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1. 发明授权

US5807916A Process for obtaining polymers which are superabsorbent for water and aqueous fluids in the form of particle aggregates 失效
标题翻译：获得聚合物的方法，该聚合物是颗粒聚集体形式的水和含水流体的超吸收剂
公开(公告)号：US5807916A
公开(公告)日：1998-09-15
申请号：US634309
申请日：1996-04-10
申请人： Christian Collette , Manuel Hidalgo , Andre Kowalik , Emmanuel Puchois , Shu-Rong Rebre
发明人： Christian Collette , Manuel Hidalgo , Andre Kowalik , Emmanuel Puchois , Shu-Rong Rebre
IPC分类号： B01J20/26 , A61L15/60 , C08F2/18 , C08F2/32 , C08F265/02 , C08J3/12 , C08F6/22
CPC分类号： C08J3/12 , A61L15/60 , C08F265/02 , C08J3/16 , C08J2300/14
摘要： The process consists in the agglomeration of fine particles of superabsorbent polymer, carried out by introducing an aqueous solution of monomer into a slurry of aqueous polymer dispersed within a hydrocarbon liquid, this introduction being performed directly at the temperature and in conditions of polymerization of the monomer. A superabsorbent product is thus obtained in a very good yield, in the form of aggregates of particles such that the fraction passing through a 100-micron screen is less than 1%.
摘要翻译：该方法包括通过将单体水溶液引入分散在烃液体中的水性聚合物的浆液中进行的超吸收聚合物细颗粒的聚集，该引入直接在单体的聚合温度和条件下进行。因此，以非常好的产率获得超吸收性产品，呈颗粒聚集体的形式，使得通过100微米筛网的级分小于1％。

2. 发明授权

US06458896B1 Superabsorbent powders of high absorption and high capillary suction 有权
标题翻译：高吸收和高毛细吸力的超吸收性粉末
公开(公告)号：US06458896B1
公开(公告)日：2002-10-01
申请号：US09180524
申请日：1999-05-21
申请人： Christian Collette , Manuel Hidalgo , Andre Kowalik , Fabienne Lebendenko , Emmanuel Puchois
发明人： Christian Collette , Manuel Hidalgo , Andre Kowalik , Fabienne Lebendenko , Emmanuel Puchois
IPC分类号： C08F400
CPC分类号： C08J3/12 , C08J2333/02 , C08L33/02
摘要： Certain mixtures of two superabsorbent powders having very different capillary suctions exhibit a resulting capillary suction which approaches the higher value. The resulting mixtures simultaneously exhibit a high capillary suction and a high intrinsic absorption capacity.
摘要翻译：具有非常不同毛细管吸力的两种超吸收性粉末的某些混合物表现出接近较高值的所得毛细吸力。所得混合物同时表现出高毛细吸力和高固有吸收能力。

3. 发明授权

US5976696A Shell/core particulates of superabsorbent polymers 失效
标题翻译：超吸收聚合物的壳/核心颗粒
公开(公告)号：US5976696A
公开(公告)日：1999-11-02
申请号：US796730
申请日：1997-02-07
申请人： Christian Collette , Manuel Hidalgo , Andre Kowalik , Emmanuel Puchois
发明人： Christian Collette , Manuel Hidalgo , Andre Kowalik , Emmanuel Puchois
IPC分类号： B01J20/26 , C08F8/00 , C08J3/24 , B32B5/16
CPC分类号： C08J3/245 , C08J2300/14 , Y10T428/2998
摘要： Shell/core distortion-resistant particulates of a partially crosslinked superabsorbent polymer, the gradient of partial crosslinking of which being to such extent that the shells are harder and less flexible than the cores thereof, have a capacity to absorb 0.9% saline water of at least 50 g/g and the modulus of which is at least 35,000 Pa; a bed of a saline water gel of the subject particulates has a saline water absorption of at least 20 g/g and a porosity of at least 500 g.
摘要翻译：部分交联的超吸收聚合物的壳/芯抗变形颗粒，其部分交联的梯度在这样的程度上使得壳比其芯更硬并且柔韧性更小，具有至少吸收0.9％盐水的能力 50g / g，模量为35,000Pa以上; 本发明颗粒的盐水凝胶床具有至少20g / g的盐水吸收和至少500g的孔隙率。

