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    • 3. 发明公开
    • COMPOSITION DE CAOUTCHOUC POUR PNEUMATIQUE COMPORTANT UN AGENT DE COUPLAGE AZOSILANE
    • GUMMIREIFENZUSAMMENSETZUNG MIT EINEM AZO-SILUP-KUPPLER
    • EP3134472A1
    • 2017-03-01
    • EP15716064.9
    • 2015-04-16
    • Compagnie Générale des Etablissements MichelinMichelin Recherche et Technique S.A.
    • MOUGIN, CatherineVEYLAND, AnnePETERLE, TorstenKECK, JuliaERHARDT, SaschaBLUME, AnkeRÖBEN, Caren
    • C08K5/5455C08K5/548B60C1/00C08K3/36
    • C08K5/5455B60C1/0016C08K3/36C08K5/548C08L7/00
    • The invention concerns a rubber tyre composition made from at least one diene elastomer, an inorganic filler as a reinforcing filler, a coupling agent linking the inorganic filler and the diene elastomer, characterised in that the coupling agent is an azo-silane compound of the following formula (I): (G
      1 )
      3-a (G
      2 )
      a Si-Z-NH-C(O)-N=N-G4 (I) in which: - G
      1 , identical or different, each represent a monovalent hydrocarbon group chosen from the linear or branched, substituted or unsubstituted alkyls having 1 to 18 carbon atoms, the substituted or unsubstituted cycloalkyls or aryls having from 5 to 18 carbon atoms, - G
      2 , identical or different, each represent a hydroxyl group or a monovalent group in the form (G
      3 )
      n -OG
      1 , in which G
      3 is a divalent linking group comprising 1 to 18 carbon atoms and containing one or more heteroatoms chosen from O, S, Si and N, and n is a number greater than or equal to 0 and less than or equal to 18, - G
      4 represents an aromatic or heteroaromatic, substituted or unsubstituted group, or a substituted or unsubstituted alkyl group, - Z represents a divalent linking group comprising 1 to 18 carbon atoms, - a is equal to 1, 2 or 3.
    • 本发明涉及由至少一种二烯弹性体,无机填料作为增强填料制成的橡胶轮胎组合物,连接无机填料和二烯弹性体的偶联剂,其特征在于偶联剂是下列的偶氮硅烷化合物 式(I):(G1)3-a(G2)aSi-Z-NH-C(O)-N = N-G4(I)其中:-G1相同或不同,各自表示选择的一价烃基 来自具有1至18个碳原子的直链或支链的取代或未取代的烷基,取代或未取代的具有5至18个碳原子的环烷基或芳基,相同或不同,各自表示羟基或单价基团 形式(G3)n-OG1,其中G3是包含1至18个碳原子并含有一个或多个选自O,S,Si和N的杂原子的二价连接基团,n是大于或等于0的数, 小于或等于18,-G4表示芳族或杂芳族,取代或未取代的 取代基或取代或未取代的烷基,-Z表示包含1至18个碳原子的二价连接基团,a等于1,2或3。
    • 8. 发明授权
    • COMPOSITION DE CAOUTCHOUC POUR PNEUMATIQUE A BASE D UN ALUMINOSILICATE RENFORCANT
    • 成分DE CAOUCHOUC POUR PNEUMATIQUE A BASE D UN ALUMINOSILICATE RENFORCANT
    • EP1576043B8
    • 2012-08-01
    • EP03789182.7
    • 2003-12-09
    • Compagnie Générale des Etablissements MichelinMichelin Recherche et Technique S.A.
    • SIMONOT, LaureVEYLAND, AnneLAPRA, ArnaudCUSTODERO, Emmanuel
    • C08K3/34C08L9/00C08L7/00C08J5/12B60C1/00
    • B60C1/0016B60C1/00C08K3/34C08L21/00
    • The invention relates to a rubber composition which can be used to produce tyres and which is based on at least one diene elastomer, an inorganic reinforcing filler and a coupling agent which is used to join the inorganic filler and the elastomer. The inventive composition is characterised in that the aforementioned inorganic filler comprises a synthetic aluminosilicate having formula (I) Mx Si Aly Oa (OH)b, (H20)c, wherein: M is a cation which is selected from the group comprising K+, Na+, Ca++ and mixtures of said cations; x > 0; y > 0; a ≥ 0; b ≥ 0, c ≥ 0 and a+b > 0, and having the following characteristics: (a) a specific surface area (BET) of between 20 and 300 m2/g; (b) an average particle size in mass (dW) of between 20 and 400 nm; and (c) a deagglomeration speed (α), using ultrasound, which is greater than 5.10-4 µm-1/min. The invention also relates to the use of one such rubber composition for the production of rubber articles, in particular tyres or semi-finished rubber products, such as treads, which are intended for tyres.
    • 本发明涉及可用于生产轮胎并且基于至少一种二烯弹性体,无机增强填料和用于连接无机填料和弹性体的偶联剂的橡胶组合物。 本发明的组合物的特征在于上述无机填料包含具有式(I)的合成硅铝酸盐:其中:M是选自K +,Na + ,Ca ++和所述阳离子的混合物; x> 0; y> 0; a≥0; b≥0,c≥0和a + b> 0,并且具有以下特征:(a)比表面积(BET)为20-300m 2 / g; (b)平均粒径(dW)为20-400nm; 和(c)使用超过5.10-4μm-1 / min的超声波的解聚速度(α)。 本发明还涉及一种这样的橡胶组合物用于生产橡胶制品,特别是用于轮胎的轮胎或半成品橡胶制品如胎面。