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    • 2. 发明专利
    • DE102006025471A1
    • 2007-02-08
    • DE102006025471
    • 2006-05-30
    • DENSO CORPADEKA CORP
    • USAMI KYOHEIFUKAYA ATSUSHIYAMADA MANABUTAKI TAKAYUKIYAMAMOTO KOKEI
    • H01M10/05H01M10/052H01M10/0567H01M10/0568H01M10/0569
    • A nonaqueous electrolyte containing a silicon compound of formula (1) or (2) and a nonaqueous electrolyte secondary battery using the nonaqueous electrolyte and excellent in cycle characteristics and low temperature characteristics, wherein R 1 and R 2 each represent alkyl, cycloalkyl, alkoxy or halogen; R 3 represents alkenyl; and X represents halogen, wherein R 4 , R 5 , R 6 , and R 7 each represent alkyl, alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, phenyl or phenoxy, each of which may have an ether bond in its chain; R 8 represents halogen, halogen-substituted aryl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl; a trifluoromethyl group, an acyloxy group having 5 to 8 carbon atoms, a sulfonate group having 1 to 8 carbon atoms, an isocyanyl group an isothianyl or a cyano group, R 9 represents halogen, a trifluoromethyl group,an acyloxy group having 5 to 8 carbon atoms, a sulfonate group having 1 to 8 carbon atoms, an isocyanyl group an isothianyl or a cyano group: halogen-substituted aryl; n represents 1 or 2; and Y represents a single bond, oxygen, alkylene, alkylenedioxy, alkenylene, alkenylenedioxy, alkynylene, alkynylenedioxy, arylene or arylenedioxy; provided that the number of groups having an unsaturated bond in R 4 , R 5 , R 6 , R 7 , R 8 , and R 9 is zero or one.
    • 5. 发明公开
    • NONAQUEOUS ELECTROLYTE SOLUTION FOR BATTERIES, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY USING SAME
    • 自由水电解质溶液对于电池及二次电池与水无电解质与溶液
    • EP2683011A4
    • 2014-08-13
    • EP11860524
    • 2011-03-04
    • DENSO CORPADEKA CORP
    • YAMAMOTO KOUHEIUMEMOTO HISASHIUSAMI KYOHEIYAMADA MANABUTAKI TAKAYUKIOHNUMA YUYUWATANABE HIROAKISHIBUYA ATSUKI
    • H01M4/62H01M4/587H01M10/0525H01M10/0567H01M10/0568H01M10/0569
    • H01M10/0567H01M4/36H01M4/587H01M4/622H01M10/0525H01M10/0568H01M10/0569Y02T10/7011
    • The present invention relates to provide a nonaqueous electrolyte solution for secondary batteries, which can maintain a small internal resistance and a high electrical capacitance in long-term use in a nonaqueous electrolyte secondary battery using, as an active material, a crystalline carbon material having a high crystallinity, such as graphite and using a negative electrode produced using a polymeric carboxylic compound as a binding agent, and a nonaqueous electrolyte secondary battery using the nonaqueous electrolyte solution for secondary batteries. The present invention further provides a nonaqueous electrolyte solution for batteries, which contains, as an (A) component, at least one compound selected from a group consisting of an unsaturated phosphate ester compound represented by a general formula (1) and an unsaturated phosphate ester compound represented by a general formula (2), as a (B) component, at least one compound selected from a group consisting of a sulfite ester compound, a sulfonate ester compound, an alkali metal imide salt compound, a fluorosilane compound, and an organic disilane compound or an organic disiloxane compound, an organic solvent as a (C) component, and electrolyte salt as a (D) component, and a nonaqueous electrolyte secondary battery using the nonaqueous electrolyte solution for batteries.
    • 本发明涉及提供一种用于二次电池的非水电解质溶液,其可以保持内阻小,并且在非水电解质二次电池的长期使用使用高电容,作为活性材料的,具有结晶性的碳材料 高结晶度,颜色:如石墨和使用利用聚羧酸化合物,其为结合剂制成的负电极,以及使用的二次电池用非水电解质溶液的非水电解质二次电池。 本发明还提供了电池的非水电解质溶液,其含有作为(A)成分,从以下一组由通式表示的不饱和磷酸酯化合物中的至少一种化合物(1)和非饱和磷酸酯 由通式(2)表示的化合物,作为(B)成分,从一组以超过碱金属亚胺盐化合物,氟硅烷化合物亚硫酸盐酯化合物,磺酸酯化合物,由......组成中的至少一种化合物,以及 有机化合物或有机二硅氧烷化合物,以有机溶剂作为组分(C),和电解质盐,其为(D)成分的二硅烷和使用用于电池的非水电解质溶液的非水电解质二次电池。
    • 9. 发明公开
    • NONAQUEOUS ELECTROLYTE SECONDARY BATTERY
    • EP2613395A4
    • 2016-12-28
    • EP11821523
    • 2011-08-08
    • ADEKA CORP
    • TAKI TAKAYUKIOHNUMA YUYUWATANABE HIROAKISHIBUYA ATSUKI
    • H01M10/0567B82Y30/00H01M4/02H01M4/58H01M4/587H01M10/0525H01M10/0569
    • H01M10/056B82Y30/00H01M4/5825H01M4/587H01M10/0525H01M10/0567H01M10/0569H01M2004/021H01M2004/027H01M2300/0025H01M2300/0028Y02E60/122Y02T10/7011
    • The present invention provides a non-aqueous electrolyte secondary battery that can improve the balance of the both of the output and capacity of the battery in the case when a negative electrode containing graphite particles having high crystallinity which have an exposed crystal face and are bonded with each other so as to be parallel to the orientation plane of each other as a negative electrode active material is used. Specifically, provided is a non-aqueous electrolyte secondary battery having a negative electrode containing graphite particles as a negative electrode active material, a positive electrode containing a lithium-containing oxide of a transition metal or a lithium-containing phosphate of a transition metal as a positive electrode active material, and a non-aqueous electrolyte in which a lithium salt is dissolved in an organic solvent, wherein the graphite particles have an exposed crystal face and are bonded with each other so as to be parallel to the orientation plane of each other, and the non-aqueous electrolyte contains a phosphate ester compound represented by the following general formula (1) to which an alkynyl group is bonded and/or an unsaturated phosphate ester compound represented by the following general formula (2): wherein R 1 and R 2 each independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atom(s), and R 3 represents an alkyl group having 1 to 8 carbon atom(s), an alkenyl group having 2 to 8 carbon atoms, an alkynyl group having 2 to 8 carbon atoms or a halogenated alkyl group having 1 to 8 carbon atom(s), wherein R 4 and R 5 each independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atom(s), R 6 represents an alkyl group having 1 to 8 carbon atom(s), an alkenyl group having 2 to 8 carbon atoms, an alkynyl group having 2 to 8 carbon atoms or a halogenated alkyl group having 1 to 8 carbon atom(s), and n represents a number of 1 or 2.