4. 发明授权

US5994419A Preparation of rapidly dissolving/absorbing powders of hydrophilic/super absorbent (CO)polymers 失效
标题翻译：亲水/超吸收（CO）聚合物快速溶解/吸收粉末的制备
公开(公告)号：US5994419A
公开(公告)日：1999-11-30
申请号：US970608
申请日：1997-11-14
申请人： Christian Collette , Manuel Hidalgo , Jean-Marc Corpart , Andre Kowalik , Paul Mallo
发明人： Christian Collette , Manuel Hidalgo , Jean-Marc Corpart , Andre Kowalik , Paul Mallo
IPC分类号： C08F2/00 , C08F2/18 , C08F2/32 , C08F20/06 , C08F20/56 , C08J9/28
CPC分类号： C08F2/32
摘要： Rapidly dissolving/absorbing free-flowing powders of hydrophilic/superabsorbent (co)polymers, having irregular nonspherical morphology and a particle size distribution ranging from 100 .mu.m to 800 .mu.m, are prepared by (a) phase inversion (co)polymerizing stirred admixture of (i) a hydrocarbonic solution of at least one surfactant having an HBL ranging from 8 to 12 and (ii) an aqueous solution of at least one hydrophilic unsaturated monomer, in the presence of an effective amount of a radical polymerization initiator and at a predetermined temperature of (co)polymerization, (b) next introducing into the medium of (co)polymerization, after (co)polymerization of the at least one hydrophilic unsaturated monomer, a second aqueous solution of at least one hydrophilic unsaturated monomer, (c) then (co)polymerizing the second aqueous solution, and (d) thence extracting the hydrocarbonic phase and water from the resulting (co)polymerizate and drying same, with the proviso (e) that the second aqueous monomer solution is introduced at a temperature of about the predetermined temperature of (co)polymerization and the volumetric ratio of aqueous phase to hydrocarbonic phase ranges from 0.6 to 1.2.
摘要翻译：通过（a）相转化（共）聚合搅拌的混合物制备具有不规则非球形形态和100μm至800μm的粒度分布的亲水/超吸收（共）聚合物的快速溶解/吸收的自由流动粉末（i）至少一种具有8-12的HBL的表面活性剂的烃溶液，和（ii）至少一种亲水性不饱和单体的水溶液，在有效量的自由基聚合引发剂存在下，和（共）聚合的预定温度，（b）在至少一种亲水性不饱和单体（第二种）亲水性不饱和单体的第二水溶液（c）聚合后，再次引入（共）聚合的介质中然后（共）聚合第二水溶液，和（d）从所得（共）聚合物中提取烃相和水并干燥，条件是（e）第二个在约（共）聚合的预定温度和水相与烃相的体积比范围为0.6至1.2的温度下引入高分子单体溶液。

5. 发明授权

US09017473B2 Neutralizing agent for paints 有权
标题翻译：油漆中和剂
公开(公告)号：US09017473B2
公开(公告)日：2015-04-28
申请号：US13121307
申请日：2009-09-25
申请人： Bruno Van Hemelryck , Manuel Hidalgo
发明人： Bruno Van Hemelryck , Manuel Hidalgo
IPC分类号： C09D7/12 , C09D5/16 , C08K5/3467 , C07D233/36 , C09D5/02 , C09D17/00 , C08K5/17 , C08K5/34
CPC分类号： C09D7/1233 , C08K5/17 , C08K5/34 , C09D7/63 , C09D17/003
摘要： The invention relates to a method of neutralizing paints, that includes adding at least one associative neutralizing agent to a formulation such as a pigment concentrate, a white paint base or paint. The associative neutralizing agent includes at least one neutralizing group N and at least one nitrogenous associative group A bonded together by at least one “spacer” group Sp. The invention also relates to pigment concentrates and to paints containing at least one such associative neutralizing agent.
摘要翻译：本发明涉及一种中和涂料的方法，其包括向制剂如颜料浓缩物，白漆基料或涂料中加入至少一种缔合中和剂。缔合中和剂包括至少一个中和基团N和至少一个通过至少一个“间隔基”基团Sp连接在一起的含氮缔合基团A. 本发明还涉及颜料浓缩物和含有至少一种这种缔合中和剂的油漆。

