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1. 发明授权

US08088850B1 Polyacrylate compositions 有权
标题翻译：聚丙烯酸酯组合物
公开(公告)号：US08088850B1
公开(公告)日：2012-01-03
申请号：US11755159
申请日：2007-05-30
申请人： Chiu-Sing Lin , Shingo Tsuno , Rajat K. Agarwal , Thomas Fay-Oy Lim
发明人： Chiu-Sing Lin , Shingo Tsuno , Rajat K. Agarwal , Thomas Fay-Oy Lim
IPC分类号： C08K5/41 , C08K5/51 , C08K5/16 , C08G18/42 , C08L83/06 , C08L47/00
CPC分类号： C08G18/10 , C08K5/18 , C08K5/42 , C08L43/04
摘要： The present invention provides curable poly(acrylate) compositions, cured reaction products of which demonstrate improved resistance to shrinkage when exposed to hydrocarbon fluids, such as transmission fluids and oil-and fuel-based fluids.
摘要翻译：本发明提供可固化的聚（丙烯酸酯）组合物，其固化反应产物在暴露于烃流体（例如透射液体和基于油和燃料的流体）时表现出改善的抗收缩性。

2. 发明授权

US08066288B2 Components comprising polyisobutylene compositions 有权
标题翻译：组分包括聚异丁烯组合物
公开(公告)号：US08066288B2
公开(公告)日：2011-11-29
申请号：US12477253
申请日：2009-06-03
申请人： Matthew P. Burdzy , Shingo Tsuno
发明人： Matthew P. Burdzy , Shingo Tsuno
IPC分类号： F02F11/00
CPC分类号： C08L23/22 , C08L83/04 , C08L2312/02 , C08L2312/08 , Y10T428/31663 , C08L83/00
摘要： This document provides components comprising a predetermined sealing surface and a curable composition thereon. The cured reaction product of the curable composition forms a seal having improved resistance to vapor permeation when exposed to hydrocarbon fluids and especially to hydrocarbon fluids comprising low molecular weight components, oxygenated compounds, polar compounds or blends containing polar and non-polar compounds such as alcohol and alcohol containing fuels.
摘要翻译：本文件提供了包含预定密封表面和其上的可固化组合物的组分。可固化组合物的固化反应产物当暴露于烃流体，特别是包含低分子量组分，含氧化合物，极性化合物或含有极性和非极性化合物如酒精的共混物的烃流体时形成具有改善的耐蒸汽渗透性的密封剂和含有燃料的酒精。

3. 发明申请

US20090299017A1 One-Part Type Moisture Curable Composition 审中-公开
标题翻译：单组分型水分可固化组合物
公开(公告)号：US20090299017A1
公开(公告)日：2009-12-03
申请号：US12223660
申请日：2007-02-08
申请人： Shingo Tsuno , Toshihide Sasaki
发明人： Shingo Tsuno , Toshihide Sasaki
IPC分类号： C08F283/12 , C08F283/06
CPC分类号： C08G18/4825 , C08G18/10 , C08G2190/00 , C09J175/04 , C08G18/289
摘要： To provide a one-part type moisture curable composition exhibiting superior adhesion properties, weather resistance, coating tolerance, and the like, and providing good operationability, which is cured by moisture in the atmosphere to form an elastic material in the form of a rubber A one-part type moisture curable composition comprising: (A) a prepolymer having a urea bond(s), a urethane bond(s), and a hydrolysable silyl group(s) at a chain end(s) or pendent position(s) thereof; and (B) a polymer comprising a polyether structure(s) and/or a polyacryl structure(s) in the main chain, and having a hydrolysable silyl group(s) at a chain end(s) or pendent position(s) thereof.
摘要翻译：为了提供显示出优异的粘合性，耐候性，涂布耐受性等的单组分型的湿气固化性组合物，并且提供良好的可操作性，其由大气中的水分固化以形成橡胶A形式的弹性材料一部分型湿气固化组合物，其包含：（A）在链末端或侧挂位置具有尿素键，氨基甲酸酯键和可水解甲硅烷基的预聚物，的; 和（B）在主链中包含聚醚结构和/或聚丙烯酸酯结构的聚合物，并且在链末端或其侧链位置具有可水解甲硅烷基。

