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1. 发明授权

US09399206B2 Process for producing encapsulated metal colloids as inorganic coloured pigments 有权
标题翻译：作为无机着色颜料生产封装金属胶体的方法
公开(公告)号：US09399206B2
公开(公告)日：2016-07-26
申请号：US13514484
申请日：2010-12-15
申请人： Claudia Fink-Straube , Kira Fries , Martin Mennig , Dieter Anschutz , Sarah Schumacher , Peter William De Oliveira , Masahiko Ishii , Wataru Murata , Veronique Vandenberghe
发明人： Claudia Fink-Straube , Kira Fries , Martin Mennig , Dieter Anschutz , Sarah Schumacher , Peter William De Oliveira , Masahiko Ishii , Wataru Murata , Veronique Vandenberghe
IPC分类号： C09C1/28 , B29B9/10 , B01J13/00
CPC分类号： B01J13/0043 , B01J13/0091
摘要： A process for producing encapsulated metal colloids useful as inorganic colored pigments, including, reacting one or more glass-forming components according to the sol-gel process to obtain a sol dispersing a metal salt in the resulting sol in the presence of an additional reducing agent to form metal colloids, converting the resulting dispersion into xerogel-encapsulated metal colloids by spray drying, heating the resulting xerogel-encapsulated metal colloids to density them. The present invention relates, furthermore, to inorganic colored pigments, in particular producible by the process of the invention, including metal colloids produced from metal salts and encapsulated in an encapsulation, the encapsulation being produced from glass-forming components according to the sol-gel process and being densified to a xerogel or glass, the proportion of metal colloid in the capsules being at least 80%.
摘要翻译：一种制备用作无机着色颜料的包封金属胶体的方法，包括根据溶胶 - 凝胶法使一种或多种玻璃形成成分反应，得到在所得溶胶中分散金属盐的溶胶，在另外的还原剂存在下形成金属胶体，通过喷雾干燥将所得到的分散体转化成干凝胶包封的金属胶体，加热得到的干凝胶包封的金属胶体以使其密实。本发明还涉及无机着色颜料，特别是可通过本发明的方法生产，包括由金属盐制备并包封在包封中的金属胶体，该封装由根据溶胶 - 凝胶的玻璃形成组分制备过程并致密化为干凝胶或玻璃，胶囊中金属胶体的比例为至少80％。

2. 发明申请

US20120266780A1 PROCESS FOR PRODUCING ENCAPSULATED METAL COLLOIDS AS INORGANIC COLOURED PIGMENTS 有权
标题翻译：用于生产作为无机颜料的颜料的金属胶体的方法
公开(公告)号：US20120266780A1
公开(公告)日：2012-10-25
申请号：US13514484
申请日：2010-12-15
申请人： Claudia Fink-Straube , Kira Fries , Martin Mennig , Dieter Anschutz , Sarah Schumacher , Peter William De Oliveira , Masahiko Ishii , Wataru Murata , Veronique Vandenberghe
发明人： Claudia Fink-Straube , Kira Fries , Martin Mennig , Dieter Anschutz , Sarah Schumacher , Peter William De Oliveira , Masahiko Ishii , Wataru Murata , Veronique Vandenberghe
IPC分类号： C09C1/28 , C09C1/22 , B29B9/10 , C09C1/14
CPC分类号： B01J13/0043 , B01J13/0091
摘要： A process for producing encapsulated metal colloids useful as inorganic coloured pigments, including, reacting one or more glass-forming components according to the sol-gel process to obtain a sol dispersing a metal salt in the resulting sol in the presence of an additional reducing agent to form metal colloids, converting the resulting dispersion into xerogel-encapsulated metal colloids by spray drying, heating the resulting xerogel-encapsulated metal colloids to density them. The present invention relates, furthermore, to inorganic coloured pigments, in particular producible by the process of the invention, including metal colloids produced from metal salts and encapsulated in an encapsulation, the encapsulation being produced from glass-forming components according to the sol-gel process and being densified to a xerogel or glass, the proportion of metal colloid in the capsules being at least 80%.
摘要翻译：一种制备用作无机着色颜料的包封金属胶体的方法，包括根据溶胶 - 凝胶法使一种或多种玻璃形成成分反应，得到在所得溶胶中分散金属盐的溶胶，在另外的还原剂存在下形成金属胶体，通过喷雾干燥将所得到的分散体转化成干凝胶包封的金属胶体，加热得到的干凝胶包封的金属胶体以使其密实。本发明还涉及无机着色颜料，特别是可通过本发明的方法生产，包括由金属盐制备并包封在包封中的金属胶体，该封装由根据溶胶 - 凝胶的玻璃形成组分制备过程并致密化为干凝胶或玻璃，胶囊中金属胶体的比例为至少80％。

