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    • 2. 发明申请
    • Mesoporous carbon composite, method of preparing the same, and fuel cell using the mesoporous carbon composite
    • 介孔碳复合材料,其制备方法和使用介孔碳复合材料的燃料电池
    • US20070042268A1
    • 2007-02-22
    • US11443165
    • 2006-05-31
    • Chan-ho PakYeong-suk ChoiHyuk ChangSang-hoon Joo
    • Chan-ho PakYeong-suk ChoiHyuk ChangSang-hoon Joo
    • H01M4/60H01M4/62B01J31/00B01J21/18
    • B01J21/18B01J23/42B01J29/0308B01J35/10B01J35/1023B01J35/1047B01J35/1061B01J37/0018B01J37/084H01M4/90H01M4/9083H01M4/926H01M8/08H01M8/086H01M8/10H01M8/1007H01M8/1011Y02E60/523Y02P70/56
    • A mesoporous carbon composite includes mesoporous carbon having mesopores; a conductive polymer coated on only an outer surface of the mesoporous carbon; and an organic electrolyte comprising a lithium salt and an organic solvent. The mesoporous carbon composite may be prepared by impregnating an ordered mesoporous silica (OMS) with a carbon precursor mixture comprising a carbon precursor, an acid, and a solvent; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; mixing the OMS-carbon composite with a monomer that forms a conductive polymer and a solvent to provide a surface of the OMS-carbon composite with the monomer that forms a conductive polymer; polymerizing the monomer to obtain a conductive polymer-coated OMS-carbon composite; removing the OMS from the conductive polymer-coated OMS-carbon composite to obtain a conductive polymer-coated mesoporous carbon; and doping the conductive polymer-coated mesoporous carbon with an organic electrolyte comprising a lithium salt and an organic solvent to form the mesoporous carbon composite. A supported catalyst contains the mesoporous carbon composite, and a fuel cell uses an electrode containing the mesoporous carbon composite.
    • 介孔碳复合材料包括具有中孔的中孔碳; 只涂覆在介孔碳外表面上的导电聚合物; 以及包含锂盐和有机溶剂的有机电解质。 介孔碳复合材料可以通过用含碳前体,酸和溶剂的碳前体混合物浸渍有序介孔二氧化硅(OMS)来制备; 对浸渍的OMS进行热处理和碳化以形成OMS-碳复合材料; 将OMS-碳复合物与形成导电聚合物和溶剂的单体混合以提供OMS-碳复合材料与形成导电聚合物的单体的表面; 聚合单体以获得导电聚合物涂覆的OMS-碳复合材料; 从导电聚合物涂覆的OMS-碳复合材料中除去OMS以获得导电聚合物涂覆的介孔碳; 并用包含锂盐和有机溶剂的有机电解质掺杂导电聚合物涂覆的介孔碳以形成中孔碳复合物。 载体催化剂含有介孔碳复合材料,燃料电池使用含有介孔碳复合材料的电极。
    • 4. 发明申请
    • Supported catalyst, method of preparing the same, and fuel cell using the same
    • 负载催化剂,其制备方法和使用其的燃料电池
    • US20070270305A1
    • 2007-11-22
    • US11708600
    • 2007-02-21
    • Chan-ho PakDae-jong YooSang-hoon JooHyuk ChangSeol-ah Lee
    • Chan-ho PakDae-jong YooSang-hoon JooHyuk ChangSeol-ah Lee
    • B01J31/00
    • H01M4/926H01M4/8657H01M4/8814H01M4/885H01M4/92H01M4/921H01M8/1007H01M8/1011Y02E60/523Y02P70/56
    • A method of preparing a supported catalyst, the method comprising mixing a first catalytic metal precursor and a first solvent to obtain a first catalytic metal precursor mixture; mixing a carbon support for catalyst and the first catalytic metal precursor mixture, and drying the mixture to obtain a primary supported catalyst precursor; subjecting the primary supported catalyst precursor to a hydrogen reduction heat treatment, to obtain a primary supported catalyst; mixing the primary supported catalyst and a polyhydric alcohol to obtain a primary supported catalyst mixture; mixing a second catalytic metal precursor and a second solvent to obtain a second catalytic metal precursor mixture; mixing the primary supported catalyst mixture and the second catalytic metal precursor mixture to obtain a secondary supported catalyst precursor mixture; and adjusting the pH of the secondary supported catalyst precursor mixture, and then heating the secondary supported catalyst precursor mixture to obtain a supported catalyst, a supported catalyst prepared by the method, an electrode comprising the supported catalyst, and a fuel cell including the electrode are provided. A supported catalyst having a desired amount of loaded catalytic metal particles can be obtained by preparing a primary supported catalyst containing catalytic metal particles that are obtained by a primary gas phase reduction reaction of a portion of the final loading amount of catalytic metal, and reducing the remaining portion of the catalytic metal by a secondary liquid phase reduction reaction. The supported catalyst contains catalytic metal particles having a very small average particle size, which are uniformly distributed on a carbon support at a high concentration, and thus exhibits maximal catalyst activity. A fuel cell produced using the supported catalyst has improved efficiency.
