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    • 1. 发明申请
    • Method for the production of chlorine
    • 生产氯的方法
    • US20060263290A1
    • 2006-11-23
    • US10567579
    • 2004-08-06
    • Christian WalsdorffMartin FieneMartin SesingOlga MetelkinaLothar SeidemannEckhard StroeferKlaus Harth
    • Christian WalsdorffMartin FieneMartin SesingOlga MetelkinaLothar SeidemannEckhard StroeferKlaus Harth
    • C01B7/00
    • C01B7/04Y02P20/228
    • The invention relates to a process for preparing chlorine by catalytic gas-phase oxidation of hydrogen chloride, which comprises the steps: a) providing a feed gas stream I comprising hydrogen chloride and a feed gas stream II comprising oxygen; b) in a first oxidation stage, feeding the feed gas stream I, the feed gas stream II, if desired a recycle stream la comprising hydrogen chloride and if desired an oxygen-containing recycle stream IIa into a first oxidation zone and bringing them into contact with a first oxidation catalyst so that a first partial amount of the hydrogen chloride is oxidized to chlorine and a gas stream III comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; c) in a second oxidation stage, feeding the gas stream III into a second oxidation zone and bringing it into contact with at least one further oxidation catalyst so that a second partial amount of the hydrogen chloride is oxidized to chlorine and a product gas stream IV comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; d) isolating chloride, if desired the recycle stream Ia and if desired the recycle stream IIa from the product gas stream IV, wherein the first oxidization catalyst in the first oxidation zone is present in a fluidized bed and the further oxidation catalyst or catalysts in the second oxidation zone is/are present in a fixed bed.
    • 本发明涉及通过氯化氢的催化气相氧化制备氯的方法,其包括以下步骤:a)提供包含氯化氢的进料气流I和包含氧的进料气流II; b)在第一氧化阶段,如果需要,将进料气流I,进料气流II进料到包含氯化氢的再循环流1a,并且如果需要,将含氧循环流IIa进入第一氧化区并使其接触 用第一氧化催化剂使得第一部分氯化氢被氧化成氯,得到包含氯,未反应的氧,未反应的氯化氢和水蒸气的气流III; c)在第二氧化阶段,将气流III进料到第二氧化区并使其与至少一种其它氧化催化剂接触,使得第二部分量的氯化氢被氧化成氯,产物气流IV 包括氯,未反应的氧,未反应的氯化氢和水蒸气; d)如果需要,根据需要从产物气流IV中分离氯化物,如果需要,再循环流Ia,如果需要,再循环流IIa,其中第一氧化区中的第一氧化催化剂存在于流化床中, 第二氧化区存在于固定床中。
    • 5. 发明申请
    • Method for producing chlorine from hydrochloric from hydrochloric aid
    • 从盐酸辅助的盐酸生产氯的方法
    • US20060099138A1
    • 2006-05-11
    • US10532725
    • 2003-10-27
    • Christian WalsdorffMartin FieneChristian KuhrsEckhard StroeferKlaus Harth
    • Christian WalsdorffMartin FieneChristian KuhrsEckhard StroeferKlaus Harth
    • C01B7/00
    • C01B7/0718C01B7/04C01B7/0743C07C263/10C07C265/14C07C265/06
    • Process for preparing chlorine from hydrochloric acid, which comprises the steps: a) providing a hydrochloric acid feed stream I; b) providing a hydrochloric acid recycle stream II; c) separating off a hydrogen chloride stream IV from the hydrochloric acid feed stream I and the hydrochloric acid recycle stream II in a distillation step; d) feeding the hydrogen chloride stream IV, an oxygen-containing steam V and, if desired, an oxygen-containing recycle stream Va into an oxidation zone and oxidizing hydrogen chloride to chlorine in the presence of a catalyst to give a product gas stream VI comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor; e) separating off hydrogen chloride and water from the product gas stream VI in an absorption step to give a gas stream VII and the hydrochloric acid recycle stream II; f) if desired, drying the gas stream VII; g) separating off an oxygen-containing stream from the gas stream VII and, if desired, recirculating at least part of this as oxygen-containing recycle stream Va to the oxidation zone, leaving a chlorine-containing product stream VIII; h) if desired, further purifying the chlorine-containing product stream VIII.