3. 发明授权

US06463760B1 Method for the production of optical layers having uniform layer thickness 失效
标题翻译：用于生产具有均匀层厚度的光学层的方法
公开(公告)号：US06463760B1
公开(公告)日：2002-10-15
申请号：US09763644
申请日：2001-02-23
申请人： Claudia Fink-Straube , Axel Kalleder , Thomas Koch , Martin Mennig , Helmut Schmidt
发明人： Claudia Fink-Straube , Axel Kalleder , Thomas Koch , Martin Mennig , Helmut Schmidt
IPC分类号： C03B800
CPC分类号： G02B1/10
摘要： The wet film thickness during spraying of the coating composition onto the substrate is preferably adjusted such that it is greater by a factor of at least 8 than the target dry film thickness.
摘要翻译：优选将涂料组合物喷涂到基材上时的湿膜厚度调节至比目标干膜厚度大至少8倍。

4. 发明授权

US5731091A Process for producing functional vitreous layers 失效
标题翻译：生产功能性玻璃体层的方法
公开(公告)号：US5731091A
公开(公告)日：1998-03-24
申请号：US635971
申请日：1996-08-01
申请人： Helmut Schmidt , Martin Mennig , Thomas Burkhart , Claudia Fink-Straube , Gerhard Jonschker , Mike Schmitt , Annette Bauer
发明人： Helmut Schmidt , Martin Mennig , Thomas Burkhart , Claudia Fink-Straube , Gerhard Jonschker , Mike Schmitt , Annette Bauer
IPC分类号： C03C14/00 , C03C17/00 , C03C17/30 , C04B41/50 , C04B41/86 , C23C18/12 , B05D5/06
CPC分类号： C03C14/004 , C03C14/006 , C03C14/008 , C03C17/007 , C03C17/008 , C03C17/009 , C04B41/5022 , C04B41/86 , C03C2214/32 , C03C2217/485 , C03C2217/92
摘要： To produce functional vitrous, preferably colored or colloid-dyed layers, a composition produced by hydrolysis and polycondensation of (A) at least on hydrolyzable silane of general formula (I) SiX.sub.4 (I) wherein the radicals X are the same or different and represent hydrolyzable groups or hydroxy groups, or an oligomer derived therefrom, and (B) at least one organosilane of general formula (II) R.sup.1.sub.a R.sup.2.sub.b SiX.sub.(4-a-b) (II) wherein R.sup.1 is a non-hydrolyzable radical, R.sup.2 represents a radical carrying a functional group, X has the meaning given above, and a and b have the values 0, 1, 2 or 3, the sum (a+b) having the values 1, 2 or 3, or an oligomer derived therefrom with an (A):(B) substance ratio of 5-50:50-95, and optionally (C) one or more compounds of glass-forming elements, is mixed with at least one function carrier from the group of temperature-stable dyes or pigments, metallic or non-metallic oxides, coloring metallic ions, metallic or metallic compound colloids, and metal ions that react under reduction conditions to form metallic colloids; the composition mixed with the function carrier is applied onto a substrate and the coating is thermally condensed to form a vitreous layer.
摘要翻译： PCT No.PCT / EP94 / 03423 Sec。 371日期：1996年8月1日 102（e）日期1996年8月1日PCT 1994年10月18日PCT PCT。公开号WO95 / 13249 日期1995年5月18日为了生产功能性玻璃色，优选着色或胶体染色层，通过（A）至少在通式（I）SiX 4（I）的可水解硅烷上进行水解和缩聚制备的组合物，其中基团X相同或者不同，表示可水解基团或羟基，或由其衍生的低聚物，和（B）至少一种通式（II）的有机硅烷R 1 a R 2 b SiX（4-ab）（II）其中R 1是不可水解的基团，带有官能团的基团X具有上述含义，a和b具有值0,1,2或3，具有值1,2或3的和（a + b）或由其衍生的低聚物（A）：（B）的物质比例为5-50:50-95，和任选的（C）一种或多种玻璃形成元素化合物，与至少一种功能性载体从温度稳定的染料或颜料，金属或非金属氧化物，着色金属离子，金属或金属化合物胶体和金属在还原条件下反应形成金属胶体的离子; 将与功能性载体混合的组合物施加到基材上，并将涂层热凝聚以形成玻璃质层。

