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    • 3. 发明授权
    • Polycarbonate copolymers having improved hydrolytic stability
    • 具有改善的水解稳定性的聚碳酸酯共聚物
    • US06608163B2
    • 2003-08-19
    • US09764795
    • 2001-01-17
    • Christian Maria Emile BaillyTiberiu Mircea Siclovan
    • Christian Maria Emile BaillyTiberiu Mircea Siclovan
    • C08G6400
    • C08G64/06C08G64/12
    • The present invention provides polycarbonate copolymers having improved hydrolytic stability, solvent resistance, or combinations thereof. In particular, certain of the copolymers of the invention have improved resistance to dilute caustic solution. Thus, the copolymers of the present invention are particularly useful as structural elements in applications where such elements routinely come in contact with caustic solutions, such as in automatic dishwashing equipment. Preferred comonomers include 4,4′-biphenol, bis-(4-hydroxyphenyl)terephthalamide (“BHPT”), and a bisimide bisphenol obtained by reacting Bisphenol A dianhydride (BPADA) with 4,4′-isopropylidene phenol aniline. The comonomers are utilized along with 2,2-bis(4-hydroxyphenyl)propane (Bisphenol A) in concentrations in a range between about 1 and about 50 weight percent of the repeating units in the polycarbonate.
    • 本发明提供了具有改进的水解稳定性,耐溶剂性或其组合的聚碳酸酯共聚物。 特别地,本发明的某些共聚物具有改进的对苛性碱溶液的耐受性。 因此,本发明的共聚物特别可用作这些元素常规地与苛性碱溶液接触的应用中的结构元件,例如在自动洗碗设备中。 优选的共聚单体包括4,4'-联苯酚,双 - (4-羟基苯基)对苯二甲酰胺(“BHPT”)和通过双酚A二酐(BPADA)与4,4'-异亚丙基苯酚苯胺反应获得的双酰亚胺双酚。 共聚单体与聚碳酸酯中重复单元的约1至约50重量%之间的浓度与2,2-双(4-羟基苯基)丙烷(双酚A)一起使用。