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1. 发明申请

US20070265162A1 CARBON NANOSTRUCTURES MANUFACTURED FROM CATALYTIC TEMPLATING NANOPARTICLES 失效
标题翻译：由催化态纳米粒子制备的碳纳米管
公开(公告)号：US20070265162A1
公开(公告)日：2007-11-15
申请号：US11539042
申请日：2006-10-05
申请人： Cheng Zhang , Martin Fransson , Changkun Liu , Bing Zhou
发明人： Cheng Zhang , Martin Fransson , Changkun Liu , Bing Zhou
IPC分类号： D01F9/12 , B01J23/02
CPC分类号： H01M4/96 , B01J21/18 , B01J21/185 , B01J23/40 , B01J23/74 , B01J37/084 , B82Y30/00 , C01B32/05 , H01M4/9083
摘要： Methods for manufacturing carbon nanostructures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.
摘要翻译：制造碳纳米结构的方法包括：1）使用多个分散剂分子形成多个催化模板颗粒; 2）通过在多个模板纳米颗粒的存在下聚合碳前体形成中间碳纳米结构; 3）碳化中间碳纳米结构以形成复合纳米结构; 和4）从复合纳米结构中去除模板纳米颗粒以产生碳纳米结构。碳纳米结构非常适合用作催化剂载体。碳纳米结构表现出高的表面积，高孔隙率和高石墨化。根据本发明的碳纳米结构可用作更昂贵且可能更脆弱的碳纳米管的替代物。

2. 发明申请

US20100125035A1 CARBON NANOSTRUCTURES MANUFACTURED FROM CATALYTIC TEMPLATING NANOPARTICLES 审中-公开
标题翻译：由催化态纳米粒子制备的碳纳米管
公开(公告)号：US20100125035A1
公开(公告)日：2010-05-20
申请号：US12693915
申请日：2010-01-26
申请人： Cheng Zhang , Martin Fransson , Changkun Liu , Bing Zhou
发明人： Cheng Zhang , Martin Fransson , Changkun Liu , Bing Zhou
IPC分类号： C01B31/04 , B01J21/18
CPC分类号： H01M4/96 , B01J21/18 , B01J21/185 , B01J23/40 , B01J23/74 , B01J37/084 , B82Y30/00 , C01B32/05 , H01M4/9083
摘要： Methods for manufacturing carbon nanostructures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.
摘要翻译：制造碳纳米结构的方法包括：1）使用多个分散剂分子形成多个催化模板颗粒; 2）通过在多个模板纳米颗粒的存在下聚合碳前体形成中间碳纳米结构; 3）碳化中间碳纳米结构以形成复合纳米结构; 和4）从复合纳米结构中去除模板纳米颗粒以产生碳纳米结构。碳纳米结构非常适合用作催化剂载体。碳纳米结构表现出高的表面积，高孔隙率和高石墨化。根据本发明的碳纳米结构可用作更昂贵且可能更脆弱的碳纳米管的替代物。

3. 发明授权

US07718155B2 Carbon nanostructures manufactured from catalytic templating nanoparticles 失效
标题翻译：由催化模板纳米颗粒制成的碳纳米结构
公开(公告)号：US07718155B2
公开(公告)日：2010-05-18
申请号：US11539042
申请日：2006-10-05
申请人： Cheng Zhang , Martin Fransson , Changkun Liu , Bing Zhou
发明人： Cheng Zhang , Martin Fransson , Changkun Liu , Bing Zhou
IPC分类号： C01B31/00 , C01B31/04 , C09C1/44 , C09C1/46 , B01J21/18
CPC分类号： H01M4/96 , B01J21/18 , B01J21/185 , B01J23/40 , B01J23/74 , B01J37/084 , B82Y30/00 , C01B32/05 , H01M4/9083
摘要： Methods for manufacturing carbon nanostructures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.
摘要翻译：制造碳纳米结构的方法包括：1）使用多个分散剂分子形成多个催化模板颗粒; 2）通过在多个模板纳米颗粒的存在下聚合碳前体形成中间碳纳米结构; 3）碳化中间碳纳米结构以形成复合纳米结构; 和4）从复合纳米结构中去除模板纳米颗粒以产生碳纳米结构。碳纳米结构非常适合用作催化剂载体。碳纳米结构表现出高的表面积，高孔隙率和高石墨化。根据本发明的碳纳米结构可用作更昂贵且可能更脆弱的碳纳米管的替代物。

