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1. 发明授权

US06221934B1 Aqueous dispersions of epoxy resins 失效
标题翻译：环氧树脂的水性分散体
公开(公告)号：US06221934B1
公开(公告)日：2001-04-24
申请号：US09116923
申请日：1998-07-17
申请人： Charles J. Stark , Jimmy D. Elmore , Gayle Edward Back , Pen-Chung Wang , Ernest Charles Galgoci, Jr.
发明人： Charles J. Stark , Jimmy D. Elmore , Gayle Edward Back , Pen-Chung Wang , Ernest Charles Galgoci, Jr.
IPC分类号： C08K320
CPC分类号： C08J3/03 , C08J2363/00 , C08L63/00 , C08L2666/22
摘要： Stable aqueous emulsions of epoxy resins are provided using an epoxy-functional surfactant prepared by reacting an amidoamine having the formula: wherein R1 is an alkyl, aryl, or arylalkyl group or mixtures thereof having 1 to 15 carbon atoms, R2 is aliphatic, cycloaliphatic, or aromatic group having 2 to 18 carbon atoms optionally containing non-reactive oxygen or at most all average of 4 secondary and/or tertiary nitrogen atoms per structure in the backbone, X and Y are independently a hydrogen, methyl or ethyl group with the provision that if X is methyl or ethyl, Y is hydrogen or if Y is methyl or ethyl, X is hydrogen, and n+m+o is a real number from 40 to 400, and n+o is a real number in an amount effective to provide resin emulsification, and the ratio of (I) to (II) by weight. is in the range of 100:0 to 0:100, the ratio of (I) to (III) by weight in the range of 100:0 to 0:100, and the ratio of (II) to (III) by weight in the range of 100:0 to 0:100, and at least one epoxy resin having a functionality of from greater than 0.8 epoxide group per molecule in an amine to epoxy equivalent ratio of at least 1:2.
摘要翻译：使用环氧官能表面活性剂提供稳定的环氧树脂水性乳液，该表面活性剂通过使具有下式的酰氨基胺反应制备：其中R1是烷基，芳基或芳烷基或其具有1至15个碳原子的混合物，R2是脂族，脂环族，或任选地含有非活性氧的碳原子数为2〜18的芳族基团，或者骨架中每个结构最多具有4个仲和/或叔氮原子的平均值，X和Y独立地为氢，甲基或乙基，如果X是甲基或乙基，Y是氢或Y是甲基或乙基，X是氢，n + m + o是从40到400的实数，n + o是有效量的实数提供树脂乳化，以及（I）与（II）的重量比。在100:0至0:100的范围内，（I）至（III）的重量比在100:0至0:100的范围内，（II）与（III）的重量比在100:0至0:100的范围内，以及至少一种具有至少1：2的胺/环氧当量比的每分子具有大于0.8个环氧基的官能度的环氧树脂。

2. 发明授权

US06359037B1 Polyamine/epoxy-functional amidoamine product with epoxy resin 有权
标题翻译：聚胺/环氧官能的酰胺胺产品与环氧树脂
公开(公告)号：US06359037B1
公开(公告)日：2002-03-19
申请号：US09635909
申请日：2000-08-10
申请人： Charles J. Stark , Gayle Edward Back , Jimmy D. Elmore , Kalyan Ghosh , Pen-Chung Wang , Kailash Dangayach
发明人： Charles J. Stark , Gayle Edward Back , Jimmy D. Elmore , Kalyan Ghosh , Pen-Chung Wang , Kailash Dangayach
IPC分类号： C08G5914
CPC分类号： C08G59/184
摘要： An aqueous system comprises at least one epoxy resin and a reaction product with an amine equivalent weight of at least 50 prepared by the reaction of an (A) epoxy-functional amidoamine derived from at least one epoxy resin and an amidoamine obtained via the reaction of an acid-terminated polyalkylene glycol and a diamine in an active hydrogen:epoxy groups ratio of from 1:15 to 1:350, with (B) at least one polyamine in an active amine hydrogen:epoxy groups equivalent ratio of from 2:1 to 30:1, and, optionally (C) a monoepoxide in a remaining active amine hydrogen:epoxy groups equivalent ratio of from 5:1 to 20:1.
摘要翻译：水性体系包含至少一种环氧树脂和胺当量重量至少为50的反应产物，该反应产物是由衍生自至少一种环氧树脂的（A）环氧官能酰胺基胺和通过活性氢：环氧基团比例为1:15至1:350的酸封端的聚亚烷基二醇和二胺，（B）活性胺氢中的至少一种多胺：环氧基当量比为2：1 至30：1，和任选地（C）单环氧化物中剩余的活性胺氢：环氧基当量比为5：1至20：1。

