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1. 发明授权

US08044152B2 Epoxy resin containing side-chain-tethered caged POSS and preparation method thereof as well as epoxy resin material containing POSS-epoxy and preparation method thereof 有权
标题翻译：含有侧链笼式POSS的环氧树脂及其制备方法以及含有POSS-环氧树脂的环氧树脂材料及其制备方法
公开(公告)号：US08044152B2
公开(公告)日：2011-10-25
申请号：US12247335
申请日：2008-10-08
申请人： Cheng-Chien Yang , Chen-Chi M. Ma , Wang-Tsae Gu , Chin-Yih Chen
发明人： Cheng-Chien Yang , Chen-Chi M. Ma , Wang-Tsae Gu , Chin-Yih Chen
IPC分类号： C08G77/42
CPC分类号： C08G77/045 , C08G77/08 , C08G77/14
摘要： An epoxy resin containing side-chain-tethered caged POSS and a preparation method thereof as well as epoxy resin material containing POSS-epoxy and a preparation method thereof are disclosed. The epoxy resin containing side-chain-tethered caged POSS (POSS epoxy) is formed by tethering of POSS group to the side chain of the diglycidyl ether of bisphenol A (DGEBA) epoxy resin. The preparation method of the POSS epoxy includes a step of reacting epoxy resin with caged POSS to form epoxy resin containing side-chain-tethered caged POSS (POSS-epoxy). The preparation method of epoxy resin material containing POSS-epoxy includes a step of reacting DGEBA epoxy resin with POSS-epoxy to get epoxy resin material containing POSS-epoxy. The POSS-epoxy is distributed evenly in the epoxy resin material with POSS-epoxy.
摘要翻译：公开了含有侧链笼式POSS的环氧树脂及其制备方法以及含有POSS-环氧树脂的环氧树脂材料及其制备方法。含有侧链笼式POSS（POSS环氧树脂）的环氧树脂通过将POSS基团连接到双酚A（DGEBA）环氧树脂的二缩水甘油醚的侧链而形成。 POSS环氧树脂的制备方法包括使环氧树脂与笼状POSS反应形成含有侧链笼式POSS（POSS-环氧树脂）的环氧树脂的步骤。含有POSS-环氧树脂的环氧树脂材料的制备方法包括使DGEBA环氧树脂与POSS-环氧树脂反应得到含有POSS-环氧树脂的环氧树脂材料的步骤。 POSS-环氧树脂均匀分布在具有POSS-环氧树脂的环氧树脂材料中。

2. 发明申请

US20100087616A1 Epoxy resin containing side-chain-tethered caged POSS and preparation method thereof as well as epoxy resin material containing POSS-epoxy and preparation method thereof 有权
标题翻译：含有侧链笼式POSS的环氧树脂及其制备方法以及含有POSS-环氧树脂的环氧树脂材料及其制备方法
公开(公告)号：US20100087616A1
公开(公告)日：2010-04-08
申请号：US12247335
申请日：2008-10-08
申请人： Cheng-Chien YANG , Chen-Chi M. Ma , Wang-Tsae Gu , Chin-Yih Chen
发明人： Cheng-Chien YANG , Chen-Chi M. Ma , Wang-Tsae Gu , Chin-Yih Chen
IPC分类号： C08G77/08 , C08G77/04
CPC分类号： C08G77/045 , C08G77/08 , C08G77/14
摘要： An epoxy resin containing side-chain-tethered caged POSS and a preparation method thereof as well as epoxy resin material containing POSS-epoxy and a preparation method thereof are disclosed. The epoxy resin containing side-chain-tethered caged POSS (POSS epoxy) is formed by tethering of POSS group to the side chain of the diglycidyl ether of bisphenol A (DGEBA) epoxy resin. The preparation method of the POSS epoxy includes a step of reacting epoxy resin with caged POSS to form epoxy resin containing side-chain-tethered caged POSS (POSS-epoxy). The preparation method of epoxy resin material containing POSS-epoxy includes a step of reacting DGEBA epoxy resin with POSS-epoxy to get epoxy resin material containing POSS-epoxy. The POSS-epoxy is distributed evenly in the epoxy resin material with POSS-epoxy.
摘要翻译：公开了含有侧链笼式POSS的环氧树脂及其制备方法以及含有POSS-环氧树脂的环氧树脂材料及其制备方法。含有侧链笼式POSS（POSS环氧树脂）的环氧树脂通过将POSS基团连接到双酚A（DGEBA）环氧树脂的二缩水甘油醚的侧链而形成。 POSS环氧树脂的制备方法包括使环氧树脂与笼状POSS反应形成含有侧链笼式POSS（POSS-环氧树脂）的环氧树脂的步骤。含有POSS-环氧树脂的环氧树脂材料的制备方法包括使DGEBA环氧树脂与POSS-环氧树脂反应得到含有POSS-环氧树脂的环氧树脂材料的步骤。 POSS-环氧树脂均匀分布在具有POSS-环氧树脂的环氧树脂材料中。

