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1. 发明授权

US09017444B2 Composite foliage Si fertilizer for lowering contents of heavy metals and nitrate in vegetable, and preparation method thereof 有权
标题翻译：复合叶片用于降低植物中重金属和硝酸盐含量的化肥及其制备方法
公开(公告)号：US09017444B2
公开(公告)日：2015-04-28
申请号：US13500988
申请日：2010-08-03
申请人： Chuanping Liu , Qing Li , Fangbai Li , Tongxu Liu , Xianghua Xu , Huimin Li
发明人： Chuanping Liu , Qing Li , Fangbai Li , Tongxu Liu , Xianghua Xu , Huimin Li
IPC分类号： C05D9/00 , C05D9/02 , C05G3/00
CPC分类号： C05D9/02 , C05D9/00 , C05G3/0064
摘要： The present invention is related to the field of environmental protection, more specifically, to a foliage silicon fertilizer and a method for production of the fertilizer, which is a molybdenum-silica compound sol used for reducing heavy metal and nitrates in vegetables. The fertilizer, which is a molybdenum-silica compound sol, comprises 10-25 wt % silica, 0.05-5.5 wt % molybdenum ions. More preferably, the fertilize, which is a rare earth-molybdenum-silica compound sol, comprises 10-25 wt % silica, 0.05-5.5 wt % molybdenum ions and 0.1-7.5 wt % rare earth ions. By the combination of silica with molybdenum in the present invention, it is effective for preventing the absorption/accumulation of nitrates in vegetables. In addition, by the further combination with rare earth element, the prevention ability of the fertilizer from absorbing heavy metal and nitrates into vegetables is even enhanced. With a preparation method with normal pressure and relatively, low temperature, that is, with mild condition, simple process and high operability, large scale production of the present invention may be readily executed.
摘要翻译：本发明涉及环境保护领域，更具体地说，涉及一种叶片硅肥，以及一种用于减少蔬菜中重金属和硝酸盐的钼 - 二氧化硅复合溶胶的生产方法。作为钼 - 二氧化硅化合物溶胶的肥料包含10-25重量％的二氧化硅，0.05-5.5重量％的钼离子。更优选地，作为稀土 - 钼 - 二氧化硅化合物溶胶的施肥包含10-25重量％的二氧化硅，0.05-5.5重量％的钼离子和0.1-7.5重量％的稀土离子。通过本发明的二氧化硅与钼的组合，可有效地防止蔬菜中硝酸盐的吸收/积聚。此外，通过与稀土元素的进一步组合，将肥料从重金属和硝酸盐吸收到蔬菜中的预防能力得到进一步提高。具有常压，相对低温的制备方法，即温和条件，工艺简单，操作性高，可以容易地进行本发明的大规模生产。

2. 发明申请

US20120198900A1 COMPOSITE FOLIAGE SI FERTILIZER FOR LOWERING CONTENTS OF HEAVY METALS AND NITRATE IN VEGETABLE, AND PREPARATION METHOD THEREOF 有权
标题翻译：复合肥料用于降低蔬菜中重金属和硝酸盐的含量及其制备方法
公开(公告)号：US20120198900A1
公开(公告)日：2012-08-09
申请号：US13500988
申请日：2010-08-03
申请人： Chuanping Liu , Qing Li , Fangbai Li , Tongxu Liu , Xianghua Xu , Huimin Li
发明人： Chuanping Liu , Qing Li , Fangbai Li , Tongxu Liu , Xianghua Xu , Huimin Li
IPC分类号： C05D9/00
CPC分类号： C05D9/02 , C05D9/00 , C05G3/0064
摘要： The present invention is related to the field of environmental protection, more specifically, to a foliage silicon fertilizer and a method for production of the fertilizer, which is a molybdenum-silica compound sol used for reducing heavy metal and nitrates in vegetables. The fertilizer, which is a molybdenum-silica compound sol, comprises 10-25 wt % silica, 0.05-5.5 wt % molybdenum ions. More preferably, the fertilize, which is a rare earth-molybdenum-silica compound sol, comprises 10-25 wt % silica, 0.05-5.5 wt % molybdenum ions and 0.1-7.5 wt % rare earth ions. By the combination of silica with molybdenum in the present invention, it is effective for preventing the absorption/accumulation of nitrates in vegetables. In addition, by the further combination with rare earth element, the prevention ability of the fertilizer from absorbing heavy metal and nitrates into vegetables is even enhanced. With a preparation method with normal pressure and relatively, low temperature, that is, with mild condition, simple process and high operability, large scale production of the present invention may be readily executed.
摘要翻译：本发明涉及环境保护领域，更具体地说，涉及一种叶片硅肥，以及一种用于减少蔬菜中重金属和硝酸盐的钼 - 二氧化硅复合溶胶的生产方法。作为钼 - 二氧化硅化合物溶胶的肥料包含10-25重量％的二氧化硅，0.05-5.5重量％的钼离子。更优选地，作为稀土 - 钼 - 二氧化硅化合物溶胶的施肥包含10-25重量％的二氧化硅，0.05-5.5重量％的钼离子和0.1-7.5重量％的稀土离子。通过本发明的二氧化硅与钼的组合，可有效地防止蔬菜中硝酸盐的吸收/积聚。此外，通过与稀土元素的进一步组合，将肥料从重金属和硝酸盐吸收到蔬菜中的预防能力得到进一步提高。具有常压，相对低温的制备方法，即温和条件，工艺简单，操作性高，可以容易地进行本发明的大规模生产。

