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1. 发明授权

US5684182A Sulfonated diphosphines and a process for their preparation 失效
标题翻译：磺化二膦及其制备方法
公开(公告)号：US5684182A
公开(公告)日：1997-11-04
申请号：US604573
申请日：1996-02-21
申请人： Christoph Naumann , Ahmed Tafesh , Dieter Regnat , Hans-Jerg Kleiner
发明人： Christoph Naumann , Ahmed Tafesh , Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07F9/50 , C07C309/35
CPC分类号： C07F9/5027
摘要： The present invention relates to sulfonated diphosphines of the formula (I) ##STR1## where M is hydrogen, ammonium, a monovalent metal or the equivalent of a polyvalent metal, a, b, c and d are each 0 or 1, with the proviso that a+b+c+d is an integer from 1 to 4, Ar is an m-(MSO.sub.3)--C.sub.6 H.sub.4 radical and M is as defined above, n is 0, 1 or 2, Ph is a phenyl radical, R.sup.1 and R.sup.2 are identical or different and are each an alkyl radical having from 1 to 10 carbon atoms or a cycloaliphatic radical having from 5 to 10 carbon atoms in the ring, and a process for their preparation.
摘要翻译：本发明涉及式（I）的磺化二膦：其中M为氢，铵，一价金属或多价金属当量，a，b，c和d各自为0或1，条件是a + b + c + d为1至4的整数，Ar为m-（MSO 3）-C 6 H 4基团，M如上定义，n为0,1或2，Ph为苯基 R 1和R 2相同或不同，并且各自为具有1-10个碳原子的烷基或环中具有5-10个碳原子的脂环族基团及其制备方法。

2. 发明授权

US5750728A Process for the preparation of aromatic bromomethyl compounds 失效
标题翻译：芳香族溴甲基化合物的制备方法
公开(公告)号：US5750728A
公开(公告)日：1998-05-12
申请号：US763877
申请日：1996-12-11
申请人： Adalbert Wagner , Heinz-Werner Kleemann , Dieter Regnat , Hans-Jerg Kleiner
发明人： Adalbert Wagner , Heinz-Werner Kleemann , Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07B39/00 , C07C17/14 , C07C22/04 , C07C67/307 , C07C67/343 , C07C69/65 , C07C69/76 , C07C205/12 , C07C255/50 , C07C257/12 , C07C257/20 , C07C311/05 , C07C311/18 , C07C311/53 , C07D275/04 , C07D275/06 , C07D333/24 , C07D333/60 , C07D333/68 , C07D333/70 , C07D471/04 , C07D487/04 , C07D495/04 , C07D333/56 , C07D333/52
CPC分类号： C07D275/06 , C07B39/00 , C07C17/14 , C07C201/08 , C07C22/04 , C07C255/50 , C07C257/12 , C07C311/18 , C07C311/53 , C07C67/307 , C07D333/24 , C07D333/60 , C07D333/68 , C07D333/70 , C07D471/04 , C07D487/04 , C07D495/04
摘要： Aromatic bromomethyl compounds play a major role in the synthesis of active substances. They can be obtained in particularly pure form by the free-radical bromination of aromatic methyl compounds in the solvent chlorobenzene.
摘要翻译：芳香族溴甲基化合物在活性物质的合成中起主要作用。它们可以通过在溶剂氯苯中芳族甲基化合物的自由基溴化而以特别纯的形式获得。