3. 发明申请

US20100127428A1 Fabrication of carbon nanotubes reinforced semi-crystalline polymer composite bipolar plates for fuel cell 审中-公开
标题翻译：用于燃料电池的碳纳米管增强半结晶聚合物复合双极板的制造
公开(公告)号：US20100127428A1
公开(公告)日：2010-05-27
申请号：US12458649
申请日：2009-07-20
申请人： Chen-Chi M. Ma , Shu-Hang Liao , Chuan-Yu Yen , Cheng-Chih Weng , Ching-Hung Yang , Ming-Yu Yen , Min-Chien Hsiao , Shuo-Jen Lee , Yi-Hsiu Hsiao
发明人： Chen-Chi M. Ma , Shu-Hang Liao , Chuan-Yu Yen , Cheng-Chih Weng , Ching-Hung Yang , Ming-Yu Yen , Min-Chien Hsiao , Shuo-Jen Lee , Yi-Hsiu Hsiao
IPC分类号： C08L23/12 , C08L23/14 , C08K3/04 , B29C45/00 , B29C43/02
CPC分类号： B29C45/0013 , B29B2009/125 , B29C43/003 , B29K2023/12 , B29K2105/16 , B29K2105/167 , B29K2303/04 , B29K2503/04 , B29L2031/3468 , C08L23/10 , H01M8/0213 , H01M8/0221 , H01M8/0226 , H01M2008/1095
摘要： A composite bipolar plate for a polymer electrolyte membrane membrane fuel cell (PEMFC) is prepared as follows: a) melt compounding a polypropylene resin and graphite powder at 100-250° C. and 30-150 rpm to form a melt compounding material, the graphite powder content ranging from 50 wt % to 95 wt % based on the total weight of the graphite powder and the polypropylene resin, and the polypropylene resin being a homopolymer of propylene or a copolymer of propylene and ethylene, wherein 0.05-20 wt % carbon nanotubes, based on the weight of the polypropylene resin, are added during the melt compounding; and b) molding the melt compounding material from step a) to form a bipolar plate having a desired shaped at 100-250° C. and 500-4000 psi.
摘要翻译：用于聚合物电解质膜式燃料电池（PEMFC）的复合双极板如下制备：a）在100-250℃和30-150rpm下将聚丙烯树脂和石墨粉末熔融混合以形成熔融配混材料，基于石墨粉末和聚丙烯树脂的总重量，石墨粉末含量为50重量％至95重量％，聚丙烯树脂为丙烯均聚物或丙烯与乙烯的共聚物，其中0.05-20重量％的碳在熔融配混过程中加入基于聚丙烯树脂重量的纳米管; 和b）从步骤a）模制熔融配混材料以形成在100-250℃和500-4000psi下具有所需成型的双极板。