3. 发明授权

US07897137B2 Method for producing high-active titanium dioxide hydrosol by using metatitanate as precursor 有权
标题翻译：以偏钛酸盐为前驱体制备高活性二氧化钛水溶胶的方法
公开(公告)号：US07897137B2
公开(公告)日：2011-03-01
申请号：US11372874
申请日：2006-03-10
申请人： Fangbai Li , Tongxu Liu
发明人： Fangbai Li , Tongxu Liu
IPC分类号： C01G23/047 , C01G23/08
CPC分类号： C01G23/053 , B01J21/063 , B01J23/10 , B01J23/50 , B01J23/745 , B01J35/004 , B01J37/033 , B01J37/036 , C01G23/00 , C01G23/0532 , C01P2002/72 , C01P2002/84 , C01P2004/03 , C01P2006/80 , H01L2924/0002 , H01L2924/00
摘要： A method for producing high-active titanium dioxide anatase hydrosol by using metatitanate as precursor, is characterized in comprising the following steps in order: (1) Wash process: adding alkali to wash so as to remove sulfate ion; (2) Dispersion process: adding acid to disperse the filter cake and obtaining a uniform suspension; (3) Peptization process: peptizing the suspension obtained in dispersion process according to the method of (a), (b) or (c). When producing transition metal or rare earth doped anatase hydrosol, transition metal or rare earth salt solution with a predetermined concentration is first prepared, and then added into the metatitanate suspension which has not been washed by alkali. Subsequently, the resulting suspension is filtered and washed until no sulfate ion is present. When producing precious metal deposited anatase hydrosol, precious metal solution is added into prepared pure anatase hydrosol, and then, the resulting solution is irradiated with ultraviolet light for 0.5-10 hours under stirring continuously. The advantages and beneficial effects of the present invention are as follows: (1) the raw material has low price and little pollution as well as abundant source; (2) the hydrosol has excellent degree of dispersibility and higher anatase crystallization; (3) the hydrosol has higher activity under visible light irradiation owing to doping/depositing technique; (4) the properties and activity of the hydrosol can be further enhanced by using post disposal, such as microwave and ultrasonic technique; and (5) the hydrosol is a kind of nano-material with about 10 nm particle size. The anatase hydrosol can be applied for indoor air purification, crop disease control, odor control and so on.
摘要翻译：以钛酸锶为原料制备高活性二氧化钛锐钛矿型水溶胶的方法，其特征在于包括以下步骤：（1）洗涤方法：加碱洗涤以除去硫酸根离子; （2）分散工艺：加入酸分散滤饼并获得均匀的悬浮液; （3）胶溶过程：根据（a），（b）或（c）的方法对分散过程中获得的悬浮液进行胶溶。当制备过渡金属或稀土掺杂的锐钛矿水溶胶时，首先制备预定浓度的过渡金属或稀土盐溶液，然后加入未经碱洗的偏钛酸盐悬浮液中。随后，将所得悬浮液过滤并洗涤直至不存在硫酸根离子。当制备贵金属沉积锐钛矿型水溶胶时，将贵金属溶液加入到制备的纯锐钛矿水溶胶中，然后将所得溶液在持续搅拌下用紫外线照射0.5-10小时。本发明的优点和有益效果如下：（1）原料价格低，污染少，来源丰富; （2）水溶胶具有优异的分散性和较高的锐钛矿结晶度; （3）由于掺杂/沉积技术，水溶胶在可见光照射下具有较高的活性; （4）通过微波和超声波技术等后处理可以进一步提高水溶胶的性能和活性; 和（5）水溶胶是一种具有约10nm粒径的纳米材料。锐钛型水溶胶可用于室内空气净化，作物病害控制，气味控制等。