3. 发明授权

US5739372A Oxaphosphorins and a process for their preparation 失效
标题翻译： Oxaphosphorins及其制备方法
公开(公告)号：US5739372A
公开(公告)日：1998-04-14
申请号：US659897
申请日：1996-06-07
申请人： Dieter Regnat , Hans-Jerg Kleiner
发明人： Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07F9/6571 , C07F9/6574
CPC分类号： C07F9/65719
摘要： The present invention relates to oxaphosphorins of the formula ##STR1## where Ar-Ar is 1-phenylnaphthyl or 1,1'-binaphthyl, R.sup.1 and R.sup.2 are identical or different and are F, Cl, alkyl or alkoxy each having from I to 8 carbon atoms or substituted or unsubstituted aryl, a and b are identical or different and are each an integer from 0 to 4, or Ar-Ar is biphenyl, R.sup.1 and R.sup.2 are identical or different and are substituted or unsubstituted aryl, a and b are as defined above, but a+b.gtoreq.1, X is Cl or Br and the Ar-P and Ar-O bonds are each arranged in the ortho position to the Ar-Ar bond. The invention further relates to a process for preparing these oxaphosphorins.
摘要翻译：本发明涉及式（I）的氧磷杂菁，其中Ar-Ar是1-苯基萘基或1,1'-联萘，R 1和R 2相同或不同，是F，Cl，烷基或烷氧基，各自具有 I至8个碳原子或取代或未取代的芳基，a和b相同或不同，各自为0至4的整数，或Ar-Ar为联苯基，R1和R2相同或不同，为取代或未取代的芳基，和b如上所定义，但a + b> / = 1，X为Cl或Br，并且Ar-P和Ar-O键各自排列在Ar-Ar键的邻位。本发明还涉及一种制备这些氧磷杂菁的方法。

4. 发明授权

US6013706A Process for the preparation of hyrolysis-stable trivalent phosphorus compounds and their use as stabilizers for thermoplastics 失效
标题翻译：制备抗热稳定性三价磷化合物的方法及其作为热塑性塑料稳定剂的用途
公开(公告)号：US6013706A
公开(公告)日：2000-01-11
申请号：US293577
申请日：1994-08-22
申请人： Hans-Jerg Kleiner , Dieter Regnat , Gerhard Pfahler
发明人： Hans-Jerg Kleiner , Dieter Regnat , Gerhard Pfahler
IPC分类号： C08K5/524 , C07F9/02 , C07F9/06 , C08K5/52 , C08K5/527 , C08K5/53 , C08K5/5393 , C08K9/02 , C08K9/08 , C08L101/00 , C08K15/32
CPC分类号： C07F9/025 , C08K9/08
摘要： The hydrolysis stability of trivalent organic phosphorus compounds of the formula I ##STR1## used as stabilizers for thermoplastics is improved if these compounds are treated with 0.01 to 5% by weight of an oxide, a carbonate, a hydroxide, a bicarbonate or a carboxylate of a metal of groups 1a, 2a, 2b and 7b of the periodic table of the elements. The storage stability and the ease of handling are increased and the discoloration of the stabilized polymers is reduced.
摘要翻译：如果这些化合物用0.01至5重量％的氧化物，碳酸盐，氢氧化物，碳酸氢盐或羧酸盐处理，则用作热塑性塑料稳定剂的式I的三价有机磷化合物的水解稳定性得到改善元件周期表的组1a，2a，2b和7b。储存稳定性和易操作性增加，并且稳定的聚合物的变色减少。

5. 发明授权

US5624979A Stabilized phosphorus-modified epoxy resins and their use 失效
标题翻译：稳定磷改性环氧树脂及其用途
公开(公告)号：US5624979A
公开(公告)日：1997-04-29
申请号：US577232
申请日：1995-12-22
申请人： Hans-Jerg Kleiner , Dieter Regnat
发明人： Hans-Jerg Kleiner , Dieter Regnat
IPC分类号： C07F9/655 , C07F9/6574 , C08G59/14 , C08K5/13 , C09D5/25 , C09D163/00 , H05K1/03 , C08L63/00
CPC分类号： C08G59/1488 , C08G59/1422 , C08K5/13 , H05K1/0326 , Y10T428/31511
摘要： The present invention relates to phosphorus-modified epoxy resins having an epoxide value of 0 to about 1 mol/100 g containing structural units which are derived from(A) polyepoxide compounds having at least two epoxide groups per molecule and(B) phosphinic and/or phosphonic acid anhydrides, wherein at least one phenolic antioxidant is admixed to them. The phosphorus-modified epoxy resins stabilized in this way are distinguished by an increased storage stability, in particular at higher temperatures.The invention furthermore relates to the use of these stabilized, phosphorus-modified epoxy resins for the production of shaped articles, coatings or laminates.
摘要翻译：本发明涉及含有结构单元的环氧化物值为0至约1mol / 100g的磷改性环氧树脂，其衍生自（A）每分子具有至少两个环氧基团的聚环氧化物化合物和（B）次膦酸和/ 或膦酸酐，其中至少一种酚类抗氧化剂与它们混合。以这种方式稳定的磷改性环氧树脂的特征在于储存稳定性增加，特别是在较高温度下。本发明还涉及这些稳定化的磷改性环氧树脂用于生产成型制品，涂料或层压材料的用途。

