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1. 发明申请

US20100036184A1 Catalyst Composition and Its Use Thereof in Aromatics Alkylation 有权
标题翻译：催化剂组合物及其在芳烃烷基化中的应用
公开(公告)号：US20100036184A1
公开(公告)日：2010-02-11
申请号：US12520608
申请日：2007-12-20
申请人： Christine N. Elia , Frederick Y. Lo , Jeffrey T. Elks , Darryl D. Lacy , Mohan Kalyanaraman
发明人： Christine N. Elia , Frederick Y. Lo , Jeffrey T. Elks , Darryl D. Lacy , Mohan Kalyanaraman
IPC分类号： C07C2/66 , B01J29/06
CPC分类号： B01J29/7088 , B01J21/063 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/7038 , B01J29/7057 , B01J29/80 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2529/70
摘要： This disclosure relates to a catalyst composition comprising (a) a crystalline MCM-49 molecular sieve; and (b) a binder comprising at least 1 wt. % of a titanium compound. In one aspect of this disclosure, the titanium compound comprises at least one of titanium oxide, titanium hydroxide, titanium sulfate, titanium phosphate, or any combination thereof. In another aspect of this disclosure, the catalyst composition further comprises a crystalline MCM-22 family molecular sieve comprising at least one of MCM-22, MCM-36, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-30, PSH-3, ERB-1, SSZ-25, or any combination thereof. In other embodiments, this disclosure relates to a process for preparing the catalyst composition of this disclosure, the process comprises (a) providing the crystalline MCM-49 molecular sieve and the binder comprising at least 1 wt. % of a titanium compound to form a mixture; and (b) forming the mixture into the catalyst composition. In a preferred embodiment, the forming step comprises extruding. In yet other embodiments, this disclosure discloses a process for alkylating an aromatic hydrocarbon with an alkylating agent to produce an alkylated aromatic product by contacting the aromatic hydrocarbon and the alkylating agent with the catalyst composition.
摘要翻译：本公开涉及一种催化剂组合物，其包含（a）结晶MCM-49分子筛; 和（b）包含至少1重量％％的钛化合物。在本公开的一个方面，钛化合物包括氧化钛，氢氧化钛，硫酸钛，磷酸钛或其任何组合中的至少一种。在本公开的另一方面，催化剂组合物还包含结晶MCM-22族分子筛，其包含MCM-22，MCM-36，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ -30，PSH-3，ERB-1，SSZ-25或其任何组合。在其它实施方案中，本公开涉及制备本发明的催化剂组合物的方法，该方法包括（a）提供结晶MCM-49分子筛和包含至少1wt。％的钛化合物以形成混合物; 和（b）将该混合物形成到催化剂组合物中。在优选实施例中，成形步骤包括挤出。在其它实施方案中，本公开公开了一种使用烷基化剂烷基化芳族烃以通过使芳族烃和烷基化剂与催化剂组合物接触而产生烷基化芳族化合物的方法。

2. 发明授权

US08492602B2 Catalyst composition and its use thereof in aromatics alkylation 有权
标题翻译：催化剂组合物及其在芳烃烷基化中的应用
公开(公告)号：US08492602B2
公开(公告)日：2013-07-23
申请号：US12520608
申请日：2007-12-20
申请人： Christine N. Elia , Frederick Y. Lo , Jeffrey T. Elks , Darryl D. Lacy , Mohan Kalyanaraman
发明人： Christine N. Elia , Frederick Y. Lo , Jeffrey T. Elks , Darryl D. Lacy , Mohan Kalyanaraman
IPC分类号： C07C2/66
CPC分类号： B01J29/7088 , B01J21/063 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/7038 , B01J29/7057 , B01J29/80 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2529/70
摘要： This disclosure relates to a process for alkylating an aromatic hydrocarbon with an alkylating agent to produce an alkylated aromatic product, said process comprising contacting said aromatic hydrocarbon and said alkylating agent with a catalyst composition under alkylation conditions effective to alkylate said aromatic hydrocarbon with said alkylating agent to form an effluent comprising said alkylated aromatic product, wherein said catalyst composition comprising (a) MCM-22 family material; and (b) a binder comprising at least 1 wt. % of a titanium compound based on the weight of said catalyst composition, wherein said titanium compound was anatase and rutile phases.
摘要翻译：本公开涉及一种用烷基化剂烷基化烷基化产生烷基化芳族产物的方法，所述方法包括使烷基化剂与催化剂组合物在烷基化条件下接触，所述烷基化条件有效地使所述芳族烃与所述烷基化剂烷基化以形成包含所述烷基化芳族产物的流出物，其中所述催化剂组合物包含（a）MCM-22族材料; 和（b）包含至少1重量％％的钛化合物，基于所述催化剂组合物的重量，其中所述钛化合物是锐钛型和金红石相。