4. 发明申请

US20090263669A1 COMPONENTS COMPRISING POLYISOBUTYLENE COMPOSITIONS 有权
标题翻译：包含聚异丁烯组合物的组分
公开(公告)号：US20090263669A1
公开(公告)日：2009-10-22
申请号：US12477253
申请日：2009-06-03
申请人： Matthew P. Burdzy , Shingo Tsuno
发明人： Matthew P. Burdzy , Shingo Tsuno
IPC分类号： B32B27/06 , B32B37/00
CPC分类号： C08L23/22 , C08L83/04 , C08L2312/02 , C08L2312/08 , Y10T428/31663 , C08L83/00
摘要： This document provides components comprising a predetermined sealing surface and a curable composition thereon. The cured reaction product of the curable composition forms a seal having improved resistance to vapor permeation when exposed to hydrocarbon fluids and especially to hydrocarbon fluids comprising low molecular weight components, oxygenated compounds, polar compounds or blends containing polar and non-polar compounds such as alcohol and alcohol containing fuels.
摘要翻译：本文件提供了包含预定密封表面和其上的可固化组合物的组分。可固化组合物的固化反应产物当暴露于烃流体，特别是包含低分子量组分，含氧化合物，极性化合物或含有极性和非极性化合物如酒精的共混物的烃流体时形成具有改善的耐蒸汽渗透性的密封剂和含有燃料的酒精。

5. 发明申请

US20060155045A1 (Meth)acrylic adhesive with low odor and high impact resistance 审中-公开
标题翻译：（Meth）丙烯酸粘合剂，具有低气味和高抗冲击性
公开(公告)号：US20060155045A1
公开(公告)日：2006-07-13
申请号：US11143460
申请日：2005-06-03
申请人： Shingo Tsuno , Ria De Cooman
发明人： Shingo Tsuno , Ria De Cooman
IPC分类号： C08L53/00
CPC分类号： C09J175/16 , C08F290/048 , C08F290/062 , C08F290/067 , C08G18/4825 , C08G18/672 , C08G18/7657 , C08G18/48
摘要： The present invention relates to (meth)acrylic adhesives with high impact resistance and no or low odor. The compositions comprise at least a (meth)acrylic ester E which may be obtained by esterification of an alcohol ALC and methacrylic or acrylic acid, said alcohol ALC contains at least 5 carbon atoms; and at least a rubber block co-polymer RS being solid at room temperature and which is a co-polymer of styrene and butadiene and/or isoprene and/or ethylene propylene diene monomer; and at least a polymer PL having pending (meth)acrylic groups and is a butadiene/acrylonitrile co-poly- mer with terminal (meth)acrylic groups or a polyurethane (meth)acrylate or an ester obtainable by esterification of an alcohol ALC-II and methacrylic or acrylic acid and which has a molecular weight between 200 and 9000 g/mol. Such combinations E-RS-PL have lower viscosity than PL and a combination E-RS.
摘要翻译：本发明涉及具有高耐冲击性和无气味的（甲基）丙烯酸类粘合剂。组合物包含至少一种（甲基）丙烯酸酯E，其可以通过醇ALC和甲基丙烯酸或丙烯酸的酯化获得，所述醇ALC含有至少5个碳原子; 并且至少橡胶嵌段共聚物RS在室温下为固体，并且是苯乙烯和丁二烯和/或异戊二烯和/或乙烯丙烯二烯单体的共聚物; 和至少具有未决（甲基）丙烯酸基团的聚合物PL和具有末端（甲基）丙烯酸基团的丁二烯/丙烯腈共聚物或聚氨酯（甲基）丙烯酸酯或通过醇ALC-II酯化获得的酯甲基丙烯酸或丙烯酸，其分子量为200-9000g / mol。这种组合E-RS-PL具有比PL更低的粘度和组合E-RS。

