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1. 发明授权

US5538929A Phosphorus-treated activated carbon composition 失效
标题翻译：磷处理的活性炭组成
公开(公告)号：US5538929A
公开(公告)日：1996-07-23
申请号：US287825
申请日：1994-08-09
申请人： Chakka Sudhakar , Robert K. Beckler , James R. Miller , Mahendra S. Patel
发明人： Chakka Sudhakar , Robert K. Beckler , James R. Miller , Mahendra S. Patel
IPC分类号： B01J20/20 , B01J20/32 , B01J21/18 , B01J27/16
CPC分类号： B01J20/20 , B01J20/0259 , B01J20/28066 , B01J20/3007 , B01J20/3078 , B01J20/3204 , B01J20/3234 , B01J21/18 , B01J27/16 , B01J2220/485
摘要： Disclosed is a phosphorus treated activated carbon composition suitable for use as catalyst support, catalyst, and an adsorbent, which is produced by treating (e.g., by mixing or impregnating) an activated carbon material having a surface area greater than 100 m.sup.2 /g with a phosphorus-containing compound, drying, and heating to a temperature of from 450.degree. C. to about 1200.degree. C., wherein the resulting composition is characterized by a phosphorus compound combined with the carbon in the amount of from above 2.5% to about 10% phosphorus, based on the weight of the composition.
摘要翻译：公开了一种适合用作催化剂载体，催化剂和吸附剂的磷处理的活性炭组合物，其通过用表面积大于100m 2 / g的活性炭材料处理（例如，通过混合或浸渍）含磷化合物，干燥并加热至450℃至约1200℃的温度，其中所得组合物的特征在于与碳组合的磷化合物的含量高于2.5％至约10 ％磷，基于组合物的重量。

2. 发明授权

US5538930A Hydrotreating of cracked naphtha 失效
标题翻译：加氢处理裂化石脑油
公开(公告)号：US5538930A
公开(公告)日：1996-07-23
申请号：US407425
申请日：1995-03-17
申请人： Chakka Sudhakar , Gerald G. Sandford , Phillip L. Dahlstrom , Mahendra S. Patel , Edwin L. Patmore
发明人： Chakka Sudhakar , Gerald G. Sandford , Phillip L. Dahlstrom , Mahendra S. Patel , Edwin L. Patmore
IPC分类号： B01J23/85 , B01J23/887 , C10G45/08 , B01J21/18 , B01J23/02
CPC分类号： B01J23/85 , B01J23/8871 , B01J23/8872 , C10G45/08
摘要： A sulfided carbon support catalyst bearing (i) a non-noble Group VIII metal, (ii) a Group VI-B metal, and (iii) a metal of Group IA, II A, III-B, or the lanthanide Group of rare earths.
摘要翻译：一种硫化碳载体催化剂（i）非贵金属Ⅷ族金属，（ⅱ）ⅥB族金属和（ⅲ）IA，ⅡA，ⅢB族或镧系金属稀有金属地球。

3. 发明授权

US5472595A Process for hydrodearomatization of hydrocarbon oils using carbon supported metal sulfide catalysts promoted by phosphate 失效
标题翻译：使用由磷酸盐促进的碳负载型金属硫化物催化剂，加氢脱氢化烃油的方法
公开(公告)号：US5472595A
公开(公告)日：1995-12-05
申请号：US287738
申请日：1994-08-09
申请人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Mahendra S. Patel
发明人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Mahendra S. Patel
IPC分类号： B01J21/18 , B01J27/188 , C07B61/00 , C10G45/08 , C10G45/50 , C10G45/46
CPC分类号： B01J27/188 , B01J21/18 , C10G45/50
摘要： A process for treating a charge hydrocarbon oil containing undesired aromatic components, sulfur and nitrogen compounds, which comprisesmaintaining a bed of a sulfided catalyst comprising 0.1 to 15% by weight of nickel; and from 1 to 50% by weight of tungsten and 0.01 to 10% by weight of phosphorus, on an activated carbon support, andpassing a charge hydrocarbon feed in the presence of hydrogen into contact with said catalyst at hydrotreating conditions, thereby effecting hydrodearomatization, hydrodesulfurization and hydrodenitrogenation of said charge hydrocarbon feed containing undesired aromatic components, sulfur and nitrogen, and forming a product stream of hydrocarbon containing a lesser quantity of undesired aromatic components, sulfur and nitrogen; andrecovering said product stream of hydrocarbon containing a lesser quantity of undesired aromatic components, sulfur and nitrogen.
摘要翻译：一种处理含有不需要的芳族组分，硫和氮化合物的电荷烃油的方法，其包括保持包含0.1至15重量％镍的硫化催化剂床; 和1至50重量％的钨和0.01至10重量％的磷，在活性炭载体上，并使氢气存在下的电荷烃进料在加氢处理条件下与所述催化剂接触，从而进行加氢脱芳构化，所述含有不需要的芳族组分，硫和氮的加料烃进料的加氢脱硫和加氢脱氮，并形成含有较少量的不需要的芳族组分，硫和氮的烃的产物流; 并回收含有较少量的不需要的芳族组分，硫和氮的烃的产物流。

