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    • 1. 发明专利
    • DE602005002866D1
    • 2007-11-29
    • DE602005002866
    • 2005-04-27
    • DAIDO STEEL CO LTDMITSUBISHI HEAVY IND LTD
    • UETA SHIGEKINODA TOSHIHARUYAMAMOTO RYUICHIKADOYA YOSHIKUNIMAGOSHI RYOTARONISHIMOTO SHIN
    • C22F1/10C22C19/03C22C19/05C22F1/00
    • The present invention provides a method for producing a low thermal expansion Ni-base superalloy, which includes: preparing an alloy including, by weight%, C: 0.15% or less, Si: 1% or less, Mn: 1% or less, Cr: 5 to 20%, at least one of Mo, W and Re, which satisfy the relationship Mo + 1/2(W + Re): 17 to 27%, Al: 0.1 to 2%, Ti: 0.1 to 2%, Nb and Ta, which satisfy the relationship Nb + Ta/2: 1.5% or less, Fe: 10% or less, Co: 5% or less, B: 0.001 to 0.02%, Zr: 0.001 to 0.2%, a reminder of Ni and inevitable components; subjecting the alloy to a solution heat treatment under the condition of at a temperature of 1000 to 1200°C; subjecting the alloy to either a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides under the conditions of at a temperature of not less than 850°C and less than 1000°C and for 1 to 50 hours, or a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides by cooling from the temperature in the solution heat treatment to 850°C at a cooling rate of 100°C or less per hour; subjecting the alloy to a first aging treatment for precipitating y' phase under the conditions of at a temperature of 720 to 900°C and for 1 to 50 hours; and subjecting the alloy to a second aging treatment for precipitating A 2 B phase under the conditions of at a temperature of 550 to 700°C and for 5 to 100 hours.
    • 3. 发明专利
    • AT376077T
    • 2007-11-15
    • AT05009211
    • 2005-04-27
    • DAIDO STEEL CO LTDMITSUBISHI HEAVY IND LTD
    • UETA SHIGEKINODA TOSHIHARUYAMAMOTO RYUICHIKADOYA YOSHIKUNIMAGOSHI RYOTARONISHIMOTO SHIN
    • C22F1/10C22C19/03C22C19/05C22F1/00
    • The present invention provides a method for producing a low thermal expansion Ni-base superalloy, which includes: preparing an alloy including, by weight%, C: 0.15% or less, Si: 1% or less, Mn: 1% or less, Cr: 5 to 20%, at least one of Mo, W and Re, which satisfy the relationship Mo + 1/2(W + Re): 17 to 27%, Al: 0.1 to 2%, Ti: 0.1 to 2%, Nb and Ta, which satisfy the relationship Nb + Ta/2: 1.5% or less, Fe: 10% or less, Co: 5% or less, B: 0.001 to 0.02%, Zr: 0.001 to 0.2%, a reminder of Ni and inevitable components; subjecting the alloy to a solution heat treatment under the condition of at a temperature of 1000 to 1200°C; subjecting the alloy to either a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides under the conditions of at a temperature of not less than 850°C and less than 1000°C and for 1 to 50 hours, or a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides by cooling from the temperature in the solution heat treatment to 850°C at a cooling rate of 100°C or less per hour; subjecting the alloy to a first aging treatment for precipitating y' phase under the conditions of at a temperature of 720 to 900°C and for 1 to 50 hours; and subjecting the alloy to a second aging treatment for precipitating A 2 B phase under the conditions of at a temperature of 550 to 700°C and for 5 to 100 hours.
