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1. 发明申请

US20060225349A1 Process and apparatus for thermally integrated hydrogen generation system 有权
标题翻译：热集成氢气发生系统的工艺和装置
公开(公告)号：US20060225349A1
公开(公告)日：2006-10-12
申请号：US11092555
申请日：2005-03-29
申请人： Curtis Krause , Kevin Nguyen , Bhaskar Balasubramanian , Yunquan Liu
发明人： Curtis Krause , Kevin Nguyen , Bhaskar Balasubramanian , Yunquan Liu
IPC分类号： C01B3/26
CPC分类号： C01B3/48 , B01J8/0257 , B01J19/2485 , B01J2208/00176 , B01J2208/00274 , B01J2208/00309 , B01J2208/00495 , B01J2208/0053 , B01J2208/025 , B01J2219/00006 , C01B2203/0233 , C01B2203/0283 , C01B2203/0844 , C01B2203/0894 , C01B2203/1241 , C01B2203/1294 , Y02P20/124 , Y02P20/125 , Y02P20/129
摘要： Relates to a process and apparatus that improves the hydrogen production efficiency for small scale hydrogen production. According to one aspect, the process provides heat exchangers that are thermally integrated with the reaction steps such that heat generated by exothermic reactions, combustion and water gas shift, are arranged closely to the endothermic reaction, steam reformation, and heat sinks, cool natural gas, water and air, to minimize heat loss and maximize heat recovery. Effectively, this thermally integrated process eliminates excess piping throughout, reducing initial capital cost.
摘要翻译：涉及提高小规模氢气生产的氢气生产效率的方法和装置。根据一个方面，该方法提供热交换器，其与反应步骤热集成，使得由放热反应，燃烧和水煤气变换产生的热量紧密地布置于吸热反应，蒸汽重整和散热器，冷却天然气，水和空气，以尽量减少热损失并最大限度地提高热回收率。有效地，这种热综合过程消除了多余的管道，降低了初始资本成本。

2. 发明授权

US07964176B2 Process and apparatus for thermally integrated hydrogen generation system 有权
标题翻译：热集成氢气发生系统的工艺和装置
公开(公告)号：US07964176B2
公开(公告)日：2011-06-21
申请号：US11092555
申请日：2005-03-29
申请人： Curtis L. Krause , Kevin H. Nguyen , Bhaskar Balasubramanian , Yunquan Liu , Jeroen Valensa , Michael J. Reinke , Mark G. Voss , Todd M. Bandhauer
发明人： Curtis L. Krause , Kevin H. Nguyen , Bhaskar Balasubramanian , Yunquan Liu , Jeroen Valensa , Michael J. Reinke , Mark G. Voss , Todd M. Bandhauer
IPC分类号： F28F1/00 , C01B3/26
CPC分类号： C01B3/48 , B01J8/0257 , B01J19/2485 , B01J2208/00176 , B01J2208/00274 , B01J2208/00309 , B01J2208/00495 , B01J2208/0053 , B01J2208/025 , B01J2219/00006 , C01B2203/0233 , C01B2203/0283 , C01B2203/0844 , C01B2203/0894 , C01B2203/1241 , C01B2203/1294 , Y02P20/124 , Y02P20/125 , Y02P20/129
摘要： Relates to a process and apparatus that improves the hydrogen production efficiency for small scale hydrogen production. According to one aspect, the process provides heat exchangers that are thermally integrated with the reaction steps such that heat generated by exothermic reactions, combustion and water gas shift, are arranged closely to the endothermic reaction, steam reformation, and heat sinks, cool natural gas, water and air, to minimize heat loss and maximize heat recovery. Effectively, this thermally integrated process eliminates excess piping throughout, reducing initial capital cost.
摘要翻译：涉及提高小规模氢气生产的氢气生产效率的方法和装置。根据一个方面，该方法提供热交换器，其与反应步骤热集成，使得由放热反应，燃烧和水煤气变换产生的热量紧密地布置于吸热反应，蒸汽重整和散热器，冷却天然气，水和空气，以尽量减少热损失并最大限度地提高热回收率。有效地，这种热综合过程消除了多余的管道，降低了初始资本成本。