5. 发明授权

US06639039B1 Photochromic coating composition comprising nanoscales particles and process for providing substrate coated with the same 失效
标题翻译：包含纳米尺寸颗粒的光致变色涂料组合物和用于提供用其涂布的基材的方法
公开(公告)号：US06639039B1
公开(公告)日：2003-10-28
申请号：US09601423
申请日：2000-07-31
申请人： Kira Fries , Lisong Hou , Marion Pietsch , Martin Mennig , Helmut Schmidt
发明人： Kira Fries , Lisong Hou , Marion Pietsch , Martin Mennig , Helmut Schmidt
IPC分类号： C08G7720
CPC分类号： G02B5/23 , C03C17/006 , C03C17/009 , C03C2217/40 , C03C2217/478 , C08G59/1433 , C09D163/00 , C09D183/06 , C09D183/14 , C09D185/00 , C09K9/02 , Y10S977/778 , Y10S977/813 , Y10S977/834 , Y10S977/897 , C08L2666/28
摘要： A photochromic coating composition contains a silicon-containing precondensate derived from a hydrolysable silane containing a polymerizable functional group on a hydrolysis-stable radical, a photochromic dye, a stabilizer, and nanoscale particles. The coating composition, when applied to transparent plastic and glass substrates and cured, gives a coating having high light stability and good scratch resistance.
摘要翻译：光致变色涂料组合物含有衍生自在水解稳定基团上含有可聚合官能团的可水解硅烷，光致变色染料，稳定剂和纳米级颗粒的含硅预缩合物。涂料组合物当应用于透明塑料和玻璃基材并固化时，得到具有高光稳定性和良好耐擦伤性的涂层。

6. 发明授权

US06303730B1 Organic/inorganic composites with low hydroxyl group content, method for their production and application 失效
标题翻译：低羟基含量的有机/无机复合材料，其生产和应用方法
公开(公告)号：US06303730B1
公开(公告)日：2001-10-16
申请号：US09367884
申请日：1999-08-19
申请人： Kira Fries , Martin Mennig , Helmut Schmidt , Ulrich Sohling , Qiwu Xing , Michael Zahnhausen
发明人： Kira Fries , Martin Mennig , Helmut Schmidt , Ulrich Sohling , Qiwu Xing , Michael Zahnhausen
IPC分类号： C08G7706
CPC分类号： C08G77/58 , C08F299/02 , C08G77/20 , C08G77/24 , C09K3/1018
摘要： The invention relates to transparent organic/inorganic composites with low hydroxyl group content, based on silicic acid heteropolycondensates having extremely low water uptakes. These composites are obtained for example by nonhydrolytic condensation of chlorosilanes with polymerizable groups and optionally fluorinated groups, with the help of a condensation agent (e.g., t-butanol) capable of non-hydrolytic condensation of this chlorosilane, and thermal and/or photochemical polymerization of the obtained condensation product, preferably in the presence of preferably fluorinated organic monomers.
摘要翻译：本发明涉及具有低羟基含量的透明有机/无机复合材料，其基于具有非常低的吸水量的硅酸杂多糖缩合物。这些复合物例如通过氯代硅烷与可聚合基团和任选的氟化基团的非水解缩合获得，借助于能够使该氯硅烷无水解缩合的缩合剂（例如，叔丁醇）和热和/或光化学聚合的所得缩合产物，优选在优选氟化有机单体存在下进行。

7. 发明授权

US08034435B2 Plastic film with a multilayered interference coating 有权
标题翻译：塑料薄膜与多层干涉涂层
公开(公告)号：US08034435B2
公开(公告)日：2011-10-11
申请号：US10508193
申请日：2003-03-14
申请人： Andreas Zimmermann , Fumio Kita , Anette Berni , Martin Mennig , Peter W. Oliveira , Helmut Schmidt , Takamasa Harada
发明人： Andreas Zimmermann , Fumio Kita , Anette Berni , Martin Mennig , Peter W. Oliveira , Helmut Schmidt , Takamasa Harada
IPC分类号： B32B7/02
CPC分类号： G02B5/0841 , B32B27/06 , C08J7/047 , C08J7/16 , G02B1/11 , Y10T428/24942 , Y10T428/256
摘要： The invention relates to a plastic film with an interference multilayer system applied thereon that comprises at least two layers. Said layers can be obtained by hardening and/or applying thermal treatment to a coating composition containing nanoscale inorganic solid particles having polymerizable and/or polycondensable organic surface groups, thereby forming a layer that is crosslinked by means of the polymerizable and/or polycondensable organic surface groups. The films can be used as an optical laminating film.
摘要翻译：本发明涉及一种其上施加有干涉多层系统的塑料膜，其包括至少两层。所述层可以通过硬化和/或施加热处理获得，所述涂层组合物含有具有可聚合和/或可缩聚有机表面基团的纳米级无机固体颗粒，由此形成通过可聚合和/或可缩聚有机表面交联的层团体这些膜可以用作光学层压膜。