3. 发明授权

US07381676B1 Catalyst composition and its use thereof in aromatics alkylation 有权
标题翻译：催化剂组合物及其在芳烃烷基化中的应用
公开(公告)号：US07381676B1
公开(公告)日：2008-06-03
申请号：US11654061
申请日：2007-01-16
申请人： Christine N. Elia , Frederick Y. Lo , Jeffrey T. Elks , Darryl D. Lacy , Mohan Kalyanaraman
发明人： Christine N. Elia , Frederick Y. Lo , Jeffrey T. Elks , Darryl D. Lacy , Mohan Kalyanaraman
IPC分类号： B01J29/04 , B01J29/06 , B01J21/00
CPC分类号： B01J29/7088 , B01J21/063 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/7038 , B01J29/7057 , B01J29/80 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2529/70
摘要： This disclosure relates to a catalyst composition comprising (a) a crystalline MCM-49 molecular sieve; and (b) a binder comprising at least 1 wt. % of a titanium compound. In one aspect of this disclosure, the titanium compound comprises at least one of titanium oxide, titanium hydroxide, titanium sulfate, titanium phosphate, or any combination thereof. In another aspect of this disclosure, the catalyst composition further comprises a crystalline MCM-22 family molecular sieve comprising at least one of MCM-22, MCM-36, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-30, PSH-3, ERB-1, SSZ-25, or any combination thereof. In other embodiments, this disclosure relates to a process for preparing the catalyst composition of this disclosure, the process comprises (a) providing the crystalline MCM-49 molecular sieve and the binder comprising at least 1 wt. % of a titanium compound to form a mixture; and (b) forming the mixture into the catalyst composition. In a preferred embodiment, the forming step comprises extruding. In yet other embodiments, this disclosure discloses a process for alkylating an aromatic hydrocarbon with an alkylating agent to produce an alkylated aromatic product by contacting the aromatic hydrocarbon and the alkylating agent with the catalyst composition.
摘要翻译：本公开涉及一种催化剂组合物，其包含（a）结晶MCM-49分子筛; 和（b）包含至少1重量％％的钛化合物。在本公开的一个方面，钛化合物包括氧化钛，氢氧化钛，硫酸钛，磷酸钛或其任意组合中的至少一种。在本公开的另一方面，催化剂组合物还包含结晶MCM-22族分子筛，其包含MCM-22，MCM-36，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ -30，PSH-3，ERB-1，SSZ-25或其任何组合。在其它实施方案中，本公开涉及制备本发明的催化剂组合物的方法，该方法包括（a）提供结晶MCM-49分子筛和包含至少1wt。％的钛化合物以形成混合物; 和（b）将该混合物形成到催化剂组合物中。在优选实施例中，成形步骤包括挤出。在其它实施方案中，本公开公开了一种使用烷基化剂烷基化芳族烃以通过使芳族烃和烷基化剂与催化剂组合物接触而产生烷基化芳族化合物的方法。