4. 发明申请

US20070082959A1 Method for producing high-active titanium dioxide hydrosol by using metatitanate as precursor 有权
标题翻译：以偏钛酸盐为前驱体制备高活性二氧化钛水溶胶的方法
公开(公告)号：US20070082959A1
公开(公告)日：2007-04-12
申请号：US11372874
申请日：2006-03-10
申请人： Fangbai Li , Tongxu Liu
发明人： Fangbai Li , Tongxu Liu
IPC分类号： B01F3/12
CPC分类号： C01G23/053 , B01J21/063 , B01J23/10 , B01J23/50 , B01J23/745 , B01J35/004 , B01J37/033 , B01J37/036 , C01G23/00 , C01G23/0532 , C01P2002/72 , C01P2002/84 , C01P2004/03 , C01P2006/80 , H01L2924/0002 , H01L2924/00
摘要： A method for producing high-active titanium dioxide anatase hydrosol by using metatitanate as precursor, is characterized in comprising the following steps in order: (1) Wash process: adding alkali to wash so as to remove sulfate ion; (2) Dispersion process: adding acid to disperse the filter cake and obtaining a uniform suspension; (3) Peptization process: peptizing the suspension obtained in dispersion process according to the method of (a), (b) or (c). When producing transition metal or rare earth doped anatase hydrosol, transition metal or rare earth salt solution with a predetermined concentration is first prepared, and then added into the metatitanate suspension which has not been washed by alkali. Subsequently, the resulting suspension is filtered and washed until no sulfate ion is present. When producing precious metal deposited anatase hydrosol, precious metal solution is added into prepared pure anatase hydrosol, and then, the resulting solution is irradiated with ultraviolet light for 0.5-10 hours under stirring continuously. The advantages and beneficial effects of the present invention are as follows: (1) the raw material has low price and little pollution as well as abundant source; (2) the hydrosol has excellent degree of dispersibility and higher anatase crystallization; (3) the hydrosol has higher activity under visible light irradiation owing to doping/depositing technique; (4) the properties and activity of the hydrosol can be further enhanced by using post disposal, such as microwave and ultrasonic technique; and (5) the hydrosol is a kind of nano-material with about 10 nm particle size. The anatase hydrosol can be applied for indoor air purification, crop disease control, odor control and so on.
摘要翻译：以钛酸锶为原料制备高活性二氧化钛锐钛矿型水溶胶的方法，其特征在于包括以下步骤：（1）洗涤方法：加碱洗涤以除去硫酸根离子; （2）分散工艺：加入酸分散滤饼并获得均匀的悬浮液; （3）胶溶过程：根据（a），（b）或（c）的方法对分散过程中获得的悬浮液进行胶溶。当制备过渡金属或稀土掺杂的锐钛矿水溶胶时，首先制备预定浓度的过渡金属或稀土盐溶液，然后加入未经碱洗的偏钛酸盐悬浮液中。随后，将所得悬浮液过滤并洗涤直至不存在硫酸根离子。当制备贵金属沉积锐钛矿型水溶胶时，将贵金属溶液加入到制备的纯锐钛矿水溶胶中，然后将所得溶液在持续搅拌下用紫外线照射0.5-10小时。本发明的优点和有益效果如下：（1）原料价格低，污染少，来源丰富; （2）水溶胶具有优异的分散性和较高的锐钛矿结晶度; （3）由于掺杂/沉积技术，水溶胶在可见光照射下具有较高的活性; （4）通过微波和超声波技术等后处理可以进一步提高水溶胶的性能和活性; 和（5）水溶胶是一种具有约10nm粒径的纳米材料。锐钛型水溶胶可用于室内空气净化，作物病害控制，气味控制等。

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