6. 发明授权

US5801291A Process for the preparation of aldehydes by means of a catalyst system comprising rhodium and substituted diphenyldiphospines 失效
标题翻译：通过包含铑和取代的二苯基二磷的催化剂体系制备醛的方法
公开(公告)号：US5801291A
公开(公告)日：1998-09-01
申请号：US813877
申请日：1997-03-07
申请人： Helmut Bahrmann , Hans-Jerg Kleiner , Dieter Regnat
发明人： Helmut Bahrmann , Hans-Jerg Kleiner , Dieter Regnat
IPC分类号： B01J31/24 , B01J31/28 , B01J31/40 , C07B61/00 , C07C45/50 , C07C45/78 , C07C47/02
CPC分类号： B01J31/04 , B01J31/2409 , B01J31/2414 , B01J31/2452 , B01J31/4046 , B01J31/4061 , C07C45/50 , C07C45/786 , B01J2231/321 , B01J2531/822 , B01J2540/40 , B01J2540/42 , Y02P20/584
摘要： The present invention relates to a process for the preparation of aldehydes, which comprises reacting an olefinic compound having 2 to 20 carbon atoms with carbon monoxide and hydrogen, in the presence or absence of a solvent, in the presence of a catalyst comprising rhodium and a compound or a mixture of compounds of the formula (I) ##STR1## in which R.sup.1 is H or an alkyl radical having 1 to 12 carbon atoms, R.sup.2 is a straight-chain alkylene radical having 1 to 8 carbon atoms, an oxygen-containing alkylene radical having 2 to 4 carbon atoms, a radical of the formula (II) or (III) ##STR2## or a cycloalkylene radical having 3 to 10 carbon atoms, R.sup.3 is an alkyl radical having 1 to 25 carbon atoms or an aryl radical having 6 to 10 carbon atoms, A is a radical --COO.sup.- or --SO.sub.3.sup.- and x=0, y=1, m=1 and n=1, or x=0.1, y=1, m=(1 or 2) and n=(1 or 2), or, if R.sup.2 is a radical of the formula (II) or (III), x=1, y=0, m=(0 or 1) and n=(0 or 1), at a temperature from 50.degree. to 190.degree. C. and under a pressure from 0.1 to 45 MPa, and separating the reaction product off from the catalyst.
摘要翻译：本发明涉及醛的制备方法，其包括在存在或不存在溶剂的情况下，使含有2-20个碳原子的烯属化合物与一氧化碳和氢反应，在包含铑和化合物或其中R 1为H或具有1至12个碳原子的烷基的式（I）化合物（I）的化合物，R 2为具有1至8个碳原子的直链亚烷基，具有2至4个碳原子的含氧亚烷基，式（II）或（III）的基团（III）或具有3至10个碳原子的亚环烷基，R 3是具有1至25个碳原子的烷基或具有6至10个碳原子的芳基，A是基团-COO-或-SO 3 - ，x = 0，y = 1，m = 1和n = 1，或x = 0.1，y = 1，m =（1或2）和n =（1或2），或者如果R2是式（II）或（III）的基团，x = 1，y = 0，m = （0或1）和n =（0或1），在50°至190℃的温度下并在0.1至45MPa的压力下，将反应产物与催化剂分离。

