膜的方法。

5. 发明专利

AU2003216205A1 METHOD OF MAKING A NANOPOROUS FILM 未知
公开(公告)号：AU2003216205A1
公开(公告)日：2003-09-09
申请号：AU2003216205
申请日：2003-02-07
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： SO YING HUNG , NIU QING SHAN J , TOWNSEND PAUL H III , MARTIN STEVEN J , KALANTAR THOMAS H , GODSCHALX JAMES P , BRUZA KENNETH J , BOUCK KEVIN J
IPC分类号： C08J9/26 , C08F257/02 , C08F283/00 , C08G61/02 , C08G61/10 , C08J9/28 , H01L21/312 , H01L21/316 , H01L23/532 , C08J9/00 , C08L25/00 , C08L61/00 , C08G83/00 , C08L101/00 , C08K7/16 , C08L51/04 , C08J9/18 , C08L25/06 , H01B3/46 , H01L23/00 , H01L21/332
摘要： Applicants found that selection of reactive nanoparticles as poragens when combined with monomeric precusors to organic, particularly polyarylene or polyarylene ether, matrix materials are effective in obtaining very small pore sizes.

6. 发明申请

WO2004089862A3 MULTIFUNCTIONAL UNSYMMETRICALLY SUBSTITUTED MONOMERS AND POLYARYLENE COMPOSITIONS THEREFROM 审中-公开
标题翻译：多功能非对称取代的单体和聚烯烃组合物
公开(公告)号：WO2004089862A3
公开(公告)日：2004-11-25
申请号：PCT/US2004009973
申请日：2004-04-01
申请人： DOW GLOBAL TECHNOLOGIES INC , GODSCHALX JAMES P , HEFNER ROBERT E JR , NIU JASON Q , SILVIS H CRAIG
发明人： GODSCHALX JAMES P , HEFNER ROBERT E JR , NIU JASON Q , SILVIS H CRAIG
IPC分类号： C07C17/266 , C07C45/29 , C07C45/68 , C07C45/74 , C07C49/683 , C07C49/753 , C08F38/00 , C08G61/10
CPC分类号： C07C49/753 , C07C17/266 , C07C45/29 , C07C45/30 , C07C45/68 , C07C45/74 , C07C49/683 , C08G2261/312 , H01L21/312 , H01L21/31695 , C07C25/24 , C07C49/813 , C07C49/796
摘要： A monomer suitable for use in forming low dielectric constant films in semiconductor devices comprising i) two dienophile groups (A-functional groups) attached to a single aromatic ring and ii) a second ring structure comprising two conjugated carbon-to-carbon double bonds and a leaving group L (B-functional group), characterized in that said single aromatic ring is directly covalently attached to one of the double bonded carbons of the B functional group or to a fused aromatic ring containing two such double bonded carbons of the B-functional group, and one A-functional group of one monomer is capable of reaction under cycloaddition reaction conditions with the B-functional group of a second monomer to thereby form a polymer.
摘要翻译：一种适用于在半导体器件中形成低介电常数膜的单体，其包括：i）与单个芳香环相连的两个亲电子基团（A-官能团）和ii）包含两个共轭碳 - 碳双键的第二环结构和离去基团L（B-官能团），其特征在于所述单芳环直接共价连接到B官能团的双键键合碳之一或含有两个这样的双键结合碳的稠合芳环上，官能团和一个单体的一个A官能团能够在环加成反应条件下与第二单体的B官能团反应，从而形成聚合物。

