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    • 1. 发明申请
    • SURFACE MODIFIED INORGANIC MATERIAL AND PRODUCING METHOD THEREOF
    • 表面改性无机材料及其制备方法
    • US20130060014A1
    • 2013-03-07
    • US13600976
    • 2012-08-31
    • Chul-Ho JunYe-Lim YeonJi-Sung LeeYoung-Jun Park
    • Chul-Ho JunYe-Lim YeonJi-Sung LeeYoung-Jun Park
    • C07F7/12C07F7/10C07F7/08
    • C03C17/42C03C17/009C08F292/00C08K3/36
    • A surface-modified inorganic material and a preparation method thereof. A surface-modified inorganic material is provided which is obtained by allowing an organosilane compound having allyl or an allyl derivative to react with an inorganic material, particularly solid silica or ITO glass, in the presence of an acid and an organic solvent, to introduce an organic group into the inorganic material even at room temperature, as well as a preparation method thereof. The invention can effectively introduce the organic group into the inorganic material even at room temperature, and thus is very effective in introducing compounds having a thermally sensitive functional group, for example, natural compounds or proteins. It is possible to introduce various organic groups into an inorganic material and to separate and purify organic molecule-bonded organosilane compounds using a silica gel column to effectively bond them to inorganic materials.
    • 表面改性无机材料及其制备方法。 提供了通过使具有烯丙基或烯丙基衍生物的有机硅烷化合物与无机材料,特别是固体二氧化硅或ITO玻璃在酸和有机溶剂的存在下反应而得到的表面改性无机材料, 有机基团也可以在室温下进入无机材料,以及其制备方法。 本发明即使在室温下也可有效地将有机基团引入到无机材料中,因此在引入具有热敏性官能团的化合物,例如天然化合物或蛋白质中非常有效。 可以将各种有机基团引入无机材料中,并使用硅胶柱分离和纯化有机分子键合的有机硅烷化合物以有效地将它们键合到无机材料上。
    • 2. 发明申请
    • Surface Modified Inorganic Material and Producing Method Thereof
    • 表面改性无机材料及其制备方法
    • US20090270590A1
    • 2009-10-29
    • US11989367
    • 2006-05-16
    • Chul-Ho JunYe-Lim YeonJi-Sung LeeYoung-Jun Park
    • Chul-Ho JunYe-Lim YeonJi-Sung LeeYoung-Jun Park
    • C07F7/08C07H15/00C03C17/30C07K2/00C07K1/00
    • C03C17/42C03C17/009C08F292/00C08K3/36
    • A surface-modified inorganic material and a preparation method thereof. A surface-modified inorganic material is provided which is obtained by allowing an organosilane compound having allyl or an allyl derivative to react with an inorganic material, particularly solid silica or ITO glass, in the presence of an acid and an organic solvent, to introduce an organic group into the inorganic material even at room temperature, as well as a preparation method thereof. The invention can effectively introduce the organic group into the inorganic material even at room temperature, and thus is very effective in introducing compounds having a thermally sensitive functional group, for example, natural compounds or proteins. It is possible to introduce various organic groups into an inorganic material and to separate and purify organic molecule-bonded organosilane compounds using a silica gel column to effectively bond them to inorganic materials. Accordingly, the invention is very useful in the chemical industry.
    • 表面改性无机材料及其制备方法。 提供了通过使具有烯丙基或烯丙基衍生物的有机硅烷化合物与无机材料,特别是固体二氧化硅或ITO玻璃在酸和有机溶剂的存在下反应而得到的表面改性无机材料, 有机基团也可以在室温下进入无机材料,以及其制备方法。 本发明即使在室温下也可有效地将有机基团引入到无机材料中,因此在引入具有热敏性官能团的化合物,例如天然化合物或蛋白质中非常有效。 可以将各种有机基团引入无机材料中,并使用硅胶柱分离和纯化有机分子键合的有机硅烷化合物以有效地将它们键合到无机材料上。 因此,本发明在化学工业中非常有用。