7. 发明授权

US5789623A Process for the preparation of hydroxybiarylphosphines and novel compounds of this group of substances 失效
标题翻译：制备羟基联芳基膦的方法和该组物质的新化合物
公开(公告)号：US5789623A
公开(公告)日：1998-08-04
申请号：US661629
申请日：1996-06-11
申请人： Dieter Regnat , Hans-Jerg Kleiner
发明人： Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07C45/50 , C07F9/50 , C07F9/6568 , C07F9/52
CPC分类号： C07F9/65683 , C07C45/505 , C07F9/5022 , C07F9/5068 , C07F9/5081
摘要： The present invention relates to a hydroxybiarylphosphines of the formula ##STR1## in which Ar-Ar is biphenyl, 1-phenyinaphthyl or 1,1'-binaphthyl, R.sup.1 and R.sup.2 are identical or different and are F or alkoxy having in each case 1 to 8 carbon atoms or are substituted or unsubstituted aryl, a and b are identical or different and are an integer from 0 to 4, in which R.sup.3 and R.sup.4 are identical or different and are alkyl having 1 to 8 carbon atoms, cycloalkyl having 4 to 10 carbon atoms, alkaryl having 7 to 9 carbon atoms, Ar.sup.3 --(R.sup.5).sub.n, in which A.sup.3 is an aryl radical having 6 to 10 carbon atoms, R.sup.5 is CF.sub.3, dialkylamino having a total of 2 to 8 carbon atoms or --CH.sub.2 N(alkyl).sub.2 having 1 to 3 carbon atoms per alkyl and n is an integer from 0 to 5, or --R.sup.3 --R.sup.4 -- forms a chain of 3 to 5 members to which one or two aromatic rings or ring systems having 6 to 10 carbon atoms are optionally fused together with the P atom, forms a ring having 4 to 6 members, with the proviso that Ar.sup.3 --(R.sup.5).sub.n is not phenyl or a phenyl substituted by halogen, alkyl or alkoxy each having 1 to 8 carbon atoms, if Ar-Ar is bipohenyl or 1,1'-binaphthyl and a.dbd.b.dbd.0 and R.sup.3 and R.sup.4 are identical in each case.
摘要翻译：本发明涉及下式的羟基联芳基膦：其中Ar-Ar为联苯基，1-苯基萘基或1,1'-联萘，R 1和R 2相同或不同，为各自为F或烷氧基 1至8个碳原子或为取代或未取代的芳基，a和b相同或不同，为0至4的整数，其中R 3和R 4相同或不同，为具有1至8个碳原子的烷基，环烷基具有 4至10个碳原子，具有7至9个碳原子的烷芳基，Ar 3 - （R 5）n，其中A 3是具有6至10个碳原子的芳基，R 5是CF 3，具有2至8个碳原子的二烷基氨基或每个烷基具有1至3个碳原子的-CH 2 N（烷基）2，n是0至5的整数，或-R 3 -R 4形成3至5个成员的链，其中一个或两个芳环或环系具有6个至10个碳原子任选地与P原子稠合在一起形成具有4至6个成员的环，条件是Ar 3 - （R 5）n不是苯基或phe 如果Ar-Ar是二苯基或1,1'-联萘，并且a = b = 0，并且R 3和R 4在每种情况下相同，则被卤素，烷基或烷氧基各自具有1至8个碳原子取代。

8. 发明授权

US5502261A Process for preparing 2,2'-bis(halomethyl)-1,1'-binaphthyl 失效
标题翻译：制备2,2'-双（卤代甲基）-1,1'-联萘的方法
公开(公告)号：US5502261A
公开(公告)日：1996-03-26
申请号：US408057
申请日：1995-03-21
申请人： Hans-Jerg Kleiner , Dieter Regnat , Horst Ro/ schert
发明人： Hans-Jerg Kleiner , Dieter Regnat , Horst Ro/ schert
IPC分类号： C07B61/00 , C07B60/00 , C07C17/14 , C07C25/22 , C07C22/04
CPC分类号： C07C17/14
摘要： The present invention relates to a process for preparing 2,2'-bis(halomethyl)-1,1'-binaphthyl, by reacting 2,2'-dimethyl-1,1'-binaphthyl in the presence of a solvent with a halogenating agent under the action of light having a wavelength of from 10.sup.-5 to 10.sup.-8 m in the presence or absence of a free-radical former at from -10.degree. to 120.degree. C.
摘要翻译：本发明涉及一种制备2,2'-双（卤代甲基）-1,1'-联萘的方法，通过在溶剂存在下使2,2'-二甲基-1,1'-联萘与卤化反应在-10至120℃下，在存在或不存在自由基形成剂的情况下，在波长为10-5至10-8μm的光的作用下，

