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1. 发明授权

US06267849B1 Method for the photocatalytic conversion of gas hydrates 失效
标题翻译：气体水合物的光催化转化方法
公开(公告)号：US06267849B1
公开(公告)日：2001-07-31
申请号：US09616689
申请日：2000-07-14
申请人： Charles E. Taylor , Richard P. Noceti , Bradley C. Bockrath
发明人： Charles E. Taylor , Richard P. Noceti , Bradley C. Bockrath
IPC分类号： C07C2900
CPC分类号： C07C29/48 , C07C31/04
摘要： A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0° C., and allows for the direct conversion of methane contained within the hydrate in situ.
摘要翻译：通过曝光将甲烷水合物转化成甲醇以及氢气的方法。该方法包括通过添加自由基引发剂的光转化甲烷水合物，并且可以被修饰以包括用光转化甲烷水合物，其中由合适的金属和电子转移剂掺杂的光催化剂产生甲醇和氢。本发明在低于0℃的温度下操作，并允许原位在水合物中直接转化甲烷。

2. 发明授权

US4769504A Process for converting light alkanes to higher hydrocarbons 失效
标题翻译：将轻质烷烃转化为高级烃的方法
公开(公告)号：US4769504A
公开(公告)日：1988-09-06
申请号：US45634
申请日：1987-03-04
申请人： Richard P. Noceti , Charles E. Taylor
发明人： Richard P. Noceti , Charles E. Taylor
IPC分类号： C07C1/26 , C07C17/154 , C07C2/42
CPC分类号： C07C1/26 , C07C17/154 , C07C2529/40 , Y10S585/901 , Y10S585/935
摘要： A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.
摘要翻译：公开了用于从低级烷烃，特别是甲烷生产富含芳香族的汽油沸程烃的方法。该过程分两个阶段进行。首先，烷烃与氧氯化氢催化剂如氯化铜与少量氯化钾和稀土氯化物一起与氧和氯化氢反应。这产生含有水和氯化烷烃的中间气体混合物。氯化烷烃与氢或金属促进形式的结晶硅铝酸盐催化剂接触，以生产具有高比例芳族化合物和少量轻烃（C 2 -C 4）的汽油范围烃。轻质烃可以再循环用于进一步处理氧化氢氯化催化剂。

3. 发明授权

US5720858A Method for the photocatalytic conversion of methane 失效
标题翻译：甲烷光催化转化方法
公开(公告)号：US5720858A
公开(公告)日：1998-02-24
申请号：US682498
申请日：1996-07-17
申请人： Richard P. Noceti , Charles E. Taylor , Joseph R. D'Este
发明人： Richard P. Noceti , Charles E. Taylor , Joseph R. D'Este
IPC分类号： C07C29/48 , C07F1/00 , C07B41/00 , C07C29/00
CPC分类号： C07C29/48
摘要： A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.
摘要翻译：提供了将甲烷转化成甲醇的方法，包括在催化剂和电子转移剂存在下使甲烷经受可见光。本发明的另一个实施方案提供了一种使甲烷和水反应生成甲醇和氢气的方法，包括制备含有甲烷，电子转移剂和光解催化剂的流体，并使所述流体在可见光下进行一段有效的时间。

4. 发明授权

US5139991A Oxyhydrochlorination catalyst 失效
标题翻译：氧化氢氯化催化剂
公开(公告)号：US5139991A
公开(公告)日：1992-08-18
申请号：US666972
申请日：1991-03-11
申请人： Charles E. Taylor , Richard P. Noceti
发明人： Charles E. Taylor , Richard P. Noceti
IPC分类号： B01J27/10 , B01J27/128 , B01J37/02 , C07C17/154 , C07C51/215
CPC分类号： C07C17/154 , B01J27/10 , B01J27/128 , B01J37/0244 , C07C51/215
摘要： An improved catalyst and method for the oxyhydrochlorination of methane is disclosed. The catalyst includes a pyrogenic porous support on which is layered as active material, cobalt chloride in major proportion, and minor proportions of an alkali metal chloride and of a rare earth chloride. On contact of the catalyst with a gas flow of methane, HCl and oxygen, more than 60% of the methane is converted and of that converted more than 40% occurs as monochloromethane. Advantageously, the monochloromethane can be used to produce gasoline boiling range hydrocarbons with the recycle of HCl for further reaction. This catalyst is also of value for the production of formic acid as are analogous catalysts with lead, silver or nickel chlorides substituted for the cobalt chloride.
摘要翻译：公开了一种用于甲烷氧化氢氯化的改进的催化剂和方法。催化剂包括热解多孔载体，其上以活性材料层叠氯化钴，主要成分为氯化钴，少量的碱金属氯化物和稀土氯化物。在催化剂与甲烷，HCl和氧气的气流接触时，甲烷的转化率超过60％，转化率高达40％，就像一氯甲烷一样。有利地，一氯甲烷可用于生产汽油沸程烃，再循环HCl进一步反应。该催化剂对于生产甲酸也是有价值的，就像使用铅，银或氯化镍代替氯化钴的类似催化剂一样。

5. 发明授权

US5019652A Catalysts and method 失效
标题翻译：催化剂和方法
公开(公告)号：US5019652A
公开(公告)日：1991-05-28
申请号：US516611
申请日：1990-04-30
申请人： Charles E. Taylor , Richard P. Noceti
发明人： Charles E. Taylor , Richard P. Noceti
IPC分类号： B01J27/10 , B01J27/128 , B01J37/02 , C07C17/154 , C07C51/215
CPC分类号： C07C17/154 , B01J27/10 , B01J27/128 , B01J37/0244 , C07C51/215
摘要： An improved catlayst and method for the oxyhydrochlorination of methane is disclosed. The catalyst includes a pyrogenic porous support on which is layered as active material, cobalt chloride in major proportion, and minor proportions of an alkali metal chloride and of a rare earth chloride. On contact of the catalyst with a gas flow of methane, HC1 and oxygen, more than 60% of the methane is converted and of that converted more than 40% occurs as monochloromethane. Advantageously, the monochloromethane can be used to produce gasoline boiling range hydrocarbons with the recycle of HCl for further reaction. This catalyst is also of value for the production of formic acid as are analogous catalysts with lead, silver or nickel chlorides substituted for the cobalt chloride.
摘要翻译：公开了一种用于甲烷氧化氢氯化的改进的涂料和方法。催化剂包括热解多孔载体，其上以活性材料层叠氯化钴，主要成分为氯化钴，少量的碱金属氯化物和稀土氯化物。当催化剂与甲烷，HC1和氧气的气流接触时，甲烷的转化率超过60％，转化率高达40％，就像一氯甲烷一样。有利地，一氯甲烷可用于生产汽油沸程烃，再循环HCl进一步反应。该催化剂对于生产甲酸也是有价值的，就像使用铅，银或氯化镍代替氯化钴的类似催化剂一样。

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