3. 发明申请

US20140230317A1 In-Situ Upgrading Of Biomass Pyrolysis Vapor Using Water-Gas Shift And Hydroprocessing 审中-公开
标题翻译：使用水煤气转换和加氢处理原位升级生物质热解蒸气
公开(公告)号：US20140230317A1
公开(公告)日：2014-08-21
申请号：US13772738
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/18
CPC分类号： C10L1/02 , C10B49/10 , C10B53/02 , C10G3/46 , C10G2300/4006 , C10G2300/4012 , C10G2300/42 , C10K1/026 , C10K3/02 , C10K3/04 , C10L1/023 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , C10L2290/02 , C10L2290/562 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with a water-gas shift reaction catalyst and a hydrotreating catalyst, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。这些步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使热解蒸汽与水煤气变换反应催化剂和加氢处理催化剂接触，并将所得升级的热解蒸汽转化成液体产品。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

4. 外观设计

USD676597S1 Lighting fixture 有权
公开(公告)号：USD676597S1
公开(公告)日：2013-02-19
申请号：US29422013
申请日：2012-05-15
申请人： Ming-Wei Zhu , Yunquan Liu
设计人： Ming-Wei Zhu , Yunquan Liu

5. 发明申请

US20080141675A1 Hybrid Combustor for Fuel Processing Applications 有权
标题翻译：燃料加工应用的混合燃烧器
公开(公告)号：US20080141675A1
公开(公告)日：2008-06-19
申请号：US11610983
申请日：2006-12-14
申请人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
发明人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
IPC分类号： F23Q11/00
CPC分类号： F23C13/06 , F23C2900/03002
摘要： The present invention discloses a hybrid combustor, such as an anode tailgas oxidizer (ATO), for fuel processing applications which combines both flame and catalytic type burners. The hybrid combustor of the present invention combines the advantages of both flame and catalytic type burners. The flame burner component of the hybrid combustor is used during start-up for the preheating of the catalytic burner component. As soon as the catalytic burner bed is preheated or lit off, the flame burner will be shut off. Optionally, the hybrid combustor may also include an integrated heat recovery unit located downstream of the catalytic burner for steam generation and for the preheating of the feed for a reformer, such as an autothermal reformer.
摘要翻译：本发明公开了一种混合式燃烧器，例如阳极尾气氧化器（ATO），用于结合火焰和催化型燃烧器的燃料处理应用。本发明的混合燃烧器结合了火焰和催化型燃烧器的优点。在启动期间使用混合燃烧器的火焰燃烧器部件来预热催化燃烧器部件。一旦催化燃烧器床被预热或点亮，火焰燃烧器将被关闭。可选地，混合式燃烧室还可以包括位于用于蒸汽产生的催化燃烧器下游并用于预热重整器例如自热重整器的进料的集成热回收单元。

6. 发明授权

US08062392B2 Small distributed gasification units with syngas transportation via pipeline network for biomass treatment 有权
标题翻译：小型分布式气化装置，通过管道网络进行合成气运输，用于生物质处理
公开(公告)号：US08062392B2
公开(公告)日：2011-11-22
申请号：US12336928
申请日：2008-12-17
申请人： Paul F. Bryan , Yunquan Liu , Curtis L. Krause
发明人： Paul F. Bryan , Yunquan Liu , Curtis L. Krause
IPC分类号： C10B1/00 , C10J3/00 , C10J3/72 , B01J19/00
CPC分类号： C10J3/721 , C10J3/00 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1618 , C10J2300/1659 , C10K1/004 , C10K1/008 , C10K3/026 , C10K3/04 , Y02E20/18 , Y02P20/145 , Y02P20/146
摘要： The present invention discloses a system for biomass treatment which addresses the need to find economical solutions to transport biomass. In the present invention, small, distributed gasifiers convert the biomass into synthesis gas (“syngas”). The syngas is then transported via a pipeline network to a central fuel production facility.
摘要翻译：本发明公开了一种用于生物质处理的系统，其满足了寻找运输生物质的经济解决方案的需要。在本发明中，小型分布式气化器将生物质转化为合成气（“合成气”）。合成气然后通过管道网络运输到中央燃料生产设施。