8. 发明申请

US20100028631A1 FINE INTERFERENCE PIGMENTS CONTAINING GLASS LAYERS ON METAL, GLASS AND CERAMIC SURFACES AND METHOD FOR PRODUCTION THEREOF 审中-公开
标题翻译：包含金属，玻璃和陶瓷表面的玻璃层的精细干涉性颜料及其生产方法
公开(公告)号：US20100028631A1
公开(公告)日：2010-02-04
申请号：US12519102
申请日：2008-02-15
申请人： Martin Mennig , Helmut Schmidt
发明人： Martin Mennig , Helmut Schmidt
IPC分类号： B32B3/10 , B05D5/00 , C09D11/02
CPC分类号： C23C18/1283 , C08K3/34 , C08K9/04 , C09D7/61 , C09D11/037 , C23C18/1212 , C23C18/1241 , C23C18/1254 , C23C18/127 , C23C18/1275 , C23C18/1279 , Y02T50/6765 , Y10T428/24901
摘要： A process for providing a substrate having a metal, glass or ceramic surface with a vitreous layer comprising an interference pigment. The process comprises comminuting an interference pigment having at least one dielectric interference layer by a wet grinding process; dispersing the comminuted interference pigment into a silicate-containing suspension to obtain a coating composition; applying the coating composition to the surface by a wet coating process; and densifying the coating composition at a temperature of not more than 650° C.
摘要翻译：一种用于提供具有金属，玻璃或陶瓷表面的基底的方法，其具有包含干涉颜料的玻璃质层。该方法包括通过湿磨研磨粉碎具有至少一个介电干涉层的干涉颜料; 将粉碎的干涉颜料分散在含硅酸盐的悬浮液中以获得涂料组合物; 通过湿式涂布方法将涂料组合物施加到表面; 并在不超过650℃的温度下使涂料组合物致密化。

9. 发明授权

US07390532B2 Method for the production of optical elements with gradient structures 有权
标题翻译：用于生产具有梯度结构的光学元件的方法
公开(公告)号：US07390532B2
公开(公告)日：2008-06-24
申请号：US10885618
申请日：2004-07-08
申请人： Ulrike Dellwo , Martin Mennig , Peter W. Oliveira , Helmut Schmidt , Heike Schneider
发明人： Ulrike Dellwo , Martin Mennig , Peter W. Oliveira , Helmut Schmidt , Heike Schneider
IPC分类号： B05D5/06
CPC分类号： G02B6/13 , C08F283/12 , C08F283/124 , C08L51/085 , G02B3/0087 , Y10T428/31507 , C08L2666/02 , C08L2666/14
摘要： A process for producing an optical element having a gradient structure, wherein a potential difference is generated in a nanocomposite material comprising nanoscale particles in a matrix material to cause a directed diffusion of the nanoscale particles in the matrix material and a concentration gradient of the nanoscale particles in the matrix material.
摘要翻译：一种用于制造具有梯度结构的光学元件的方法，其中在纳米复合材料中产生电位差，所述纳米复合材料包含基质材料中的纳米级颗粒，以引起纳米尺度颗粒在基体材料中的定向扩散，以及纳米尺度颗粒的浓度梯度在基质材料中。

10. 发明授权

US06919444B2 Magnetic particles for purifying nucleic acids 有权
标题翻译：用于纯化核酸的磁性颗粒
公开(公告)号：US06919444B2
公开(公告)日：2005-07-19
申请号：US10371375
申请日：2003-02-20
申请人： Herbert Harttig , Michael Riedling , Martin Mennig , Helmut Schmidt
发明人： Herbert Harttig , Michael Riedling , Martin Mennig , Helmut Schmidt
IPC分类号： C12N15/00 , B01D15/08 , B01J2/00 , B03C1/00 , B03C1/01 , B22F1/02 , C03B8/02 , C03C3/091 , C03C3/093 , C04B35/653 , C12M1/00 , C12N15/09 , C12N15/10 , C12Q1/68 , H01F1/00 , H01F1/11 , H01F1/24 , C07H21/04
CPC分类号： B82Y25/00 , B03C1/01 , C12N15/1006 , C12N15/1013 , C12Q1/6806 , H01F1/11 , H01F1/112 , Y10T428/2989 , Y10T428/2993 , Y10T428/2996
摘要： Preparations of particles having a glass surface, wherein more than 75% by weight of these particles have a particle size between 0.5 μm and 15 μm and a glass surface which contains between 2 and 6 mole % zinc oxide, have proven to be particularly advantageous in processes for the purification of nucleic acids. This in particular results in an increased nucleic acid yield.
摘要翻译：具有玻璃表面的颗粒的制备，其中大于75重量％的这些颗粒具有0.5μm和15μm之间的粒度和含有2至6摩尔％氧化锌的玻璃表面，已被证明是特别有利的核酸纯化方法。这特别导致增加的核酸产量。

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