9. 发明授权

US6114340A Fungicidal compositions 有权
标题翻译：杀真菌剂
公开(公告)号：US6114340A
公开(公告)日：2000-09-05
申请号：US202967
申请日：1999-02-03
申请人： Hans-Jerg Kleiner , Martin Mach , Heinz Hagemeister , Dieter Regnat , Herbert Buschhaus , Hans-Peter Jende , David Stock , Geoffrey Gower Briggs
发明人： Hans-Jerg Kleiner , Martin Mach , Heinz Hagemeister , Dieter Regnat , Herbert Buschhaus , Hans-Peter Jende , David Stock , Geoffrey Gower Briggs
IPC分类号： A01N43/54 , A01N43/653 , A01N57/20 , A01N57/22 , C07F9/32 , C07F9/40 , A01N57/00 , A01N57/18
CPC分类号： C07F9/4028 , A01N43/653 , A01N57/20 , A01N57/22 , C07F9/3229 , C07F9/4006
摘要： An improved fungicidal composition is a mixture of (a) fungicide used to combat phytopathogenic fungi and (b) at least one phosphonate or phosphinate of formula R.sup.1 R.sup.2 P(O)OR.sup.3 where R.sup.1 is C.sub.6-20 alkyl, C.sub.6-20 alkoxy or optionally substituted phenyl, R.sup.2 is benzyl, C.sub.6-20 alkyl optionally interrupted by NH or O, di-C.sub.6-20 alkylamino or the group --CH.sub.2 CH.sub.2 --R.sup.1 P(O)OR.sup.3, and R.sup.3 C.sub.6-20 alkyl. Some of the compounds of formula (I) are novel.
摘要翻译： PCT No.PCT / GB97 / 01738 Sec。一九九九年二月三日 102（e）1999年2月3日PCT 1997年6月26日PCT公布。第WO98 / 00021号公报日期1998年1月8日改良的杀真菌组合物是（a）用于对抗植物病原性真菌的（a）杀真菌剂和（b）至少一种式R1R2P（O）OR3的膦酸酯或次膦酸酯的混合物，其中R1是C6-20烷基，C6-20烷氧基或任选取代的苯基，R 2是苄基，任选地被NH或O，二-C 20-20烷基氨基或基团-CH 2 CH 2 -R 1 P（O）OR 3和R 3 C 6-20烷基间隔的C 6-20烷基。一些式（I）的化合物是新的。

10. 发明授权

US5972825A Substituted diphenyldiphosphines and a process for their preparation 失效
标题翻译：取代的二苯基二膦及其制备方法
公开(公告)号：US5972825A
公开(公告)日：1999-10-26
申请号：US95195
申请日：1998-06-10
申请人： Dieter Regnat , Hans-Jerg Kleiner , Helmut Bahrmann
发明人： Dieter Regnat , Hans-Jerg Kleiner , Helmut Bahrmann
IPC分类号： C07F9/50 , B01J21/18
CPC分类号： C07F9/5027
摘要： The present invention relates to compounds of the formula (I) ##STR1## where R.sup.1 is H or an alkyl radical having from 1 to 12 carbon atoms, R.sup.2 is a straight-chain alkylene radical having from 1 to 8 carbon atoms, an oxygen-containing alkylene radical having from 2 to 4 carbon atoms, a radical of the formula (II) or (III) ##STR2## or a cycloalkylene radical having from 3 to 10 carbon atoms, R.sup.3 is an alkyl radical having from 1 to 25 carbon atoms or an aryl radical having from 6 to 10 carbon atoms, A is a radical --COO.sup.- or --SO.sub.3 .sup.- and x=0, y=1, m=1 and n=1, or x=1, y=1, m=(1 or 2) and n=(1 or 2), or, if R.sup.2 is a radical of the formula (II) or (III), x=1, y=0, m=(0 or 1) and n=(0 or 1), and also a process for their preparation.
摘要翻译：本发明涉及式（I）化合物，其中R 1为H或具有1至12个碳原子的烷基，R 2为具有1至8个碳原子的直链亚烷基，含氧亚烷基具有2至4个碳原子的式（II）或（III）的基团或具有3至10个碳原子的亚环烷基，R 3是具有1至25个碳原子的烷基或具有 6至10个碳原子，A是基团-COO-或-SO 3 - ，x = 0，y = 1，m = 1和n = 1，或x = 1，y = 1，m =（1或2）或n =（1或2），或者如果R2是式（II）或（III）的基团，则x = 1，y = 0，m =（0或1）和n =（0或1），以及它们的制备过程。

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