6. 发明申请

US20130211057A1 MOLECULES HAVING COMBINABLE GROUPS 有权
标题翻译：具有组合组的分子
公开(公告)号：US20130211057A1
公开(公告)日：2013-08-15
申请号：US13809767
申请日：2011-07-12
申请人： Nicolas Seeboth , Serguey Ivanov , Jean-Luc Couturier , Manuel Hidalgo
发明人： Nicolas Seeboth , Serguey Ivanov , Jean-Luc Couturier , Manuel Hidalgo
IPC分类号： C07D233/36
CPC分类号： C07D233/36 , C07D233/32 , C07D403/12
摘要： The present invention relates to nitrogenous associative molecules comprising at least one unit rendering them capable of associating with one another or with a filler by noncovalent bonds, and comprising a function capable of reacting with a polymer containing unsaturations so as to form a covalent bond with said polymer.
摘要翻译：本发明涉及包含至少一个单元的含氮缔合分子，使得它们能够通过非共价键彼此缔合或与填料缔合，并且包含能够与含有不饱和基团的聚合物反应以便与所述的共价键形成共价键的功能聚合物。

7. 发明申请

US20120034318A1 DIAGNOSTIC METHOD USING PALB2 有权
标题翻译：诊断方法使用PALB2
公开(公告)号：US20120034318A1
公开(公告)日：2012-02-09
申请号：US13254610
申请日：2010-03-05
申请人： Bert Vogelstein , Kenneth W. Kinzler , D. Williams Parsons , Sian Jones , Scott Kern , Ralph Hruban , James R. Eshleman , Michael Goggins , Alison Klein , Manuel Hidalgo , Victor E. Velculescu
发明人： Bert Vogelstein , Kenneth W. Kinzler , D. Williams Parsons , Sian Jones , Scott Kern , Ralph Hruban , James R. Eshleman , Michael Goggins , Alison Klein , Manuel Hidalgo , Victor E. Velculescu
IPC分类号： A61K33/24 , A61P35/00 , C40B20/08 , G01N33/577 , G01N33/566 , C12Q1/68
CPC分类号： C12Q1/6886 , A61K31/407 , C12Q2600/106 , C12Q2600/156 , C12Q2600/158 , G01N33/57438 , G01N2333/47
摘要： The present invention provides a method for detecting mutations in the PALB2 gene in pancreatic cancer patients and in individuals having a family history of pancreatic cancer. Methods are also provided for diagnosing a predisposition to pancreatic cancer, for predicting a patient's response to pancreatic cancer therapies, and for treating pancreatic cancer, based on presence of a PALB2 mutation or abberant PALB2 gene expression in a patient.
摘要翻译：本发明提供了一种检测胰腺癌患者和具有胰腺癌家族史的个体中PALB2基因突变的方法。还提供了用于诊断患有胰腺癌的倾向，用于预测患者对胰腺癌治疗的反应以及用于治疗患者胰腺癌的方法，其基于在患者体内PALB2突变或异常PALB2基因表达的存在。