7. 发明申请

WO03068825A8 MULTIFUNCTIONAL MONOMERS AND THEIR USE IN MAKING CROSS-LINKED POLYMERS AND POROUS FILMS 审中-公开
标题翻译：多功能单体及其在制备交联聚合物和多孔膜中的应用
公开(公告)号：WO03068825A8
公开(公告)日：2003-12-04
申请号：PCT/US0304221
申请日：2003-02-12
申请人： DOW GLOBAL TECHNOLOGIES INC , NIU QING SHAN J , HEFNER ROBERT E JR , GODSCHALX JAMES P , PECHACEK JAMES T , ARNDT KIM E
发明人： NIU QING SHAN J , HEFNER ROBERT E JR , GODSCHALX JAMES P , PECHACEK JAMES T , ARNDT KIM E
IPC分类号： C07D309/38 , C07C45/30 , C07C45/46 , C07C45/48 , C07C45/65 , C07C45/66 , C07C45/68 , C07C45/81 , C07C49/683 , C07C49/753 , C07C49/84 , C08G61/00 , C08J9/26 , H01L23/532 , C08F
CPC分类号： C07C49/753 , C07C45/30 , C07C45/46 , C07C45/48 , C07C45/65 , C07C45/66 , C07C45/68 , C07C45/81 , C07C49/683 , C07C49/84 , C07D309/38 , H01L23/5329 , H01L2924/0002 , C07C49/233 , H01L2924/00
摘要： This invention is a monomer comprising at least two dienophile groups and at least two ring structures which ring structures are characterized by the presence of two conjugated carbon-to-carbon double bonds and the presence of a leaving group L, wherein L is characterized that when the ring structure reacts with a dienophile in the presence of heat or other energy sources, L is removed to form an aromatic ring structure. This invention is also curable oligomers and polymers and highly cross-linked polymers made with such monomers. Moreover, this invention is a method of making porous films by combining such monomers or their oligomers with a porogen, curing the polymer and removing the porogen.
摘要翻译：本发明是包含至少两个亲双烯体基团和至少两个环结构的单体，其中环结构的特征在于存在两个共轭碳 - 碳双键和存在离去基团L，其中L的特征在于当环结构在热或其他能量源的存在下与亲二烯体反应，除去L以形成芳环结构。本发明也是可固化的低聚物和聚合物以及用这种单体制备的高度交联的聚合物。此外，本发明是通过将这些单体或其低聚物与致孔剂组合，固化聚合物和除去致孔剂来制备多孔膜的方法。

8. 发明专利

AT323132T 未知
公开(公告)号：AT323132T
公开(公告)日：2006-04-15
申请号：AT99962822
申请日：1999-11-22
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： BRUZA KENNETH J , GODSCHALX JAMES P , SHAFFER EDWARD O II , SMITH DENNIS W JR , TOWNSEND PAUL H III , BOUCK KEVIN J , NIU QING SHAN J
IPC分类号： G02F1/1333 , C08F32/04 , C08F36/22 , C08F38/00 , C08J9/26 , C08L25/06 , C08L65/00 , H01L21/312
摘要： A suitable cross-linkable matrix precursor and a poragen can be treated to form a porous cross-linked matrix having a T g of greater than 300° C. The porous matrix material has a lower dielectric constant than the corresponding non-porous matrix material, making the porous matrix material particularly attractive for a variety of electronic applications including integrated circuits, multichip modules, and flat panel display devices.

9. 发明专利

DE69731010D1 未知
公开(公告)号：DE69731010D1
公开(公告)日：2004-11-04
申请号：DE69731010
申请日：1997-08-28
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： GODSCHALX JAMES P , ROMER DUANE R , SO YING HUNG , LYSENKO ZENON , MILLS MICHAEL E , BUSKE GARY R , TOWSEND III , SMITH JR , MARTIN STEVEN J , DEVRIES ROBERT A
IPC分类号： C08G61/10 , C07C49/683 , H05K1/00
摘要： The present invention refers to aromatic monomers containing at least one cyclopentadienone moiety and at least one acetylene moiety and oligomers, uncured polymers and cured polymers comprising the reaction product thereof.

10. 发明专利

DE60323152D1 未知
公开(公告)号：DE60323152D1
公开(公告)日：2008-10-02
申请号：DE60323152
申请日：2003-11-24
申请人： DOW GLOBAL TECHNOLOGIES INC , IBM
发明人： HEDRICK JEFFREY C , SANKARAPANDIAN MUTHUMANICKAM , TYBERG CHRISTY S , GODSCHALX JAMES P , NIU QING SHAN , SILVIS H CRAIG
IPC分类号： C08G61/00 , C08G61/10 , C08L65/00 , C09D165/00 , H01L23/532
摘要： A crosslinked polyarylene material with a reduced coefficient of thermal expansion at high temperatures compared with conventional crosslinked polyarylene materials is provided. In addition, an integrated circuit article containing a crosslinked polyarylene polymer with reduced coefficient of thermal expansion at high temperatures is provided.

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