4. 发明授权

US5462651A Hydrodearomatization of hydrocarbon oils using novel "phosphorus treated carbon" supported metal sulfide catalysts 失效
标题翻译：使用新型“磷处理碳”载体金属硫化物催化剂对烃油进行氢化脱色
公开(公告)号：US5462651A
公开(公告)日：1995-10-31
申请号：US287979
申请日：1994-08-09
申请人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Mahendra S. Patel , Paul O. Fritz
发明人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Mahendra S. Patel , Paul O. Fritz
IPC分类号： B01J21/18 , B01J23/85 , B01J27/188 , C10G45/08 , C10G45/50 , C10G45/46
CPC分类号： B01J27/188 , B01J23/85 , C10G45/50
摘要： A process for simultaneous hydrodearomatization, hydrodesulfurization and hydrodenitrogenation of a charge hydrocarbon oil containing undesired aromatic components, sulfur and nitrogen compounds, which comprises:maintaining a bed of a sulfided metal catalyst comprising one or more metals of non-noble Group VIII, at least one metal selected from tungsten and molybdenum on a novel "phosphorus treated carbon" support, the "phosphorus treated carbon" support being comprised of phosphorus bound to the carbon surface predominantly as polyphosphate species characterized by peaks between -5 and -30 ppm in the solid-state magic angle spinning .sup.31 P nuclear magnetic resonance spectrum;passing a charge hydrocarbon feed in the presence of hydrogen into contact with said catalyst at hydrotreating conditions, thereby effecting hydrodearomatization, and simultaneously effecting hydrodesulfurization and hydrodenitrogenation.
摘要翻译：含有不需要的芳族组分，硫和氮化合物的电荷烃油同时加氢脱硫，加氢脱硫和加氢脱氮的方法，该方法包括：保持含有一种或多种非贵金属VIII族金属的硫化金属催化剂床，至少一种选自钨和钼的金属在新型“磷处理碳”载体上，“磷处理碳”载体由结合到碳表面的磷组成，主要作为聚磷酸盐物质，其特征在于固体 - 状态魔角31P核磁共振谱; 在加氢处理条件下使氢气存在下的带电烃进料与所述催化剂接触，从而进行加氢脱芳构化，同时进行加氢脱硫和加氢脱氮。

