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1. 发明申请

US20120108816A1 PROCESS FOR PREPARING 1,4-BISHYDROXYETHYLPIPERAZINE 有权
标题翻译：制备1,4-双羟基乙基哌嗪的方法
公开(公告)号：US20120108816A1
公开(公告)日：2012-05-03
申请号：US13284178
申请日：2011-10-28
申请人： Christof Wilhelm Wigbers , Nina Challand , Johann-Peter Melder , Udo Rheude , Roman Dostalek
发明人： Christof Wilhelm Wigbers , Nina Challand , Johann-Peter Melder , Udo Rheude , Roman Dostalek
IPC分类号： C07D295/088
CPC分类号： C07D295/088
摘要： Process for preparing 1,4-bishydroxyethylpiperazine (BHEPIP) of the formula I wherein diethanolamine (DEOA) of the formula II is reacted in the liquid phase in a reactor at a temperature in the range from 130 to 300° C. in the presence of a copper-comprising, chromium-free heterogeneous catalyst.
摘要翻译：制备式I的1,4-二羟乙基哌嗪（BHEPIP）的方法，其中式II的二乙醇胺（DEOA）在液相中在反应器中在130-300℃的温度下在存在下反应一种含铜，不含铬的多相催化剂。

2. 发明授权

US08436169B2 Process for preparing 1,4-bishydroxyethylpiperazine 有权
标题翻译： 1,4-双羟乙基哌嗪的制备方法
公开(公告)号：US08436169B2
公开(公告)日：2013-05-07
申请号：US13284178
申请日：2011-10-28
申请人： Christof Wilhelm Wigbers , Nina Challand , Johann-Peter Melder , Udo Rheude , Roman Dostalek
发明人： Christof Wilhelm Wigbers , Nina Challand , Johann-Peter Melder , Udo Rheude , Roman Dostalek
IPC分类号： C07D241/04
CPC分类号： C07D295/088
摘要： Process for preparing 1,4-bishydroxyethylpiperazine (BHEPIP) of the formula I wherein diethanolamine (DEOA) of the formula II is reacted in the liquid phase in a reactor at a temperature in the range from 130 to 300° C. in the presence of a copper-comprising, chromium-free heterogeneous catalyst.
摘要翻译：制备式I的1,4-二羟乙基哌嗪（BHEPIP）的方法，其中式II的二乙醇胺（DEOA）在液相中在反应器中在130-300℃的温度下在存在下反应一种含铜，不含铬的多相催化剂。

3. 发明授权

US09000218B2 Process for preparing secondary amines in the liquid phase 有权
标题翻译：在液相中制备仲胺的方法
公开(公告)号：US09000218B2
公开(公告)日：2015-04-07
申请号：US13737158
申请日：2013-01-09
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
IPC分类号： C07C209/00 , C07C209/16 , C07C209/86
CPC分类号： C07C209/16 , C07C209/86 , C07C2601/14 , C07C2603/74 , C07C211/35 , C07C211/08
摘要： The present application relates to a process for preparing secondary amines by aminating excess primary or secondary alcohols with primary amines in the liquid phase in the presence of copper-comprising catalysts.
摘要翻译：本申请涉及通过在含铜催化剂存在下在液相中胺化过量的伯胺伯胺或仲醇来制备仲胺的方法。

4. 发明申请

US20120245389A1 PROCESS FOR HYDROGENATING NITRILES 审中-公开
标题翻译：加氢处理方法
公开(公告)号：US20120245389A1
公开(公告)日：2012-09-27
申请号：US13427308
申请日：2012-03-22
申请人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Martin Ernst , Thomas Heidemann , Johann-Peter Melder , Lucia Königsmann , Milind Joshi , Oliver Bey , Bernd Stein
发明人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Martin Ernst , Thomas Heidemann , Johann-Peter Melder , Lucia Königsmann , Milind Joshi , Oliver Bey , Bernd Stein
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C2601/14 , C07C211/36 , C07C211/09
摘要： The present invention relates to a process for hydrogenating organic nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the shaped body catalyst is arranged in a fixed bed, wherein the shaped body in the shape of spheres or rods has in each case a diameter 3 mm or less, in the shape of tablets a height of 4 mm or less, and in the case of all other geometries in each case has an equivalent diameter L=1/a′ of 0.70 mm or less, where a′ is the external surface area per unit volume (mms2/mmp3), where: a ′ = A p V p , where Ap is the external surface area of the catalyst particle (mms2) and Vp is the volume of the catalyst particle (mmp3). The present invention further relates to a process for preparing downstream products of isophoronediamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines prepared according to the invention.
摘要翻译：本发明涉及一种在反应器中催化剂存在下通过氢气氢化有机腈的方法，其中成形体催化剂布置在固定床中，其中球体或棒状的成形体具有每个壳体的直径为3mm以下，片状形状为4mm以下，在各种情况下，所有其他几何形状的等效直径L = 1 / a'为0.70mm以下，其中 a'是每单位体积的外表面积（mms2 / mmp3），其中：a'= A p V p，其中Ap是催化剂颗粒的外表面积（mms2），Vp是催化剂颗粒的体积 mmp3）。本发明还涉及由根据本发明制备的胺制备异佛尔酮二胺（IPDA）或N，N-二甲基氨基丙胺（DMAPA）的下游产物的方法。