6. 发明授权

US06602947B2 Primer 失效
标题翻译：底漆
公开(公告)号：US06602947B2
公开(公告)日：2003-08-05
申请号：US09843754
申请日：2001-04-30
申请人： Peter W. Merz , Shingo Tsuno
发明人： Peter W. Merz , Shingo Tsuno
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08G18/10 , C08G18/6208 , C08J7/04 , C08J7/047 , C08J2475/00 , C08J2483/00 , Y10T428/31551 , C08G18/307
摘要： New primers for the improvement of the adhesion of cross-linking adhesive systems top polyolefinic thermoplastic materials such as e.g., polypropylene, polyethylene or EPDM are disclosed. Said primers, on the one hand are characterized by a simple method of production and good storage stability, on the other hand by good wetting and good homogeneous film forming characteristics, said film forming characteristics enabling a uniform thickness of the layer, leading to good adhesion qualities. Essential constituents of such primers are prepolymers based on hydrogenated polyisoprene diol.
摘要翻译：公开了用于改善交联粘合剂体系粘合性的新型底漆，顶层聚烯烃热塑性材料如聚丙烯，聚乙烯或EPDM。一方面，所述底漆的特征在于简单的生产方法和良好的储存稳定性，另一方面，通过良好的润湿性和良好的均匀成膜特性，所述成膜特性使得该层的厚度均匀，导致良好的粘附力品质这种引物的基本成分是基于氢化聚异戊二烯二醇的预聚物。

7. 发明授权

US06548593B2 Thixotropic agent 失效
公开(公告)号：US06548593B2
公开(公告)日：2003-04-15
申请号：US09846293
申请日：2001-05-02
申请人： Peter W. Merz , Ukiwo Onuoha , Shingo Tsuno
发明人： Peter W. Merz , Ukiwo Onuoha , Shingo Tsuno
IPC分类号： C08L7500
CPC分类号： C09K3/1021 , C08G18/10 , C08G18/2865 , C08G18/4825 , C08G2190/00 , C09K2003/1071 , C08G18/2855
摘要： New thixotropic agents for the use in cross-linking systems, in particular one-component adhesives and sealants, are described. The thixotropic agents have the advantage that on the one hand they cause only a minor or no increase in viscosity, and on the other hand they do not cause any blead out or migration, respectively. The thixotropic agents of the present invention are based on urea derivatives that usually are present in a concentration of 5 to 50 wt.-%, in particular of 15 to 30 wt.-%, in a preferably reactive carrier material. After the cross-linking of the system, the reactive carrier material is incorporated, preferably into the structure matrix, or interwoven with said structure matrix, respectively, such that it can not diffuse out of the cured material.

8. 发明授权

US08070908B2 (Meth)acrylic adhesive with low odor and high impact resistance 失效
标题翻译：（Meth）丙烯酸粘合剂，具有低气味和高抗冲击性
公开(公告)号：US08070908B2
公开(公告)日：2011-12-06
申请号：US12113698
申请日：2008-05-01
申请人： Shingo Tsuno , Ria De Cooman
发明人： Shingo Tsuno , Ria De Cooman
IPC分类号： C09J133/20 , C08J153/00
CPC分类号： C09J175/16 , C08F290/048 , C08F290/062 , C08F290/067 , C08G18/4825 , C08G18/672 , C08G18/7657 , C08G18/48
摘要： The present invention relates to (meth)acrylic adhesives with high impact resistance and no or low odor. The compositions comprise at least a (meth)acrylic ester E which may be obtained by esterification of an alcohol ALC and methacrylic or acrylic acid, said alcohol ALC contains at least 5 carbon atoms; and at least a rubber block co-polymer RS being solid at room temperature and which is a co-polymer of styrene and butadiene and/or isoprene and/or ethylene propylene diene monomer; and at least a polymer PL having pending (meth)acrylic groups and is a butadiene/acrylonitrile co-polymer with terminal (meth)acrylic groups or a polyurethane (meth)acrylate or an ester obtainable by esterification of an alcohol ALC-II and methacrylic or acrylic acid and which has a molecular weight between 200 and 9000 g/mol. Such combinations E-RS-PL have lower viscosity than PL and a combination E-RS.
摘要翻译：本发明涉及具有高耐冲击性和无气味的（甲基）丙烯酸类粘合剂。组合物包含至少一种（甲基）丙烯酸酯E，其可以通过醇ALC和甲基丙烯酸或丙烯酸的酯化获得，所述醇ALC含有至少5个碳原子; 并且至少橡胶嵌段共聚物RS在室温下为固体，并且是苯乙烯和丁二烯和/或异戊二烯和/或乙烯丙烯二烯单体的共聚物; 和至少具有未决（甲基）丙烯酸基团的聚合物PL，并且是具有末端（甲基）丙烯酸基团的丁二烯/丙烯腈共聚物或聚氨酯（甲基）丙烯酸酯或可通过酯化醇ALC-II和甲基丙烯酸甲酯或丙烯酸，其分子量为200-9000g / mol。这种组合E-RS-PL具有比PL更低的粘度和组合E-RS。