4. 发明申请

US20100311869A1 POLYMERIC MATERIALS INCORPORATING CARBON NANOSTRUCTURES AND METHODS OF MAKING SAME 审中-公开
标题翻译：合成碳纳米管的聚合材料及其制备方法
公开(公告)号：US20100311869A1
公开(公告)日：2010-12-09
申请号：US12849959
申请日：2010-08-04
申请人： Bing Zhou , Cheng Zhang , Martin Fransson , Raymond B. Balée
发明人： Bing Zhou , Cheng Zhang , Martin Fransson , Raymond B. Balée
IPC分类号： C08K7/24
CPC分类号： H01B1/24 , Y10S977/734 , Y10S977/735 , Y10S977/753 , Y10S977/773 , Y10S977/775 , Y10S977/778 , Y10S977/78 , Y10S977/783 , Y10S977/784 , Y10S977/788
摘要： The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.
摘要翻译：本发明涉及将碳纳米球结合到聚合材料中的新型复合材料。聚合物材料可以是与石墨材料相容的任何聚合物或可聚合材料。碳纳米球是中空的石墨纳米颗粒。碳纳米球可以使用模板催化纳米颗粒由碳前体制造。碳纳米球的独特尺寸，形状和电学特性为纳入这些纳米材料的复合材料赋予了有利的特性。

5. 发明申请

US20110095238A1 POLYMERIC MATERIALS INCORPORATING CARBON NANOMATERIALS 审中-公开
标题翻译：合成碳纳米管的聚合材料
公开(公告)号：US20110095238A1
公开(公告)日：2011-04-28
申请号：US12985561
申请日：2011-01-06
申请人： Bing Zhou , Cheng Zhang , Martin Fransson , Raymond B. Balée
发明人： Bing Zhou , Cheng Zhang , Martin Fransson , Raymond B. Balée
IPC分类号： H01B1/04 , C08K3/04 , C08K3/10 , C08K3/34 , C08K3/26 , C08K3/22 , C08K3/30 , C09K19/52 , B82Y30/00
CPC分类号： H01B1/24 , Y10S977/734 , Y10S977/735 , Y10S977/753 , Y10S977/773 , Y10S977/775 , Y10S977/778 , Y10S977/78 , Y10S977/783 , Y10S977/784 , Y10S977/788
摘要： The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.
摘要翻译：本发明涉及将碳纳米球结合到聚合材料中的新型复合材料。聚合物材料可以是与石墨材料相容的任何聚合物或可聚合材料。碳纳米球是中空的石墨纳米颗粒。碳纳米球可以使用模板催化纳米颗粒由碳前体制造。碳纳米球的独特尺寸，形状和电学特性为纳入这些纳米材料的复合材料赋予了有利的特性。