3. 发明授权

US06277928B1 Epoxy-functional amidoamine reacted with excess polyamine and monoepoxy as epoxy curative 失效
标题翻译：环氧官能的酰氨基胺与过量的多胺和单环氧基作为环氧固化剂反应
公开(公告)号：US06277928B1
公开(公告)日：2001-08-21
申请号：US09095079
申请日：1998-06-10
申请人： Charles J. Stark , by Ann E. Stark, adminstrator , Gayle Edward Back , Jimmy D. Elmore , Kalyan Ghosh , Pen-Chung Wang , Kailash Dangayach
发明人： Charles J. Stark , by Ann E. Stark, adminstrator , Gayle Edward Back , Jimmy D. Elmore , Kalyan Ghosh , Pen-Chung Wang , Kailash Dangayach
IPC分类号： C08G5914
CPC分类号： C08G59/184
摘要： A water-dispersible curing agent for epoxy resins is prepared by the reaction of (a) an epoxy-functional compound obtained from the reaction of at least one epoxy resin and an amidoamine derived from the reaction of an acid-terminated polyalkylene glycol and a diamine in an active amine hydrogen:epoxy groups ratio of from 1:15 to 1:350, (b) at least one polyamine in an active amine hydrogen:epoxy groups ratio of from 2:1 to 30:1 which yields an amine-terminated product having an amine equivalent weight of at least 50, and, optionally, (c) a monoepoxy in a remaining active amine hydrogen:epoxy groups ratio of from 5:1 to 20:1.
摘要翻译：用于环氧树脂的水分散性固化剂通过（a）由至少一种环氧树脂的反应获得的环氧官能化合物和源自酸封端的聚亚烷基二醇与二胺的反应的酰氨基胺的反应来制备活性胺氢：环氧基团比例为1:15至1:350，（b）活性胺氢中至少一种多胺：环氧基团比例为2：1至30：1，其产生胺封端具有至少50的胺当量的产物，和任选地（c）剩余活性胺氢环氧基团比例为5:1至20:1的单环氧基。

4. 发明授权

US5262496A Hydroxyl functional derivatives of epoxidized diene polymers and process for making them 失效
标题翻译：环氧化二烯聚合物的羟基官能衍生物及其制备方法
公开(公告)号：US5262496A
公开(公告)日：1993-11-16
申请号：US049691
申请日：1993-04-16
申请人： Robert C. Bening , James R. Erickson , Charles J. Stark , David J. St. Clair
发明人： Robert C. Bening , James R. Erickson , Charles J. Stark , David J. St. Clair
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
摘要翻译：在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成，聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。含有0.01至15Meq / g羟基聚合物的二烯聚合物，优选包括高度反应性的伯羟基，并且由选自以下的式（Ⅹ）或（IMA）（G）的醚 - 醇单元组成：由含有至多10个碳原子的烷基组成的组，一元和二元醇基团和碳酸酯基团; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。

5. 发明授权

US5602193A Aqueous dispersions of epoxy resins 失效
标题翻译：环氧树脂的水性分散体
公开(公告)号：US5602193A
公开(公告)日：1997-02-11
申请号：US551206
申请日：1995-10-31
申请人： Charles J. Stark
发明人： Charles J. Stark
IPC分类号： C08G59/12 , C08G59/22 , C08G59/38 , C08G65/325 , C08L63/00 , C08L71/02 , C08K3/20
CPC分类号： C08L63/00 , C08G59/12 , C08G59/226 , C08G59/38 , C08G65/325 , C08L71/02
摘要： A stable aqueous emulsions of epoxy resins are provided using an epoxy-functional polyether having the formula: ##STR1## wherein Q is A or B, R.sup.1 is independently a divalent hydrocarbon group, R.sup.2 is a divalent aliphatic group optionally containing ether or ester groups or together with R.sup.3 or R.sup.4 form a spiro ring optionally containing heteroatoms, and R.sup.3 and R.sup.4 are independently hydrogen or R.sup.3 or R.sup.4 together with R.sup.2 form a spiro ring optionally containing heteroatoms such as oxygen, X and Y are independently hydrogen, methyl or ethyl group with the provision that if X is methyl or ethyl, Y is hydrogen or if Y is methyl or ethyl, X is hydrogen and n+m+o is a positive real number from about 15 to 450, and where Q is B, n+o is a real number in an amount effective to provide emulsifying property.
摘要翻译：使用具有下式的环氧官能聚醚提供稳定的环氧树脂水乳液：（I）图像（IV）或图像（V）其中Q是A或B，R1独立地是二价烃基，R2是任选地含有醚或酯基的二价脂族基团或与R 3或R 4一起形成任选地含有杂原子的螺环，和 R3和R4独立地是氢或R3或R4与R2一起形成任选地含有杂原子如氧的螺环，X和Y独立地是氢，甲基或乙基，条件是如果X是甲基或乙基，则Y是氢或如果Y为甲基或乙基，则X为氢，n + m + o为约15〜450的正实数，Q为B时，n + o为有效提供乳化性能的实数。