4. 发明授权

US5484853A Cryogenic adhesives made from epoxy terminated urethanes 失效
标题翻译：由环氧封端的聚氨酯制成的低温粘合剂
公开(公告)号：US5484853A
公开(公告)日：1996-01-16
申请号：US90798
申请日：1993-07-28
申请人： Der-Shyang Chen , Hung-Chung Hsia , Chen-Chi M. Ma , Wang-Nang Wang
发明人： Der-Shyang Chen , Hung-Chung Hsia , Chen-Chi M. Ma , Wang-Nang Wang
IPC分类号： C08G18/10 , C08G59/22 , C08G59/28 , C08G59/50 , C09J163/00 , C08F283/04
CPC分类号： C09J163/00 , C08G18/10 , C08G59/226 , C08G59/28 , C08G59/50
摘要： A two-part adhesive composition having superior adhesive strength at cryogenic temperatures contains a urethane resin composition part and a hardener part. The urethane resin composition part comprises 50 to 99% by weight of a modified polyurethane prepolymer having an epoxy group at each of its respective ends and 1 to 50% by weight of a modified urethane compound having substantially no ether cyanate (NCO) groups and at least two epoxy groups per molecule and a molecular weight of less than 800 daltons. The hardener part is a polyamine containing primary or secondary amine groups. The equivalent ratio of the amine groups of the polyamine to the epoxy groups of the urethane resin composition part is 0.5 to 2.0.
摘要翻译：在低温下具有优异粘合强度的两部分粘合剂组合物包含聚氨酯树脂组合物部分和硬化剂部分。聚氨酯树脂组合物部分包含50〜99重量％的各自末端具有环氧基的改性聚氨酯预聚物和1〜50重量％的基本上不具有醚氰酸酯（NCO）的改性氨基甲酸酯化合物，并且在每分子至少两个环氧基团和分子量小于800道尔顿。固化剂部分是含有伯胺或仲胺基团的多胺。聚氨酯与聚氨酯树脂组合物部分的环氧基的胺基的当量比为0.5〜2.0。

5. 发明授权

US4622192A Stampable sheets of glass/carbon fiber mat reinforced polymers of olefin and method of preparation 失效
标题翻译：玻璃/碳纤维毡可压缩片材烯烃增强聚合物及其制备方法
公开(公告)号：US4622192A
公开(公告)日：1986-11-11
申请号：US569624
申请日：1984-01-10
申请人： Chen-Chi M. Ma
发明人： Chen-Chi M. Ma
IPC分类号： B29B11/16 , B29B15/12 , B29C51/12 , B29C70/38 , B29C70/50 , B29K23/00 , B29K105/08 , C08J5/04 , B29C24/00 , B32B1/02 , B32B17/04 , H05K9/00
CPC分类号： B29C70/506 , B29B15/12 , B29B15/125 , C08J5/047 , C08J2323/02 , C08J2323/06 , Y10S428/922 , Y10T156/1048 , Y10T428/249949 , Y10T428/30
摘要： A method for preparing stampable composites of polymer of olefin and fiber mat composites which are a mixture of glass fiber and carbon fiber by surrounding a fiber mat of a mixture of glass fiber and carbon fiber with a matrix of polymer of olefin. A stampable composite of polymer of olefin and fiber mat produced by such a method.
摘要翻译：一种通过将玻璃纤维和碳纤维的混合物的纤维垫与烯烃聚合物基体包围的方法，制备作为玻璃纤维和碳纤维的混合物的烯烃和纤维毡复合材料的可冲压复合材料的方法。通过这种方法生产的可聚合烯烃和纤维垫的可冲压复合材料。

6. 发明申请

US20120001130A1 METHOD FOR MANUFACTURING CONDUCTIVE ADHESIVE CONTAINING ONE-DIMENSIONAL CONDUCTIVE NANOMATERIAL 有权
标题翻译：制造含有一维导电性纳米材料的导电粘合剂的方法
公开(公告)号：US20120001130A1
公开(公告)日：2012-01-05
申请号：US12827093
申请日：2010-06-30
申请人： Yi-Hsiuan Yu , Bao-Yann Lin , Ming-Hsiung Wei , Lea-Hwung Leu , Gou-Hong Yiin , Chen-Chi M. Ma
发明人： Yi-Hsiuan Yu , Bao-Yann Lin , Ming-Hsiung Wei , Lea-Hwung Leu , Gou-Hong Yiin , Chen-Chi M. Ma
IPC分类号： H01B1/02
CPC分类号： H01B1/22
摘要： A method for manufacturing a conductive adhesive containing a one-dimensional (1D) conductive nanomaterial is revealed. The method produces a conductive adhesive by mixing the 1D conductive nanomaterial with water-based or solvent-based resin solution. The conductive adhesive has good industrial applications, not influenced by industrial adaptability and environmental adaptability. The conductive adhesive obtained also has better conductivity. Moreover, the amount of the 1D conductive nanomaterial used in the present invention is less than the amount of conductive nanoparticles used and the cost is reduced effectively.
摘要翻译：揭示了含有一维（1D）导电纳米材料的导电粘合剂的制造方法。该方法通过将1D导电纳米材料与水基或溶剂型树脂溶液混合而产生导电粘合剂。导电胶粘剂具有良好的工业应用，不受工业适应性和环境适应性的影响。获得的导电粘合剂也具有更好的导电性。此外，本发明中使用的1D导电纳米材料的量小于所使用的导电纳米粒子的量，并且有效降低了成本。