6. 发明授权

US07718156B2 Method for manufacturing carbon nanostructures having minimal surface functional groups 失效
标题翻译：具有最小表面官能团的碳纳米结构的制造方法
公开(公告)号：US07718156B2
公开(公告)日：2010-05-18
申请号：US11614011
申请日：2006-12-20
申请人： Cheng Zhang , Martin Fransson , Bing Zhou
发明人： Cheng Zhang , Martin Fransson , Bing Zhou
IPC分类号： C01B31/00 , C01B31/04 , C09C1/44 , C09C1/46 , B01J21/18
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/18 , C01B32/20 , C01P2002/72 , C01P2002/82 , C01P2004/03 , C01P2004/04 , C01P2004/32 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C09C1/44
摘要： Carbon nanostructures are formed from a carbon precursor and catalytic templating nanoparticles. Methods for manufacturing carbon nanostructures generally include (1) forming a precursor mixture that includes a carbon precursor and a plurality of catalytic templating particles, (2) carbonizing the precursor mixture to form an intermediate carbon material including carbon nanostructures, amorphous carbon, and catalytic metal, (3) purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally at least a portion of the catalytic metal, and (4) heat treating the purified intermediate carbon material and/or treating the purified intermediate carbon material with a base to remove functional groups on the surface thereof. The removal of functional groups increases the graphitic content of the carbon nanomaterial and decreases its hydrophilicity.
摘要翻译：碳纳米结构由碳前体和催化模板纳米颗粒形成。制造碳纳米结构的方法通常包括（1）形成包含碳前体和多个催化模板颗粒的前体混合物，（2）将前体混合物碳化以形成包括碳纳米结构，无定形碳和催化金属的中间碳材料（3）通过除去至少一部分无定形碳和任选的至少一部分催化金属来纯化中间碳材料，和（4）对纯化的中间碳材料进行热处理和/或处理纯化的中间碳材料具有用于除去其表面上的官能团的碱。官能团的去除增加了碳纳米材料的石墨含量，降低了其亲水性。

7. 发明申请

US20080152576A1 METHOD FOR MANUFACTURING CARBON NANOSTRUCTURES HAVING MINIMAL SURFACE FUNCTIONAL GROUPS 失效
标题翻译：制造具有最小表面功能组的碳纳米结构的方法
公开(公告)号：US20080152576A1
公开(公告)日：2008-06-26
申请号：US11614011
申请日：2006-12-20
申请人： Cheng Zhang , Martin Fransson , Bing Zhou
发明人： Cheng Zhang , Martin Fransson , Bing Zhou
IPC分类号： C09C1/44 , C01B31/04
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/18 , C01B32/20 , C01P2002/72 , C01P2002/82 , C01P2004/03 , C01P2004/04 , C01P2004/32 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C09C1/44
摘要： Carbon nanostructures are formed from a carbon precursor and catalytic templating nanoparticles. Methods for manufacturing carbon nanostructures generally include (1) forming a precursor mixture that includes a carbon precursor and a plurality of catalytic templating particles, (2) carbonizing the precursor mixture to form an intermediate carbon material including carbon nanostructures, amorphous carbon, and catalytic metal, (3) purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally at least a portion of the catalytic metal, and (4) heat treating the purified intermediate carbon material and/or treating the purified intermediate carbon material with a base to remove functional groups on the surface thereof. The removal of functional groups increases the graphitic content of the carbon nanomaterial and decreases its; hydrophilicity.
摘要翻译：碳纳米结构由碳前体和催化模板纳米颗粒形成。制造碳纳米结构的方法通常包括（1）形成包含碳前体和多个催化模板颗粒的前体混合物，（2）将前体混合物碳化以形成包括碳纳米结构，无定形碳和催化金属的中间碳材料（3）通过除去至少一部分无定形碳和任选的至少一部分催化金属来纯化中间碳材料，和（4）对纯化的中间碳材料进行热处理和/或处理纯化的中间碳材料具有用于除去其表面上的官能团的碱。官能团的去除增加了碳纳米材料的石墨含量，降低了其碳纳米材料的石墨含量。亲水性。

8. 发明授权

US07935276B2 Polymeric materials incorporating carbon nanostructures 失效
标题翻译：掺入碳纳米结构的聚合材料
公开(公告)号：US07935276B2
公开(公告)日：2011-05-03
申请号：US11614006
申请日：2006-12-20
申请人： Bing Zhou , Cheng Zhang , Martin Fransson , Raymond B. Balée
发明人： Bing Zhou , Cheng Zhang , Martin Fransson , Raymond B. Balée
IPC分类号： H01B1/06
CPC分类号： H01B1/24 , Y10S977/734 , Y10S977/735 , Y10S977/753 , Y10S977/773 , Y10S977/775 , Y10S977/778 , Y10S977/78 , Y10S977/783 , Y10S977/784 , Y10S977/788
摘要： The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.
摘要翻译：本发明涉及将碳纳米球结合到聚合材料中的新型复合材料。聚合物材料可以是与石墨材料相容的任何聚合物或可聚合材料。碳纳米球是中空的石墨纳米颗粒。碳纳米球可以使用模板催化纳米颗粒由碳前体制造。碳纳米球的独特尺寸，形状和电学特性为纳入这些纳米材料的复合材料赋予了有利的特性。