7. 发明申请

US20080145309A1 Fluidized Bed System for Single Step Reforming for the Production of Hydrogen 有权
标题翻译：用于氢气生产的单步重整流化床系统
公开(公告)号：US20080145309A1
公开(公告)日：2008-06-19
申请号：US11611638
申请日：2006-12-15
申请人： Farshad Bavarian , James F. Stevens , Balaji Krishnamurty , Yunquan Liu , Curtis L. Krause , Lixin You , Daniel G. Casey
发明人： Farshad Bavarian , James F. Stevens , Balaji Krishnamurty , Yunquan Liu , Curtis L. Krause , Lixin You , Daniel G. Casey
IPC分类号： F27B15/00
CPC分类号： F27B15/00 , B01J8/0055 , B01J8/1809 , B01J8/1863 , B01J2208/00292 , B01J2208/00752 , B01J2208/00761 , C01B3/44 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0425 , C01B2203/0475 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/148 , C01B2203/86 , C01F11/18 , Y02P10/122 , Y02P10/143 , Y02P30/30
摘要： The present invention discloses a fluidized bed system for the single step reforming technology for the production of hydrogen. Single step reforming combines the steam methane reforming, water gas shift, and carbon dioxide removal in a single step process of hydrogen generation. In the present invention, to address the heat transfer and the replenishment issues associated with single step reforming, the sorbent particles are fluidized. This fluidization allows the sorbent particles to be regenerated and consequently allows the optimal operating conditions for single step reforming to be maintained.
摘要翻译：本发明公开了一种用于生产氢气的单步重整技术的流化床系统。单步重整在氢气生成的一个单步过程中结合蒸汽甲烷重整，水煤气变换和二氧化碳去除。在本发明中，为了解决与单步重整相关的传热和补充问题，吸附剂颗粒被流化。这种流化允许吸附剂颗粒再生，因此允许保持单步重整的最佳操作条件。

8. 发明申请

US20140230319A1 IN-SITU UPGRADING OF BIOMASS PYROLYSIS VAPOR USING ACID CATALYST AND ALCOHOL 审中-公开
标题翻译：使用酸性催化剂和酒精的生物质热解蒸发器的现场升级
公开(公告)号：US20140230319A1
公开(公告)日：2014-08-21
申请号：US13772700
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/19
CPC分类号： C10L1/19 , C10G3/42 , C10G3/46 , C10G3/48 , C10G3/50 , C10G67/02 , C10G2400/02 , C10G2400/04 , C10L1/02 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with an acid catalyst in the presence of alcohol, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。这些步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使热解蒸汽在醇存在下与酸催化剂接触，并将所得升级的热解蒸汽转化成液体产物。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

9. 发明申请

US20140230318A1 In-Situ Upgrading Of Biomass Pyrolysis Vapor By Cracking And Hydroprocessing 审中-公开
标题翻译：通过裂解和加氢处理原位升级生物质热解蒸气
公开(公告)号：US20140230318A1
公开(公告)日：2014-08-21
申请号：US13772749
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/18
CPC分类号： C10L1/1802 , C10G3/42 , C10G3/46 , C10G3/48 , C10G3/50 , C10G67/02 , C10G2400/02 , C10G2400/04 , C10L1/06 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with a cracking catalyst, a water-gas shift reaction catalyst, and a hydrotreating catalyst, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。这些步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使裂解蒸气与裂化催化剂，水煤气变换反应催化剂和加氢处理催化剂接触，并将所得到的升级热解蒸气成液体产物。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

10. 发明授权

US07578669B2 Hybrid combustor for fuel processing applications 有权
标题翻译：用于燃料处理应用的混合燃烧器
公开(公告)号：US07578669B2
公开(公告)日：2009-08-25
申请号：US11610983
申请日：2006-12-14
申请人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
发明人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
IPC分类号： C10L3/00 , F23D3/40
CPC分类号： F23C13/06 , F23C2900/03002
摘要： The present invention discloses a hybrid combustor, such as an anode tailgas oxidizer (ATO), for fuel processing applications which combines both flame and catalytic type burners. The hybrid combustor of the present invention combines the advantages of both flame and catalytic type burners. The flame burner component of the hybrid combustor is used during start-up for the preheating of the catalytic burner component. As soon as the catalytic burner bed is preheated or lit off, the flame burner will be shut off. Optionally, the hybrid combustor may also include an integrated heat recovery unit located downstream of the catalytic burner for steam generation and for the preheating of the feed for a reformer, such as an autothermal reformer.
摘要翻译：本发明公开了一种混合式燃烧器，例如阳极尾气氧化器（ATO），用于结合火焰和催化型燃烧器的燃料处理应用。本发明的混合燃烧器结合了火焰和催化型燃烧器的优点。在启动期间使用混合燃烧器的火焰燃烧器部件来预热催化燃烧器部件。一旦催化燃烧器床被预热或点亮，火焰燃烧器将被关闭。可选地，混合式燃烧室还可以包括位于用于蒸汽产生的催化燃烧器下游并用于预热重整器例如自热重整器的进料的集成热回收单元。

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