7. 发明申请

US20110315934A1 Method for fabrication of functionalized graphene reinforced composite conducting plate 审中-公开
标题翻译：功能化石墨烯增强复合导电板的制造方法
公开(公告)号：US20110315934A1
公开(公告)日：2011-12-29
申请号：US12923545
申请日：2010-09-28
申请人： Chen-Chi M. Ma , Min-Chien Hsiao , Shu-Hang Liao , Ming-Yu Yen , Ming-Der Ger , Chung-An Wang , Nen-Wen Pu , Yuh Sung , Chih-Chun Teng , Shie-Heng Lee , Min-Hsuan Hsiao
发明人： Chen-Chi M. Ma , Min-Chien Hsiao , Shu-Hang Liao , Ming-Yu Yen , Ming-Der Ger , Chung-An Wang , Nen-Wen Pu , Yuh Sung , Chih-Chun Teng , Shie-Heng Lee , Min-Hsuan Hsiao
IPC分类号： H01B1/24
CPC分类号： H01B1/24 , H01M4/96 , H01M8/0213 , H01M8/188 , H01M8/20 , Y02E60/528
摘要： A graphite-vinyl ester resin composite conducting plate is prepared in the present invention. The conducting plate can be used as a bipolar plate for a fuel cell, counter electrode for dye-sensitized solar cell and electrode of vanadium redox battery. The conducting plate is prepared as follows: a) compounding vinyl ester resin and graphite powder to form a bulk molding compound (BMC) material, the graphite powder content ranging from 70 wt % to 95 wt % based on the total weight of the graphite powder and vinyl ester, wherein 0.01-15 wt % functionalized graphene, based on the weight of the vinyl ester resin, are added during the compounding; b) molding the BMC material from step a) to form a conducting plate having a desired shaped at 80-250° C. and 500-4000 psi.
摘要翻译：在本发明中制备石墨 - 乙烯基酯树脂复合导电板。导电板可用作燃料电池的双极板，染料敏化太阳能电池的对电极和钒氧化还原电池的电极。导电板的制备如下：a）将乙烯基酯树脂和石墨粉末混合以形成体积模塑料（BMC）材料，石墨粉末的含量基于石墨粉末的总重量为70wt％至95wt％和乙烯基酯，其中在配混期间加入基于乙烯基酯树脂的重量的0.01-15重量％的官能化石墨烯; b）从步骤a）模制BMC材料，以形成在80-250℃和500-4000psi下具有所需成形的导电板。

8. 发明授权

US4347287A Segmented pultrusions comprising continuous lengths of fiber having selected areas along the lengths containing resin matrix impregnations 失效
标题翻译：分段拉挤包括连续长度的纤维，沿着包含树脂基质浸渍的长度具有选定的区域
公开(公告)号：US4347287A
公开(公告)日：1982-08-31
申请号：US178226
申请日：1980-08-14
申请人： Armand F. Lewis , Chen-Chi M. Ma , Hoa Quach , Edward J. Krasnicki
发明人： Armand F. Lewis , Chen-Chi M. Ma , Hoa Quach , Edward J. Krasnicki
IPC分类号： B29C70/52 , B32B3/10 , D02G3/36
CPC分类号： B29C70/527 , B29C70/525 , Y10T428/2938 , Y10T428/2967 , Y10T428/2969 , Y10T428/2976
摘要： A system and method for forming a segmented pultruded shape is provided in which a continuous length of fiber reinforcements are impregnated with a matrix material and then formed into a continuous series of alternating rigid segments and flexible segments by curing the matrix material impregnating the rigid sections and removing the matrix material impregnating the flexible sections.
摘要翻译：提供了一种用于形成分段拉挤形状的系统和方法，其中连续长度的纤维增强材料用基质材料浸渍，然后通过固化浸渍刚性部分的基质材料并形成连续系列的交替的刚性段和柔性段，去除浸渍柔性部分的基质材料。