9. 发明授权

US08318122B2 Preparation of a carbon nanomaterial using a reverse microemulsion 失效
标题翻译：使用反相微乳液制备碳纳米材料
公开(公告)号：US08318122B2
公开(公告)日：2012-11-27
申请号：US12248993
申请日：2008-10-10
申请人： Cheng Zhang , Bing Zhou
发明人： Cheng Zhang , Bing Zhou
IPC分类号： C01B31/02 , B82B3/00
CPC分类号： B82Y30/00 , C01B32/05
摘要： Powdered, amorphous carbon nanomaterials are formed from a carbon precursor in reverse microemulsion that includes organic solvent, surfactant and water. Methods for manufacturing amorphous, powdered carbon nanomaterials generally include steps of (1) forming a reverse microemulsion including at least one non-polar solvent, at least one surfactant, and at least one polar solvent, (2) adding at least one carbon precursor substance to the reverse microemulsion, (3) reacting the at least one carbon precursor substance so as to form an intermediate carbon nanomaterial, (4) separating the intermediate amorphous carbon nanomaterial from the reverse microemulsion, and (5) heating the intermediate amorphous carbon nanomaterial for a period of time so as to yield an amorphous, powdered carbon nanomaterial. Amorphous, powdered carbon nanomaterials manufactured according to the present disclosure typically have a surface area of at least 500 m2/g, a graphitic content of at least 25%, and a conductivity of at least 150 S/m.
摘要翻译：粉末状无定形碳纳米材料由反相微乳液中的碳前体形成，其包括有机溶剂，表面活性剂和水。制造无定形粉末状碳纳米材料的方法通常包括以下步骤：（1）形成包含至少一种非极性溶剂，至少一种表面活性剂和至少一种极性溶剂的反相微乳液，（2）加入至少一种碳前体物质（3）使至少一种碳前体物质反应以形成中间碳纳米材料，（4）将中间无定形碳纳米材料与反相微乳液分离，（5）将中间无定形碳纳米材料加热至一段时间以产生无定形的粉末状碳纳米材料。根据本公开制造的无定形粉末碳纳米材料通常具有至少500m 2 / g的表面积，至少25％的石墨含量和至少150S / m的电导率。

10. 发明授权

US07670588B2 Hydrogen storage using porous carbon nanospheres 失效
标题翻译：使用多孔碳纳米球储氢
公开(公告)号：US07670588B2
公开(公告)日：2010-03-02
申请号：US11850581
申请日：2007-09-05
申请人： Bing Zhou , Cheng Zhang
发明人： Bing Zhou , Cheng Zhang
IPC分类号： C01B3/00
CPC分类号： C01B3/0021 , B82Y30/00 , F17C11/005 , Y02E60/325 , Y10S420/90 , Y10S977/70 , Y10S977/84 , Y10T29/49826 , Y10T428/2991
摘要： Hydrogen is stored by adsorbing the hydrogen to a carbon nanomaterial that includes carbon nanospheres. The carbon nanospheres are multi-walled, hollow carbon nanostructures with a maximum diameter in a range from about 10 nm to about 200 nm. The nanospheres have an irregular outer surface and an aspect ratio of less than 3:1. The carbon nanospheres can store hydrogen in quantities of at least 1.0% by weight.
摘要翻译：通过将氢吸附到包括碳纳米球的碳纳米材料上来储存氢。碳纳米球是具有最大直径在约10nm至约200nm范围内的多壁中空碳纳米结构。纳米球具有不规则的外表面和小于3:1的纵横比。碳纳米球可以以至少1.0重量％的量存储氢。

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