6. 发明授权

US5021537A Polyacetoacetate-containing epoxy resin compositions 失效
标题翻译：含聚乙酰乙酸酯的环氧树脂组合物
公开(公告)号：US5021537A
公开(公告)日：1991-06-04
申请号：US515904
申请日：1990-04-27
申请人： Charles J. Stark , Rita D. Pietruszka
发明人： Charles J. Stark , Rita D. Pietruszka
IPC分类号： C08G59/40 , C09D163/00
CPC分类号： C08G59/4007 , C09D163/00
摘要： A coating composition is provided comprising an epoxy resin, a polyacetoacetate, a curing agent for the epoxy resin, and an optional organic solvent. The presence of the polyacetoacetate permits the preparation of a fast-drying high-solids coating formulation.

7. 发明授权

US4670504A Ionizable olefin based resinous tackifiers for latex 失效
标题翻译：用于胶乳的可离子化烯烃基树脂增粘剂
公开(公告)号：US4670504A
公开(公告)日：1987-06-02
申请号：US752736
申请日：1985-07-08
申请人： Carlos G. Cardenas , James M. Evans , Charles J. Stark , William J. Ehmann
发明人： Carlos G. Cardenas , James M. Evans , Charles J. Stark , William J. Ehmann
IPC分类号： C08F8/00 , C08L51/04
CPC分类号： C08F8/00
摘要： There is provided a tackifier composition especially suited for use with natural rubber latex and formed from an olefin resin, preferably a polymerized terpene hydrocarbon resin condensed with an unsaturated carboxylic acid or anhydride, optionally partially esterified with a C.sub.1 -C.sub.30 alcohol or phenol, and neutralized with a base, preferably a volatile base such as an amine, and then dispersed in an aqueous medium. The tackifier when added to a latex forms compositions useful particularly as pressure sensitive adhesives.
摘要翻译：提供了一种特别适用于天然橡胶胶乳并由烯烃树脂形成的增粘剂组合物，优选与不饱和羧酸或酸酐缩合的聚合萜烯烃树脂，任选地用C1-C30醇或苯酚部分酯化，并中和与碱，优选挥发性碱例如胺，然后分散在水性介质中。增粘剂当添加到胶乳中时，形成了特别用作压敏粘合剂的组合物。

8. 发明授权

US4344887A Method for epoxidizing olefins 失效
标题翻译：烯烃环氧化方法
公开(公告)号：US4344887A
公开(公告)日：1982-08-17
申请号：US263839
申请日：1981-05-15
申请人： Charles J. Stark
发明人： Charles J. Stark
IPC分类号： C07D301/12 , C07D303/04
CPC分类号： C07D303/04 , C07D301/12
摘要： A mixture of tetrachloroacetone and hydrogen peroxide has been found effective for epoxidizing olefinically unsaturated organic material dissolved in various aromatic or halogenated aliphatic organic solvents.
摘要翻译：已经发现四氯丙酮和过氧化氢的混合物对溶解在各种芳族或卤代脂族有机溶剂中的烯属不饱和有机材料的环氧化有效。

9. 发明授权

US5284901A Hydroxyl functional derivatives of epoxidized diene polymers and process for making them 失效
标题翻译：环氧化二烯聚合物的羟基官能衍生物及其制备方法
公开(公告)号：US5284901A
公开(公告)日：1994-02-08
申请号：US49687
申请日：1993-04-16
申请人： Robert C. Bening , James R. Erickson , Charles J. Stark , David J. St. Clair
发明人： Robert C. Bening , James R. Erickson , Charles J. Stark , David J. St. Clair
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
摘要翻译：在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成，聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。含有0.01〜15 Meq / g羟基聚合物的二烯聚合物，优选包括高反应性伯羟基，并且由式（*化学结构*）（F）或（*化学结构*）（ G）其中R选自含有至多10个碳原子的烷基，一元和二元醇基和碳酸酯基; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。

10. 发明授权

US5264480A Hydroxyl functional derivatives of epoxidized diene polymers and process for making them 失效
标题翻译：环氧化二烯聚合物的羟基官能衍生物及其制备方法
公开(公告)号：US5264480A
公开(公告)日：1993-11-23
申请号：US49682
申请日：1993-04-16
申请人： Robert C. Bening , James R. Erickson , Charles J. Stark , David J. St. Clair
发明人： Robert C. Bening , James R. Erickson , Charles J. Stark , David J. St. Clair
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08G18/6208
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.
摘要翻译：在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成，聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。含有0.01至15Meq / g羟基聚合物的二烯聚合物，优选包括高度反应性的伯羟基，并且由式（I）所示的醚 - 醇单元组成，其中R选自含有至多一个碳原子，一个羟基和二元醇基团和碳酸酯基团; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。

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