    • 从盐酸制备氯的方法,其包括以下步骤:a)提供盐酸进料流I; b)提供盐酸循环流II; c)在蒸馏步骤中,从盐酸进料流I和盐酸循环流II中分离出氯化氢料流IV; d)将氯化氢流IV,含氧蒸汽V以及如果需要的话将含氧再循环流Va加入氧化区,并在催化剂存在下将氯化氢氧化成氯,得到产物气流VI 包括氯,未反应的氧,未反应的氯化氢和水蒸气; e)在吸收步骤中从产物气流VI中分离氯化氢和水,得到气流VII和盐酸再循环流II; f)如果需要,干燥气流VII; g)从气流VII中分离含氧物流,如果需要,将其至少部分再循环为含氧再循环流Va至氧化区,留下含氯产物流VIII; h)如果需要,进一步纯化含氯产物流VIII。
    • 8. 发明申请
    • Method For Producing Chlorine
    • 氯生产方法
    • US20080159948A1
    • 2008-07-03
    • US11816045
    • 2006-02-20
    • Martin SesingArmin DiefenbacherHartwig VossOlga SchubertLothar SeidemannMartin KarchesThomas GrasslerEckhard Stroefer
    • Martin SesingArmin DiefenbacherHartwig VossOlga SchubertLothar SeidemannMartin KarchesThomas GrasslerEckhard Stroefer
    • C01B7/04
    • C01B7/075C01B7/04C01B7/0743
    • Process for preparing chlorine from hydrogen chloride, which comprises the steps: a) feeding of a stream a1 comprising hydrogen chloride and of a stream a2 comprising oxygen into an oxidation zone and catalytic oxidation of hydrogen chloride to chlorine, giving a product gas stream a3 comprising chlorine, water, oxygen, carbon dioxide and inert gases; b) cooling of the product gas stream a3 and removal of water and hydrogen chloride as aqueous hydrochloric acid, leaving a gas stream b comprising chlorine, water, oxygen, carbon dioxide and inert gases; c) optional drying of the gas stream b) to leave a gas stream c which is substantially free of water and comprises chlorine, oxygen, carbon dioxide and inert gases; d) at least partial liquefaction of the gas stream c and of a chlorine-rich recycle stream f1 comprising chlorine, oxygen and carbon dioxide by compression and cooling, giving an at least partially liquefied stream d; e) gas/liquid separation of the stream d into a gas stream e1 comprising chlorine, oxygen, carbon dioxide and inert gases and into a liquid stream e2 comprising chlorine, oxygen and carbon dioxide; f) feeding of at least part of the gas stream e1 into a membrane separation unit and fractionation by membrane separation to give the chlorine-rich recycle stream f1 and a gas stream f2 which is low in chlorine and comprises chlorine, oxygen and carbon dioxide and recirculation of the chlorine-rich recycle stream f1 to step d); g) separation of the liquid stream e2 by distillation into a chlorine stream g1 and a stream g2 comprising essentially oxygen and carbon dioxide.
    • 从氯化氢制备氯的方法,其包括以下步骤:a)将包含氯化氢的物流1和包含氧的物流2加入氧化区并将氯化氢催化氧化成氯,得到产物气流 a 3,包括氯,水,氧,二氧化碳和惰性气体; b)冷却产物气流a 3,除去水和氯化氢作为盐酸水溶液,留下包含氯,水,氧气,二氧化碳和惰性气体的气流b; c)气流的任选干燥b)留下基本上不含水的气流c,包括氯,氧,二氧化碳和惰性气体; d)通过压缩和冷却至少部分液化气流c和包含氯,氧和二氧化碳的富含氯的循环流f 1,产生至少部分液化的流d; e)将气流d气体/液体分离成包含氯气,氧气,二氧化碳和惰性气体的气流e 1并进入包含氯​​气,氧气和二氧化碳的液体流e 2中; f)将至少部分气流e 1进料到膜分离单元中并通过膜分离进行分馏,得到富氯循环流f 1和氯含量低的气流f 2,包括氯,氧和 二氧化碳和富氯循环流f 1再循环到步骤d); g)通过蒸馏将液体流e 2分离成氯流g 1和基本上包含氧和二氧化碳的流g 2。