9. 发明申请

US20100269270A1 Preparation of a nanocomposite photoanode for dye-sensitized solar cells 审中-公开
标题翻译：制备用于染料敏化太阳能电池的纳米复合光电阳极
公开(公告)号：US20100269270A1
公开(公告)日：2010-10-28
申请号：US12458809
申请日：2009-07-23
申请人： Chen-Chi M. Ma , Chuan-Yu Yen , Yu-Feng Lin , Shu-Hang Liao
发明人： Chen-Chi M. Ma , Chuan-Yu Yen , Yu-Feng Lin , Shu-Hang Liao
IPC分类号： D06P5/00
CPC分类号： H01G9/2031 , H01G9/2059 , Y02E10/542
摘要： A process for preparing a photoanode of dye-sensitized solar cells (DSSCs) is disclosed, which contains nano TiO2 and functionalized carbon nanomateiral. The process includes reacting a dispersion of functionalized carbon nanomateiral and a TiO2 precursor in a liquid organic medium under sol-gel conditions to form a carbon nanomaterial/nano TiO2 composite colloidal solution; mixing with an aqueous polymer solution, and forming a paste suitable for coating by concentrating the resulting mixture; coating the paste on a conductive glass substrate and calcining the coated layer at 300-520° C. in air for 10-60 minutes to obtain a conductive glass plate having a coating of nanocomposite, which can be used to prepare a photoanode of DSSCs by immersing in a dye solution to adsorb a dye thereon.
摘要翻译：公开了一种制备染料敏化太阳能电池（DSSC）的光电阳极的方法，其包含纳米TiO 2和官能化的碳纳米材料。该方法包括在溶胶 - 凝胶条件下使官能化的碳纳米材料和TiO2前体的分散体在液体有机介质中反应形成碳纳米材料/纳米TiO2复合胶体溶液; 与聚合物水溶液混合，并通过浓缩所得混合物形成适于涂覆的浆料; 将该糊状物涂布在导电性玻璃基板上，在空气中在300〜520℃下煅烧涂布层10〜60分钟，得到具有纳米复合材料的导电性玻璃板，其可用于制备DSSC的光电阳极浸渍在染料溶液中以吸附染料。

10. 发明授权

US5587034A Process for pultruding fiber reinforced furan composites 失效
标题翻译：拉拔纤维增强呋喃复合材料的工艺
公开(公告)号：US5587034A
公开(公告)日：1996-12-24
申请号：US965864
申请日：1992-10-23
申请人： Chen-Chi M. Ma
发明人： Chen-Chi M. Ma
IPC分类号： B29C70/52 , B29K61/00 , B29K105/08 , D01D5/08 , D01D5/084
CPC分类号： B29C70/521 , B29K2086/00
摘要： The present invention relates to a pultrusion process for preparing fiber reinforced furan resin composites by drawing a plurality of continuous filaments through an impregnating bath of liquid furan to wet-out the filaments with the resin and a squeeze orifice for removal of excess resin and air, and continuously pulling the resin-impregnated filament through a pultrusion die to heat and cure the resin. The liquid furan resin contains a furfuryl alcohol prepolymer and a minor portion of an acid catalyst, and is maintained at a temperature of 15.degree.-35.degree. C. and has a viscosity of 500-3000 cps during the impregnating step. A postcuring treatment may be optionally employed to the pultruded fiber reinforced furan resin composites for improving their mechanical properties, which includes heating the pultruded composites at a temperature of 100.degree.-220.degree. C. for a period of 1-18 hours. Adding 1-15 wt % of mineral fillers may also improve the mechanical properties of the pultruded composites.
摘要翻译：本发明涉及一种用于制备纤维增强呋喃树脂复合材料的拉挤成型方法，该方法通过用液体呋喃浸渍浴拉出多条连续长丝，用树脂润湿长丝，以及用于除去多余树脂和空气的挤压孔，并且通过拉挤模具连续地牵拉树脂浸渍的丝来加热和固化树脂。液体呋喃树脂含有糠醇预聚物和少部分酸催化剂，并且在浸渍步骤中保持在15-35℃的温度下，粘度为500-3000cps。可以任选地对拉挤成纤维增强呋喃树脂复合材料进行后固化处理以改善其机械性能，其包括在100-220℃的温度下加热拉挤成型复合材料1-18小时。添加1-15重量％的矿物填料还可以改善拉挤成型复合材料的机械性能。

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