4. 发明授权

US08022261B2 Catalyst composition, the method of manufacturing, and the process of use thereof in aromatics alkylation 有权
标题翻译：催化剂组合物，制备方法及其在芳烃烷基化中的应用方法
公开(公告)号：US08022261B2
公开(公告)日：2011-09-20
申请号：US12906393
申请日：2010-10-18
申请人： Mohan Kalyanaraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
发明人： Mohan Kalyanaraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
IPC分类号： C07C2/66
CPC分类号： B01J29/7038 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/10 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/085
摘要： A catalyst composition comprises a crystalline MCM-22 family molecular sieve and a binder, wherein the catalyst composition is characterized by an extra-molecular sieve porosity greater than or equal to 0.122 ml/g for pores having a pore diameter ranging from about 2 nm to about 8 nm, wherein the porosity is measured by N2 porosimetry. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent. The molecular sieve may have a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta.
摘要翻译：一种催化剂组合物包括结晶MCM-22族分子筛和粘合剂，其中该催化剂组合物的特征在于具有大于或等于0.122ml / g的分子量以上孔隙，孔隙范围为约2nm至约8nm，其中通过N 2孔隙率法测量孔隙度。催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。分子筛可以具有小于12，例如小于2的约束指数。可用于本公开的分子筛的实例是MCM-22族分子筛，沸石Y和沸石β。

5. 发明授权

US07919421B2 Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation 有权
标题翻译：催化剂组合物，其制备方法及其在芳烃烷基化中的应用方法
公开(公告)号：US07919421B2
公开(公告)日：2011-04-05
申请号：US11643530
申请日：2006-12-21
申请人： Mohan Kalyanaraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
发明人： Mohan Kalyanaraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
IPC分类号： B01J29/06
CPC分类号： B01J29/7038 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/10 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/085
摘要： A catalyst composition comprises a crystalline MCM-22 family molecular sieve and a binder, wherein the catalyst composition is characterized by an extra-molecular sieve porosity greater than or equal to 0.122 ml/g for pores having a pore diameter ranging from about 2 nm to about 8 nm, wherein the porosity is measured by N2 porosimetry. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent. The molecular sieve may have a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta.
摘要翻译：一种催化剂组合物包括结晶MCM-22族分子筛和粘合剂，其中该催化剂组合物的特征在于具有大于或等于0.122ml / g的分子量以上孔隙，孔隙范围为约2nm至约8nm，其中通过N 2孔隙率法测量孔隙度。催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。分子筛可以具有小于12，例如小于2的约束指数。可用于本公开的分子筛的实例是MCM-22族分子筛，沸石Y和沸石β。

6. 发明申请

US20110028772A1 Catalyst Composition, The Method of Manufacturing, and the Process of Use Thereof in Aromatics Alkylation 有权
标题翻译：催化剂组合物，制备方法及其在芳烃烷基化中的应用过程
公开(公告)号：US20110028772A1
公开(公告)日：2011-02-03
申请号：US12906393
申请日：2010-10-18
申请人： Mohan Kalyanaraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
发明人： Mohan Kalyanaraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
IPC分类号： C07C2/66
CPC分类号： B01J29/7038 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/10 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/085
摘要： A catalyst composition comprises a crystalline MCM-22 family molecular sieve and a binder, wherein the catalyst composition is characterized by an extra-molecular sieve porosity greater than or equal to 0.122 ml/g for pores having a pore diameter ranging from about 2 nm to about 8 nm, wherein the porosity is measured by N2 porosimetry. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent. The molecular sieve may have a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta
摘要翻译：一种催化剂组合物包括结晶MCM-22族分子筛和粘合剂，其中该催化剂组合物的特征在于具有大于或等于0.122ml / g的分子量以上孔隙，孔隙范围为约2nm至约8nm，其中通过N 2孔隙率法测量孔隙度。催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。分子筛可以具有小于12，例如小于2的约束指数。可用于本公开的分子筛的实例是MCM-22族分子筛，沸石Y和沸石β