5. 发明授权

US5529968A Hydrodearomatization of hydrocarbon oils using novel "phophorus treated carbon" supported metal sulfide catalysts 失效
标题翻译：使用新型“phophorus处理碳”负载的金属硫化物催化剂对烃油进行氢化脱色
公开(公告)号：US5529968A
公开(公告)日：1996-06-25
申请号：US441897
申请日：1995-05-16
申请人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Mahendra S. Patel , Paul O. Fritz
发明人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Mahendra S. Patel , Paul O. Fritz
IPC分类号： B01J21/18 , B01J23/85 , B01J27/188 , C10G45/08 , C10G45/50
CPC分类号： B01J27/188 , B01J23/85 , C10G45/50
摘要： A process for simultaneous hydrodearomatization, hydrodesulfurization and hydrodenitrogenation of a charge hydrocarbon oil containing undesired aromatic components, sulfur and nitrogen compounds, which comprises:maintaining a bed of a sulfided metal catalyst comprising one or more metals of non-noble Group VIII, at least one metal selected from tungsten and molybdenum on a novel "phosphorus treated carbon" support, the "phosphorus treated carbon" support being comprised of phosphorus bound to the carbon surface predominantly as polyphosphate species characterized by peaks between -5 and -30 ppm in the solid-state magic angle spinning .sup.31 p nuclear magnetic resonance spectrum;passing a charge hydrocarbon feed in the presence of hydrogen into contact with said catalyst at hydrotreating conditions, thereby effecting hydrodearomatization, and simultaneously effecting hydrodesulfurization and hydrodenitrogenation.
摘要翻译：含有不需要的芳族组分，硫和氮化合物的电荷烃油同时加氢脱硫，加氢脱硫和加氢脱氮的方法，该方法包括：保持含有一种或多种非贵金属VIII族金属的硫化金属催化剂床，至少一种选自钨和钼的金属在新型“磷处理碳”载体上，“磷处理碳”载体由结合到碳表面的磷组成，主要作为聚磷酸盐物质，其特征在于固体 - 状态魔角旋转31p核磁共振谱; 在加氢处理条件下使氢气存在下的带电烃进料与所述催化剂接触，从而进行加氢脱芳构化，同时进行加氢脱硫和加氢脱氮。

6. 发明授权

US5423976A Hydrotreating of cracked naphtha 失效
标题翻译：加氢处理裂化石脑油
公开(公告)号：US5423976A
公开(公告)日：1995-06-13
申请号：US209492
申请日：1994-03-14
申请人： Chakka Sudhakar , Gerald G. Sandford , Phillip L. Dahlstrom , Mahendra S. Patel , Edwin L. Patmore
发明人： Chakka Sudhakar , Gerald G. Sandford , Phillip L. Dahlstrom , Mahendra S. Patel , Edwin L. Patmore
IPC分类号： B01J23/85 , B01J23/887 , C10G45/08 , C10G45/60 , C10G45/04
CPC分类号： B01J23/85 , B01J23/8871 , B01J23/8872 , C10G45/08
摘要： Hydrodesulfurization of cracked naphtha, with minimum attendant hydrogenation of olefins, is effected over a sulfided carbon support catalyst bearing (i) a non-noble Group VIII metal, (ii) a Group VI-B metal, and (iii) a metal of Group IA, II A, III B, or the lanthanide Group of rare earths.
摘要翻译：裂化石脑油的加氢脱硫，最少伴随着烯烃的氢化，在硫化碳载体催化剂上进行，该硫化碳载体催化剂承载（i）非贵金属Ⅷ族金属，（ⅱ）ⅥB族金属，和（ⅲ） IA，IIA，IIIB或稀土的镧系元素组。

7. 发明授权

US5556824A Hydrodearomatization of hydrocarbons 失效
公开(公告)号：US5556824A
公开(公告)日：1996-09-17
申请号：US498861
申请日：1995-07-06
申请人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Jeffrey G. Weissman
发明人： Chakka Sudhakar , Frank Dolfinger, Jr. , Max R. Cesar , Jeffrey G. Weissman
IPC分类号： B01J21/02 , B01J23/85 , C10G45/50 , B01J27/04
CPC分类号： B01J23/85 , B01J21/02 , C10G45/50
摘要： A naphtha or a middle distillate hydrocarbon is hydrodearomatized by hydrotreating in the presence of a catalyst containing boron, non-noble Group VIII metal, and Group VIB metal on a carbon support.