5. 发明申请

US20130178656A1 PROCESS FOR PREPARING SECONDARY AMINES IN THE LIQUID PHASE 有权
标题翻译：在液相中制备二级胺的方法
公开(公告)号：US20130178656A1
公开(公告)日：2013-07-11
申请号：US13737158
申请日：2013-01-09
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C209/86 , C07C2601/14 , C07C2603/74 , C07C211/35 , C07C211/08
摘要： The present application relates to a process for preparing secondary amines by aminating excess primary or secondary alcohols with primary amines in the liquid phase in the presence of copper-comprising catalysts.
摘要翻译：本申请涉及通过在含铜催化剂存在下在液相中胺化过量的伯胺伯胺或仲醇来制备仲胺的方法。

6. 发明授权

US08450530B2 Process for preparing unsymmetric secondary tert-butylamines in the gas phase 失效
标题翻译：在气相中制备不对称二级叔丁胺的方法
公开(公告)号：US08450530B2
公开(公告)日：2013-05-28
申请号：US13080885
申请日：2011-04-06
申请人： Christoph Mueller , Christof Wilhelm Wigbers , Johann-Peter Melder , Gerd Haderlein , Norbert Gutfrucht
发明人： Christoph Mueller , Christof Wilhelm Wigbers , Johann-Peter Melder , Gerd Haderlein , Norbert Gutfrucht
IPC分类号： C07C209/16 , C07C209/26
CPC分类号： C07C209/26 , C07C211/08
摘要： The present invention relates to a process for preparing unsymmetric secondary tert-butylamines by continuous amination in the gas phase, wherein tert-butylamine is converted over hydrogenation catalysts in the presence of an alcohol or aldehyde and hydrogen.
摘要翻译：本发明涉及通过在气相中连续胺化来制备不对称仲叔丁胺的方法，其中叔丁胺在醇或醛和氢的存在下转化为氢化催化剂。

7. 发明申请

US20110313188A1 METHOD FOR IMPROVING THE CATALYTIC ACTIVITY OF MONOLITHIC CATALYSTS 审中-公开
标题翻译：改进单体催化剂催化活性的方法
公开(公告)号：US20110313188A1
公开(公告)日：2011-12-22
申请号：US13148595
申请日：2010-02-04
申请人： Christof Wilhelm Wigbers , Jochen Steiner , Martin Ernst , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder
发明人： Christof Wilhelm Wigbers , Jochen Steiner , Martin Ernst , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder
IPC分类号： C07C209/48 , B01J21/02 , B01J21/10 , B01J21/16 , B01J21/06 , B01J23/83 , C07C253/30 , B01J21/08
CPC分类号： B01J23/78 , B01J23/83 , B01J27/1817 , B01J27/1853 , B01J35/04 , B01J37/0201 , B01J37/0205 , B01J37/0215 , B01J37/0234 , B01J2523/00 , C07C209/48 , C07C253/30 , C07C2601/14 , C07C211/09 , C07C211/11 , C07C211/12 , C07C211/36 , C07C255/24 , B01J2523/12 , B01J2523/31 , B01J2523/51 , B01J2523/72 , B01J2523/845 , B01J2523/11 , B01J2523/48 , B01J2523/847
摘要： The present invention relates to a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, wherein said catalyst comprises one or more elements selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to processes for preparing the inventive catalyst and to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles.
摘要翻译：本发明涉及包含一种或多种选自钴，镍和铜的元素的催化剂，所述催化剂以结构化整料的形式存在，其中所述催化剂包括一种或多种选自以下的元素：碱金属，碱土金属和稀土金属。本发明还涉及用于制备本发明催化剂的方法和本发明催化剂在用于氢化有机物质，特别是用于氢化腈的方法中的用途。

