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    • 3. 发明专利
    • Reactive silicone composition, reactive thermoplastic body, cured product and optical semiconductor device
    • 反应性硅酮组合物,反应性热塑体,固化产物和光学半导体器件
    • JP2014009322A
    • 2014-01-20
    • JP2012148037
    • 2012-06-29
    • Dow Corning Toray Co Ltd東レ・ダウコーニング株式会社
    • YAMAZAKI RYOSUKEYAMAZAKI HARUNAYOSHITAKE MAKOTO
    • C08L83/07C08K3/36C08K7/14C08K7/18C08L83/05H01L33/58
    • C08K7/18C08G77/12C08G77/20C08G77/80C08K3/22C08K3/36C08K7/14C08K2003/2241C08L83/04H01L33/486H01L33/60H01L2924/0002H01L2933/0033H01L2924/00
    • PROBLEM TO BE SOLVED: To provide a reactive silicone composition being solid state at the normal temperature and capable of giving a reactive thermoplastic body fluidized at a high temperature, the reactive thermoplastic body which fluidizes once at heating and then giving a cured product, the cured product having little degradation in mechanical strength and little change of color by heat or light and high optical reflectance, and an optical semiconductor device having high luminous efficiency and little heat deterioration and little light deterioration of a light reflection material.SOLUTION: The invention provides a reactive silicone composition containing al least (A) organopolysiloxane having an alkenyl group represented by an average unit formula, (B) organopolysiloxane having an alkenyl group represented by a general formula, (C) organopolysiloxane having a hydrogen atom bound to a silicon atom represented by a general formula, (D) a catalyst for hydrosilylation reactions, (E) a white pigment, (G) a spherical silica, a non spherical silica or a glass fiber, a reactive thermoplastic body obtained by reacting the composition under specific conditions, a cured product obtained by heating the reactive thermoplastic body and an optical semiconductor device including the cured product.
    • 要解决的问题:为了提供在常温下为固态并能够提供在高温下流化的活性热塑性体的反应性硅氧烷组合物,在加热时流化一次然后产生固化产物的活性热塑性体,固化 通过热或光和高反射率的机械强度几乎没有劣化和颜色变化小的产品,以及具有高发光效率和少的热劣化以及光反射材料的轻度劣化的光半导体器件。解决方案:本发明提供了一种 含有具有由平均单元式表示的链烯基的至少(A)有机聚硅氧烷的反应性硅氧烷组合物,(B)具有通式表示的烯基的有机聚硅氧烷,(C)具有与硅原子键合的氢原子的有机聚硅氧烷, 通式(D)氢化硅烷化反应的催化剂,(E)a 白色颜料,(G)球状二氧化硅,非球形二氧化硅或玻璃纤维,通过在特定条件下使组合物反应获得的反应性热塑性体,通过加热反应性热塑性体获得的固化产物和包含固化的 产品。