9. 发明授权

US5206331A Sealant composition comprising moisture curable isocyanurate containing compound 失效
标题翻译：包含含湿固化异氰脲酸酯化合物的密封剂组合物
公开(公告)号：US5206331A
公开(公告)日：1993-04-27
申请号：US714844
申请日：1991-06-13
申请人： Shingo Tsuno , Ryuichi Ueda , Masahiro Ito
发明人： Shingo Tsuno , Ryuichi Ueda , Masahiro Ito
IPC分类号： C09K3/10 , C08G18/02 , C08G18/10
CPC分类号： C08G18/10 , C08G2170/20 , C08G2190/00 , Y10S528/905
摘要： At least some of the isocyanate groups in the cured polyurethane sealant of this invention have the isocyanurate structure. A moisture-curing sealant composition of the invention comprises an active isocyanato-terminated isocyanate prepolymer containing a polyol component with a molecular weight of 2,000 to 20,000 and an isocyanurating agent. The sealant composition of the present invention is particularly excellent in initial bond strength due to sharp viscosity buildup.
摘要翻译：本发明固化的聚氨酯密封剂中的至少一些异氰酸酯基团具有异氰脲酸酯结构。本发明的湿润固化密封剂组合物包含含有分子量为2,000〜20,000的多元醇成分的异氰酸酯基封端的异氰酸酯预聚物和异氰脲酸酯。本发明的密封剂组合物由于强烈的粘度增加而具有特别优异的初始粘结强度。

10. 发明授权

US5109057A Primer composition 失效
标题翻译：主要成分
公开(公告)号：US5109057A
公开(公告)日：1992-04-28
申请号：US550674
申请日：1990-07-10
申请人： Shingo Tsuno , Masahiro Ito
发明人： Shingo Tsuno , Masahiro Ito
IPC分类号： C09D5/00 , C08G18/80 , C09J5/02 , C09J11/06 , C09J175/04 , C09J201/00
CPC分类号： C08G18/809 , C08G18/8012 , C09J5/02
摘要： Primer composition comprising a silane coupling agent, an alkoxysilylated NCO-containing urethane prepolymer which is prepared by reacting a polyisocyanate with a diol to give an NCO-containing urethane prepolymer, and reacting the resulting NCO-containing urethane prepolymer with a trialkoxysilane having a functional group active to NCO group wherein a part of whole of the remaining NCO groups of the high molecular weight polyisocyanate are reacted with the silane. Said primer composition has excellent plasticizer resistance, solvent resistance and film-forming properties and further improved adhesin properties to glass, metals, ceramics, and is useful as a primer for various adhesives, particularly for applying to glass, metals, and ceramics.
摘要翻译：含有硅烷偶联剂，烷氧基甲硅烷基化NCO的氨基甲酸酯预聚物的底漆组合物，其通过使多异氰酸酯与二醇反应得到含有NCO的氨基甲酸酯预聚物，使得到的含有NCO的氨基甲酸酯预聚物与具有官能团的三烷氧基硅烷活性至NCO基团，其中高分子量多异氰酸酯的剩余NCO基团的全部的一部分与硅烷反应。所述底漆组合物具有优异的耐增塑剂性，耐溶剂性和成膜性，并且进一步提高了对玻璃，金属，陶瓷的粘合剂性能，并且可用作各种粘合剂的底漆，特别适用于玻璃，金属和陶瓷。

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