8. 发明授权

US09139511B2 Process for hydrogenating nitriles 有权
标题翻译：腈水解工艺
公开(公告)号：US09139511B2
公开(公告)日：2015-09-22
申请号：US13427388
申请日：2012-03-22
申请人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Petr Kubanek , Thomas Heidemann , Johann-Peter Melder , Thomas Krug , Oliver Bey
发明人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Petr Kubanek , Thomas Heidemann , Johann-Peter Melder , Thomas Krug , Oliver Bey
IPC分类号： C07C209/00 , C07C209/48
CPC分类号： C07C209/48
摘要： The present invention relates to a process for hydrogenating nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the catalyst is arranged in a fixed bed, wherein the cross-sectional loading in the reactor is in the range from 5 kg/(m2 s) to 50 kg/(m2 s). The present invention further relates to a process for preparing downstream products of isophoronediamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines prepared according to the invention.
摘要翻译：本发明涉及在反应器中催化剂存在下通过氢气氢化腈的方法，其中催化剂布置在固定床中，其中反应器中的横截面负载在5kg /（m2·s）至50 kg /（m2·s）。本发明还涉及由根据本发明制备的胺制备异佛尔酮二胺（IPDA）或N，N-二甲基氨基丙胺（DMAPA）的下游产物的方法。

9. 发明授权

US08637668B2 Process for preparing a cyclic tertiary methylamine 有权
标题翻译：制备环状叔甲胺的方法
公开(公告)号：US08637668B2
公开(公告)日：2014-01-28
申请号：US13158667
申请日：2011-06-13
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
IPC分类号： C07D295/03
CPC分类号： C07D295/03
摘要： Process for preparing a cyclic tertiary methylamine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, wherein an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) or aminoethylethanolamine of the formula IIa where R1 is as defined above or is hydrogen (H), in which case R1═CH3 in the amine I, is reacted with methanol in a reactor at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst.
摘要翻译：制备式I的环状叔甲胺的方法，其中A是C 4 - 亚烷基，C 5-亚烷基或 - （CH 2）2 -B-（CH 2）2 - 基，其中B是氧（O）或 R 1是C 1 -C 5 - 烷基，芳基或C 5 -C 7 - 环烷基，其中由1,4-氨基丁醇，1,5-氨基戊醇，氨基二甘醇（ADG）或氨基乙基乙醇胺组成的组中的氨基醇II 其中R 1如上定义或是氢（H），在这种情况下，胺I中的R 1 = CH 3在反应器中在150-270℃的温度下与甲醇反应，在在含铜的非均相催化剂存在下的液相。

10. 发明授权

US08536377B2 Method for producing N,N-substituted-3-aminopropan-1-ols 有权
标题翻译：制备N，N-取代-3-氨基丙-1-醇的方法
公开(公告)号：US08536377B2
公开(公告)日：2013-09-17
申请号：US13127828
申请日：2009-11-02
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Martin Ernst
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Martin Ernst
IPC分类号： C07C213/00
CPC分类号： C07C213/02 , C07C227/08 , Y02P20/582 , C07C215/08 , C07C229/12
摘要： The present invention relates to a process for preparing N,N-substituted 3-aminopropan-1-ols by a) reacting secondary amine with acrolein at a temperature of (−50) to 100° C. and a pressure of 0.01 to 300 bar, and b) reacting the reaction mixture obtained in stage a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a pressure of 1 to 400 bar, wherein the molar ratio of secondary amine to acrolein in stage a) is 1:1 or more and the temperature in stage b) is in the range from (−50) to 70° C. In a preferred embodiment, acrolein which has been obtained from glycerol based on renewable raw materials is used. The invention further relates to the use of an N,N-dimethyl-3-aminopropan-1-ol (DMAPOL) based on renewable raw materials as a catalyst for polyurethane preparation, as a scrubbing fluid in gas scrubbing, in the electronics chemicals and electroplating sectors, as a feedstock in organic synthesis, and as an intermediate in the production of pharmaceuticals and crop protection compositions.
摘要翻译：本发明涉及一种通过以下步骤制备N，N-取代的3-氨基丙-1-醇的方法：a）在（-50）至100℃的温度和0.01至300巴的压力下使仲胺与丙烯醛反应，和b）在加氢催化剂存在下，在1至400巴的压力下，将a）中获得的反应混合物与氢气和氨反应，其中a）步中仲胺与丙烯醛的摩尔比为1:1 或更高，步骤b）中的温度在（-50）至70℃的范围内。在优选的实施方案中，使用了基于可再生原料从甘油获得的丙烯醛。本发明还涉及使用基于可再生原料的N，N-二甲基-3-氨基丙-1-醇（DMAPOL）作为聚氨酯制备的催化剂，在电气化学品中用作气体洗涤中的洗涤液，电镀部门，作为有机合成中的原料，以及作为药物和作物保护组合物生产中的中间体。

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