8. 发明申请

US20120022221A1 Use, as a Shock Absorber, of a Material Formed from Branched Molecules Containing Associative Groups 有权
标题翻译：作为减震器使用由含有相关组的支链分子形成的材料
公开(公告)号：US20120022221A1
公开(公告)日：2012-01-26
申请号：US13254282
申请日：2010-03-29
申请人： Manuel Hidalgo , Nicolas Dufaure , Jean-Luc Couturier , Bruno Hemelryck
发明人： Manuel Hidalgo , Nicolas Dufaure , Jean-Luc Couturier , Bruno Hemelryck
IPC分类号： C08G65/333
CPC分类号： C08G63/12 , C08G83/005 , C08G83/008
摘要： The present invention relates to the use, as a shock absorber, of a material formed from branched molecules comprising associative groups. Said branched molecules are each constituted of fragments that are at least bifunctional and of fragments that are at least trifunctional joined together by ester or thioester bridges, alone or in combination with amide or urea bridges.
摘要翻译：本发明涉及作为减震器的由包含缔合基团的支链分子形成的材料的用途。所述支链分子各自由至少双功能的片段和至少三官能的片段组成，所述片段通过酯或硫酯桥连接在一起，单独或与酰胺或脲桥组合。

9. 发明申请

US20110144264A1 PROCESS FOR PREPARING STABILIZED LATICES BY EMULSION POLYMERIZATION 审中-公开
标题翻译：通过乳液聚合制备稳定胶粘剂的方法
公开(公告)号：US20110144264A1
公开(公告)日：2011-06-16
申请号：US12161447
申请日：2007-01-09
申请人： Manuel Hidalgo
发明人： Manuel Hidalgo
IPC分类号： C08L33/14
CPC分类号： C08F2/24 , C08F220/14 , C08F220/18 , C08F220/26 , C08F299/00 , C08F299/06 , C08F299/065
摘要： The invention relates to the use of poly(ethylene-co-propylene) glycol monoalkyl ether or polyethylene glycol monoalkyl ether or poly(ethylene-co-propylene) glycol or polyethylene glycol (meth)acrylic amide or ester monomers capable of contributing to stabilization in the course of a latex preparation process by emulsion polymerization of at least one polymerizable monomer in the presence of an ionizable polymerization initiator.
摘要翻译：本发明涉及能够有助于稳定化的聚（乙烯 - 共 - 丙烯）二醇单烷基醚或聚乙二醇单烷基醚或聚（乙烯 - 共 - 丙烯）二醇或聚乙二醇（甲基）丙烯酰胺或酯单体的用途通过在可电离聚合引发剂的存在下通过至少一种可聚合单体的乳液聚合的胶乳制备过程的过程。

10. 发明申请

US20110065866A1 Composition containing a halogenated vinyl polymer and a copolymer bearing associative groups 审中-公开
标题翻译：含有卤代乙烯基聚合物和带有缔合基团的共聚物的组合物
公开(公告)号：US20110065866A1
公开(公告)日：2011-03-17
申请号：US12991218
申请日：2009-05-05
申请人： Ludwik Leibler , Francois Genes Tournilhac , Nicolas Dufaure , Manuel Hidalgo
发明人： Ludwik Leibler , Francois Genes Tournilhac , Nicolas Dufaure , Manuel Hidalgo
IPC分类号： C08L39/04 , C09D139/04 , C09J139/04
CPC分类号： C09D127/00 , C08L27/00 , C08L33/00 , C08L2666/04 , C09J127/00
摘要： The present invention relates to a composition comprising: (a) at least one halogenated vinyl polymer and (b) at least one copolymer containing (i) units derived from a first monomer (A) rendering said copolymer compatible with said halogenated vinyl polymer and (ii) units derived from a second monomer (B) bearing at least one given associative group. The present invention also relates to the use of such a copolymer bearing associative groups, for improving certain properties of a halogenated vinyl polymer. The invention finally relates to the uses of the aforementioned composition.
摘要翻译：本发明涉及一种组合物，其包含：（a）至少一种卤代乙烯基聚合物和（b）至少一种共聚物，其包含（i）衍生自第一单体（A）的单元，使所述共聚物与所述卤代乙烯基聚合物相容和（ ii）衍生自具有至少一个给定缔合基团的第二单体（B）的单元。本发明还涉及这种共聚物支持缔合基团用于改进卤代乙烯基聚合物的某些性能的用途。本发明最终涉及上述组合物的用途。

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