    • 一种制备负载型催化剂的方法,所述方法包括混合第一催化金属前体和第一溶剂以获得第一催化金属前体混合物; 混合催化剂用碳载体和第一催化金属前体混合物,干燥混合物得到主要负载型催化剂前体; 对初级负载催化剂前体进行氢还原热处理,得到主要负载型催化剂; 将主要负载型催化剂和多元醇混合,得到主要负载型催化剂混合物; 混合第二催化金属前体和第二溶剂以获得第二催化金属前体混合物; 将主要负载的催化剂混合物和第二催化金属前体混合物混合,得到二次负载催化剂前体混合物; 调节二次负载型催化剂前体混合物的pH,然后加热二次负载型催化剂前体混合物,得到负载型催化剂,通过该方法制备的负载催化剂,包含负载型催化剂的电极和包含该电极的燃料电池 提供。 具有所需量的负载的催化金属颗粒的负载型催化剂可以通过制备含有催化金属颗粒的主负载催化剂获得,所述催化金属颗粒是通过催化金属的最终负载量的一部分一次气相还原反应获得的, 催化金属的剩余部分通过二次液相还原反应。 载体催化剂含有平均粒径非常小的催化金属颗粒,其以高浓度均匀分布在碳载体上,因此表现出最大的催化剂活性。 使用负载型催化剂制造的燃料电池具有提高的效率。
    • 8. 发明申请
    • Catalyst coated membrane, membrane electrode assembly containing the same, method of producing the same, and fuel cell including the membrane electrode assembly
    • 催化剂涂膜,含有其的膜电极组件,其制造方法和包括膜电极组件的燃料电池
    • US20070269699A1
    • 2007-11-22
    • US11708599
    • 2007-02-21
    • Chan-ho PakSeol-ah LeeHyuk ChangJi-rae KimDae-jong YooSang-hoon Joo
    • Chan-ho PakSeol-ah LeeHyuk ChangJi-rae KimDae-jong YooSang-hoon Joo
    • H01M8/10
    • H01M4/921H01M4/8657H01M4/8668H01M4/881H01M4/8814H01M4/8828H01M4/8875H01M4/8882H01M4/926H01M4/928
    • A catalyst coated membrane (CCM) comprising an anode catalyst layer having a first catalyst layer composed of a non-supported catalyst and a second catalyst layer composed of a supported catalyst, a cathode catalyst layer composed of a supported catalyst, and an electrolyte membrane interposed between the anode catalyst layer and a cathode catalyst layer, the first catalyst layer of the anode catalyst layer being disposed adjacent to the electrolyte membrane; a membrane electrode assembly (MEA) comprising the catalyst coated membrane; a method of preparing the membrane electrode assembly; and a fuel cell comprising the membrane electrode assembly, are provided. The CCM, which comprises a bilayered anode catalyst layer including the first catalyst layer composed of a non-supported catalyst and the second catalyst layer composed of a supported catalyst, exhibits reduced electrical resistance and interfacial resistance, and has increased catalyst availability. The use of the CCM and an MEA having the same results in a decrease in the interfacial resistance between the electrodes and the electrolyte membrane, a decrease in the amount of the catalyst used in the electrode catalyst layer, and a decrease in the thickness deviation in the electrode layers. The fuel cell employing the MEA exhibits maximal activity of the supported catalyst, and has improved cell characteristics such as output voltage, output density, efficiency, and the like.
    • 一种催化剂涂覆膜(CCM),其包括具有由非负载型催化剂构成的第一催化剂层和由负载型催化剂构成的第二催化剂层的阳极催化剂层,由负载型催化剂构成的阴极催化剂层和插入 在阳极催化剂层和阴极催化剂层之间,阳极催化剂层的第一催化剂层设置在电解质膜附近; 包含所述催化剂涂覆膜的膜电极组件(MEA) 一种制备膜电极组件的方法; 以及包括膜电极组件的燃料电池。 包含由非载体催化剂构成的第一催化剂层和由负载型催化剂构成的第二催化剂层的双层阳极催化剂层的CCM显示出降低的电阻和界面电阻,并且提高了催化剂的可利用性。 使用具有相同结果的CCM和MEA在电极和电解质膜之间的界面电阻降低,电极催化剂层中使用的催化剂量的减少以及厚度偏差的降低 电极层。 使用MEA的燃料电池显示出负载型催化剂的最大活性,并且具有改善的电池特性,例如输出电压,输出密度,效率等。