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    • 4. 发明授权
    • Substituted acylating agents and their production
    • 取代的酰化剂及其制备
    • US5137978A
    • 1992-08-11
    • US762453
    • 1991-09-19
    • David J. DegoniaPaul G. Griffin
    • David J. DegoniaPaul G. Griffin
    • C07C51/567C08F8/10C08F8/46
    • C07C51/567C08F255/10
    • Polybutenyl substituted succinic acylating agents are formed by reacting (a) an acidic reactant represented by the general formulaR--CO--CH.dbd.CH--CO--R'wherein R and R' are independently --OH, --O--lower alkyl, a halogen atom, or taken together are a single oxygen atom, with (b) a polymer composed mainly or entirely of polyisobutene, at least 50% of the polyisobutene content of the polymer having an end group represented by the formula ##STR1##The mole ratio o9f acidic reactant: polymer is at least 1:1; and the reaction mixture is maintained under superatmospheric pressure during at least a substantial portion of the reaction period. The reaction rate is high, the yields of desired product are high, and despite the fact that superatmospheric pressures and elevated temperatures are used, the process forms only small amounts of tars or resinous co-products, even when employing as much as a 20% or more molar excess of maleic anhydride. Any unreacted acidic reactant such as maleic anhydride, maleic acid, fumaric acid, etc. can be, and preferably is, recovered from the reation mixture, and thus is available for use either as recycle to the process or for other uses. Inasmuch as chlorine is not used in the process, the expense and difficulties associated with handling chlorine on a plant scale are eliminated, and the product is less corrosive than corresponding products formed by use of chlorine.
    • 聚丁烯基取代的琥珀酰化剂通过(a)由通式R-CO-CH = CH-CO-R'表示的酸性反应物反应形成,其中R和R'独立地是-OH,-O-低级烷基,卤素 原子或一起是单个氧原子,(b)主要或完全由聚异丁烯构成的聚合物,具有由下式表示的端基的聚合物的至少50%的聚异丁烯含量: 酸性反应物:聚合物至少为1:1; 并且反应混合物在至少大部分反应期间内保持在超大气压下。 反应速率高,所需产物的产率高,并且尽管使用超大气压和升高的温度,但该方法仅形成少量焦油或树脂共产物,即使使用多达20% 或更多摩尔过量的马来酸酐。 任何未反应的酸性反应物如马来酸酐,马来酸,富马酸等可以并且优选地从回收混合物中回收,因此可以作为循环使用或用于其它用途。 由于在该过程中不使用氯,因此消除了与处理工厂规模的氯相关的费用和困难,并且该产品比使用氯形成的相应产品的腐蚀性低。