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    • 1. 发明申请
    • FURTHER REACTED HALOGEN OR EPOXY LINKER-ALKOXY COMPOUND PRODUCT AS SUFACTANT
    • 进一步反应的卤化物或环氧连接体 - 烷氧基化合物产品作为反应物
    • WO2002081538A1
    • 2002-10-17
    • PCT/US2002/010330
    • 2002-04-04
    • COGNIS CORPORATION
    • WIGGINS, Michael, S.BROADBENT, Ronald, W.NARAYAN, Ramesh, L.KHAN, Ayaz
    • C08G18/48
    • C08G65/337C08G18/283C08G65/327C08G65/329C08G65/3322C08G65/33348C08L71/02C08L63/00
    • Compounds useful in the dual function as surfactants as well as defoaming agents and wetting agents are prepared from the reaction of (I) the reaction product of A) a linking agent of formula 1 R 4 (Y) 3 wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an oxygen atom, which is attached to two adjacent carbon atoms in the R 4 group to form an epoxy group, and R 4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound formula (II) R 3 (EO) n (PO) m (BO) p X wherein R 3 is a substituted or unsubstituted, saturated or unsaturated, aliphatic or araliphatic oxy or thio group having from 1 to 36 carbon atoms or a secondary amino group having from 2 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or a mercapto or amino group in place of a terminal -OH group, provided that when X is mercapto or amino; the sum of n, m, and p must be at least one; the mole ratio of A:B is from about 0:2:1 to about 5:1; and (II) an epoxy compound, isocyanate, phosphate compound, sulfate compound, organic acid, acrylate or methylol urea as a reactant.
    • 通过(I)A)式1 R 4(Y)3的连接剂的反应产物的反应制备用作表面活性剂和消泡剂和润湿剂的双重功能的化合物,其中每个Y基团为 卤素原子或一个Y基团是卤素原子,两个Y基团表示氧原子,其与R 4基团中的两个相邻的碳原子连接以形成环氧基团,并且R 4是烷三基 含有3至10个碳原子; 和B)化合物式(II)R 3(EO)n(PO)m(BO)pX其中R 3是具有1至36个碳的取代或未取代的饱和或不饱和的脂族或芳脂族氧基或硫基 原子或具有2至36个碳原子的仲氨基; n为0〜50的数; m是从0到50的数字; p是从0到50的数字; X为氢或巯基或氨基而不是末端-OH基团,条件是当X为巯基或氨基时; n,m和p的和必须至少为1; A:B的摩尔比为约0:2:1至约5:1; 和(II)作为反应物的环氧化合物,异氰酸酯,磷酸酯化合物,硫酸酯化合物,有机酸,丙烯酸酯或羟甲基脲。