7. 发明申请

US20080154080A1 Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation 有权
标题翻译：催化剂组合物，其制备方法及其在芳烃烷基化中的应用方法
公开(公告)号：US20080154080A1
公开(公告)日：2008-06-26
申请号：US11643530
申请日：2006-12-21
申请人： Mohan Kalyanoraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
发明人： Mohan Kalyanoraman , Christine N. Elia , Darryl D. Lacy , Jean W. Beeckman , Michael C. Clark
IPC分类号： C07C6/12
CPC分类号： B01J29/7038 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/10 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/085
摘要： A catalyst composition comprises a crystalline MCM-22 family molecular sieve and a binder, wherein the catalyst composition is characterized by an extra-molecular sieve porosity greater than or equal to 0.122 ml/g for pores having a pore diameter ranging from about 2 nm to about 8 nm, wherein the porosity is measured by N2 porosimetry. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent. The molecular sieve may have a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta
摘要翻译：一种催化剂组合物包括结晶MCM-22族分子筛和粘合剂，其中该催化剂组合物的特征在于具有大于或等于0.122ml / g的分子量以上孔隙，孔隙范围为约2nm至约8nm，其中通过N 2孔隙率法测量孔隙度。催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。分子筛可以具有小于12，例如小于2的约束指数。可用于本公开的分子筛的实例是MCM-22族分子筛，沸石Y和沸石β

8. 发明授权

US08445398B2 Ion exchange process for making molecular sieve composition 失效
标题翻译：用于制备分子筛组成的离子交换方法
公开(公告)号：US08445398B2
公开(公告)日：2013-05-21
申请号：US12166090
申请日：2008-07-01
申请人： Mohan Kalyanaraman , Darryl D. Lacy
发明人： Mohan Kalyanaraman , Darryl D. Lacy
IPC分类号： B01J21/00 , B01J29/00 , B01J29/04 , C10G11/02 , C10G11/04
CPC分类号： B01J37/0009 , B01J29/06 , B01J37/30 , B01J2229/20 , B01J2229/40 , B01J2229/42
摘要： This disclosure relates to a process for preparing a catalyst composition comprising (a) contacting a molecular sieve composition with a solution of a solvent and a solute under ion-exchange conditions to form an exchanged molecular sieve composition, wherein the solute comprises at least one of an amide compound, an imide compound, a strong proton donor, or any combination thereof, the solute has a solubility in the solvent of at least 0.05 g per 100 grams of the solvent, preferably at least 1 gram per 100 grams of the solvent; and (b) separating the exchanged molecular sieve from the mixture of the step (a).
摘要翻译：本公开涉及一种制备催化剂组合物的方法，其包括（a）在离子交换条件下使分子筛组合物与溶剂和溶质的溶液接触以形成交换分子筛组合物，其中所述溶质包含以下各项中的至少一种：酰胺化合物，酰亚胺化合物，强质子给体或其任何组合，溶质在溶剂中的溶解度至少为0.05g / 100克溶剂，优选至少1克/ 100克溶剂; 和（b）从步骤（a）的混合物中分离交换的分子筛。

9. 发明申请

US20090036295A1 Novel Ion Exchange Process for Making Molecular Sieve Composition 失效
标题翻译：用于制备分子筛组成的新型离子交换方法
公开(公告)号：US20090036295A1
公开(公告)日：2009-02-05
申请号：US12166090
申请日：2008-07-01
申请人： Mohan Kalyanaraman , Darryl D. Lacy
发明人： Mohan Kalyanaraman , Darryl D. Lacy
IPC分类号： B01J29/40 , B01J29/08 , B01J29/18 , B01J29/072
CPC分类号： B01J37/0009 , B01J29/06 , B01J37/30 , B01J2229/20 , B01J2229/40 , B01J2229/42
摘要： This disclosure relates to a process for preparing a catalyst composition comprising (a) contacting a molecular sieve composition with a solution of a solvent and a solute under ion-exchange conditions to form an exchanged molecular sieve composition, wherein the solute comprises at least one of an amide compound, an imide compound, a strong proton donor, or any combination thereof, the solute has a solubility in the solvent of at least 0.05 g per 100 grams of the solvent, preferably at least 1 gram per 100 grams of the solvent; and (b) separating the exchanged molecular sieve from the mixture of the step (a).
摘要翻译：本公开涉及一种制备催化剂组合物的方法，其包括（a）在离子交换条件下使分子筛组合物与溶剂和溶质的溶液接触以形成交换分子筛组合物，其中所述溶质包含以下各项中的至少一种：酰胺化合物，酰亚胺化合物，强质子给体或其任何组合，溶质在溶剂中的溶解度至少为0.05g / 100克溶剂，优选至少1克/ 100克溶剂; 和（b）从步骤（a）的混合物中分离交换的分子筛。

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