8. 发明授权

US5928501A Process for upgrading a hydrocarbon oil 失效
标题翻译：烃油改质工艺
公开(公告)号：US5928501A
公开(公告)日：1999-07-27
申请号：US17587
申请日：1998-02-03
申请人： Chakka Sudhakar , Mark T. Caspary , Stephen J. DeCanio
发明人： Chakka Sudhakar , Mark T. Caspary , Stephen J. DeCanio
IPC分类号： C10G45/08 , C10G45/16 , C10G17/00 , C10G45/04
CPC分类号： C10G45/08 , C10G45/16
摘要： A process for treating a hydrocarbon oil feed to reduce total acid number (TAN) and increase API gravity employs a catalyst which includes one or more metals of non-noble Group VIII of the periodic table (e.g., iron, cobalt and nickel), and at least one metal selected from Group VIB (e.g., chromium, tungsten and molybdenum) on a phosphorus treated carbon support, the phosphorus treated carbon support being comprised of phosphorus bound to the carbon surface predominantly as polyphosphate species characterized by peaks between -5 and -30 ppm in the solid-state magic angle spinning .sup.31 P nuclear magnetic resonance spectrum. The process includes blending the catalyst with the hydrocarbon oil feed to form a slurry which is then treated with hydrogen at moderate temperature and pressure in, for example, a tubular reactor. Deposit formation is minimized or avoided.
摘要翻译：用于处理烃油进料以减少总酸值（TAN）并增加API重力的方法使用包括一种或多种周期表非贵重族VIII（例如铁，钴和镍）的金属的催化剂，以及在磷处理的碳载体上选自VIB族（例如，铬，钨和钼）中的至少一种金属，磷处理的碳载体由磷结合的磷组成，主要作为多磷酸盐物质，其特征在于-5和 - 30ppm的固态魔角旋转31P核磁共振谱。该方法包括将催化剂与烃油进料混合以形成浆料，然后在中等温度和压力下用例如管式反应器的氢气处理。沉积物形成最小化或避免。

9. 发明授权

US5846406A Selective hydrodesulfurization of cracked naphtha using novel manganese oxide octahedral molecular sieve supported catalysts 失效
标题翻译：使用新型氧化锰八面体分子筛负载型催化剂对裂化石脑油进行选择性加氢脱硫
公开(公告)号：US5846406A
公开(公告)日：1998-12-08
申请号：US620148
申请日：1996-03-22
申请人： Chakka Sudhakar , Chi-Lin O'Young
发明人： Chakka Sudhakar , Chi-Lin O'Young
IPC分类号： C10G45/04 , C10G45/12 , C10G69/04
CPC分类号： B01J23/34 , B01J23/8892 , C10G45/12 , C10G69/04
摘要： Selective hydrodesulfurization of cracked naphtha, with minimum attendant hydrogenation of olefins, is effected over a novel catalyst composition comprising a sulfided, "manganese oxide octahedral molecular sieve" supported catalyst bearing (i) at least one non-noble Group VIII metal, (ii) at least one Group VI-B metal, optionally (iii) at least one metal of Group I-A, II-A, III-B, or the lanthanide series of rare earths, and optionally (iv) at least one metal of Group I-B. The catalyst of the present invention is highly selective in minimizing the olefin saturation and the resulting octane loss in the cracked naphtha hydrodesulfurization process.
摘要翻译：裂解石脑油的选择性加氢脱硫，最少伴随着烯烃的加氢，对包含硫化的“锰氧化物八面体分子筛”负载的催化剂（i）至少一种非贵金属VIII族金属的新催化剂组合物进行，（ii）至少一种VI-B族金属，任选地（iii）至少一种IA，II-A，III-B族金属或稀土镧系稀土金属，和任选地（iv）至少一种IB族金属。本发明的催化剂在使裂化石脑油加氢脱硫过程中的烯烃饱和度和所得辛烷值损失最小化方面具有高选择性。

10. 发明授权

US5423975A Selective hydrodesulfurization of naphtha using spent resid catalyst 失效
标题翻译：使用废渣催化剂选择加氢脱硫石脑油
公开(公告)号：US5423975A
公开(公告)日：1995-06-13
申请号：US910051
申请日：1992-07-08
申请人： Chakka Sudhakar , Gerald G. Sandford , Ajit K. Bhattacharya
发明人： Chakka Sudhakar , Gerald G. Sandford , Ajit K. Bhattacharya
IPC分类号： C10G45/08 , C10G45/04
CPC分类号： C10G45/08
摘要： Naphtha is selectively hydrodesulfurized using spent resid upgrading catalyst to remove sulfur while minimizing loss in octane level due to olefin saturation.
摘要翻译：使用废渣改质催化剂选择性地加氢脱硫，以除去硫，同时使由烯烃饱和引起的辛烷值降低最小化。

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