    • 6. 发明专利
    • DE602005002866T2
    • 2008-07-24
    • DE602005002866
    • 2005-04-27
    • DAIDO STEEL CO LTDMITSUBISHI HEAVY IND LTD
    • UETA SHIGEKINODA TOSHIHARUYAMAMOTO RYUICHIKADOYA YOSHIKUNIMAGOSHI RYOTARONISHIMOTO SHIN
    • C22F1/10C22C19/03C22C19/05C22F1/00
    • The present invention provides a method for producing a low thermal expansion Ni-base superalloy, which includes: preparing an alloy including, by weight%, C: 0.15% or less, Si: 1% or less, Mn: 1% or less, Cr: 5 to 20%, at least one of Mo, W and Re, which satisfy the relationship Mo + 1/2(W + Re): 17 to 27%, Al: 0.1 to 2%, Ti: 0.1 to 2%, Nb and Ta, which satisfy the relationship Nb + Ta/2: 1.5% or less, Fe: 10% or less, Co: 5% or less, B: 0.001 to 0.02%, Zr: 0.001 to 0.2%, a reminder of Ni and inevitable components; subjecting the alloy to a solution heat treatment under the condition of at a temperature of 1000 to 1200°C; subjecting the alloy to either a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides under the conditions of at a temperature of not less than 850°C and less than 1000°C and for 1 to 50 hours, or a carbide stabilizing treatment for making aggregated carbides on grain boundaries and stabilizing the carbides by cooling from the temperature in the solution heat treatment to 850°C at a cooling rate of 100°C or less per hour; subjecting the alloy to a first aging treatment for precipitating y' phase under the conditions of at a temperature of 720 to 900°C and for 1 to 50 hours; and subjecting the alloy to a second aging treatment for precipitating A 2 B phase under the conditions of at a temperature of 550 to 700°C and for 5 to 100 hours.
    • 9. 发明专利
    • Ni-BASED AUSTENITIC SUPERALLOY WITH LOW THERMAL EXPANSION AND MANUFACTURING METHOD THEREFOR
    • 具有低热扩张性的镍基奥氏体超级合金及其制造方法
    • JP2003013161A
    • 2003-01-15
    • JP2001195741
    • 2001-06-28
    • Daido Steel Co LtdMitsubishi Heavy Ind Ltd三菱重工業株式会社大同特殊鋼株式会社
    • YAMAMOTO RYUICHIKADOYA YOSHIKUNIUMAGOE RYUTARONODA TOSHIHARUISOBE SUSUMUOKABE MICHIOKAWAI HISATAKA
    • F16J12/00C22C19/05
    • PROBLEM TO BE SOLVED: To provide a Ni-based austenitic superalloy with a low thermal expansion, having a coefficient of thermal expansion equal to that of a ferrite-based 12Cr steel, and high-temperature strength and corrosion/oxidation resistance equal to that of an austenite-based heat resistant alloy.
      SOLUTION: This super alloy includes carbon 0.15 mass% or less, silicon 1 mass% or less, manganese 1 mass% or less, chromium 5-20 mass%, molybdenum 17-26 mass%, aluminum 0.1-2.0 mass%, titanium 0.1-2.0 mass%, iron 10 mass% or less, boron 0.02 mass% or less, zirconium 0.2 mass% or less, tungsten, rhenium, and the balance substantially nickel, while the sum of aluminum and titanium content is 1-5.5 atom.%, satisfying the expression: 17≤Mo+(W+ Re)/2≤27, where Mo indicates a molybdenum content by mass%, W indicates a tungsten content by mass%, and Re indicates a rhenium content by mass%. The super alloy, further has a structure, in which a γ'-phase consisting of intermetallic compounds, and a A
      2 B-phase consisting of intermetallic compounds, form composite precipitates.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提供具有与铁素体系12Cr钢的热膨胀系数相当的热膨胀系数的具有低热膨胀系数的Ni基奥氏体超耐热合金,以及高温强度和耐腐蚀/抗氧化性等于 奥氏体型耐热合金。 解决方案:该超合金包括0.15质量%以下的碳,1质量%以下的硅,1质量%以下的锰,5〜20质量%的铬,17〜26质量%的铬,0.1〜2.0质量%的铝,0.1质量% -2.0质量%,铁10质量%以下,硼0.02质量%以下,0.2质量%以下的钨,铼,余量基本上为镍,铝和钛的总和为1-5.5原子。 %,满足以下表达式:17 <= Mo +(W + Re)/ 2 <= 27,其中Mo表示以质量%计含有的钼含量,W表示钨质量%,并且Re表示铼含量以质量%计。 超合金还具有由金属间化合物构成的γ'相和由金属间化合物构成的A2B相形成复合析出物的结构。