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    • 1. 发明专利
    • Isoparaffin-olefin alkylation method
    • 异丙肾上腺素烷化方法
    • JP2005162626A
    • 2005-06-23
    • JP2003400101
    • 2003-11-28
    • Catalysts & Chem Ind Co LtdKaoru Fujimoto薫 藤元触媒化成工業株式会社
    • FUJIMOTO KAORUASAMI KENJIKINO KATSUHIROKOYANAGI TSUGUOUSHIO MASARU
    • B01J29/08C07B61/00C07C2/58C07C9/16
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To inhibit easy diffusion of high boiling point hydrocarbons and coke formed in producing isoparaffin-olefin alkylates to the exterior of zeolite catalyst particles to cause poisoning of the active site of the zeolite catalyst and clogging of fine pores. SOLUTION: The alkylation of an isoparaffin-olefin mixture is performed by bringing a mixture of an isoparaffin and an olefin at a ratio (Mip/Mo) of the molar number (Mip) of the isoparaffin to that (Mo) of the olefin of 2-50 into contact with a zeolite catalyst in the presence of an organic solvent at 25 to 150°C. The organic solvent is at least one kind selelcted from an aromatic hydrocarbon, an alcohol, a polyhydric alcohol, an ester, an ether, a ketone, and a saturated hydrocarbon other than the isoparaffin. The zeolite catalyst is fine zeolite particles comprising granular zeolite having an average particle diameter of 0.1-1.0 μm and/or plate zeolite having an average thickness of 0.01-0.5 μm. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了抑制在沸石催化剂颗粒的外部产生异链烷烃 - 烯烃烷基化物时形成的高沸点烃和焦炭的容易扩散,引起沸石催化剂的活性部位的中毒和细孔的堵塞。 解决方案:异链烷烃 - 烯烃混合物的烷基化是通过使异链烷烃和烯烃的混合物的摩尔数(Mip)与异链烷烃的摩尔数(Mip)的比(Mip / Mo)相对于 烯烃,在有机溶剂存在下,在25〜150℃下与沸石催化剂接触。 有机溶剂是除异链烷烃以外的芳香族烃,醇,多元醇,酯,醚,酮,饱和烃等中至少一种。 沸石催化剂是包含平均粒径为0.1-1.0μm的粒状沸石和/或平均厚度为0.01-0.5μm的板沸石的细小沸石颗粒。 版权所有(C)2005,JPO&NCIPI
    • 3. 发明专利
    • Zeolite catalyst for isoparaffin-olefin alkylation and alkylation method using the catalyst
    • 用于异烟碱烯烃的沸石催化剂和使用催化剂的烷基化方法
    • JP2005161122A
    • 2005-06-23
    • JP2003400100
    • 2003-11-28
    • Catalysts & Chem Ind Co LtdKaoru Fujimoto薫 藤元触媒化成工業株式会社
    • FUJIMOTO KAORUASAMI KENJIKINO KATSUHIROKOYANAGI TSUGUOUSHIO MASARU
    • B01J29/08B01J35/02B01J35/08B01J37/04C10G35/095
    • PROBLEM TO BE SOLVED: To provide a zeolite catalyst for isoparaffin-olefin alkylation which is excellent in selectivity of gasoline fraction hydrocarbons while suppressing the generation of high-boiling-point fractions and carbonaceous substances and can keep the selectivity high over a long period.
      SOLUTION: The zeolite catalyst for isoparaffin-olefin alkylation contains fine zeolite particles being particulate zeolite with an average particle size of 0.1-1.0 μm and/or platy zeolite with an average thickness of 0.01-0.5 μm. The zeolite is of a faujasite type and contains at least one kind of lanthanoide group element in a quantity of 5-30 wt.% in terms of oxide. The catalyst is composed of the above-mentioned zeolite and a binder and is a spherical molded article having an average particle size of 0.3-5 mm or a platy molded article having an average thickness of 0.01-5 mm.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:提供一种用于异链烷烃 - 烯烃烷基化的沸石催化剂,其在抑制高沸点馏分和含碳物质的产生的同时抑制汽油馏分烃的选择性,并且可以长时间保持选择性高 期。 解决方案:用于异链烷烃 - 烯烃烷基化的沸石催化剂包含具有平均粒度为0.1-1.0μm的颗粒状沸石的细沸石颗粒和/或平均厚度为0.01-0.5μm的板状沸石。 沸石是八面沸石型,并且含有氧化物换算量为5-30重量%的至少一种镧系元素元素。 催化剂由上述沸石和粘合剂组成,是平均粒径为0.3〜5mm的球状成型体,平均厚度为0.01-5mm的板状成型体。 版权所有(C)2005,JPO&NCIPI
    • 4. 发明专利
    • Electroconductive titanium oxide and its manufacture method
    • 电极氧化钛及其制造方法
    • JP2007320821A
    • 2007-12-13
    • JP2006154826
    • 2006-06-02
    • Catalysts & Chem Ind Co Ltd触媒化成工業株式会社
    • MIZUNO TAKAYOSHIKOYANAGI TSUGUO
    • C01G23/00H01B1/08H01B13/00
    • PROBLEM TO BE SOLVED: To provide an electroconductive titanium oxide preferably usable for forming a conductive thin film and the like, which is superior in the adhesion to a base material and in transparency, as a conductive filler, and its manufacturing method. SOLUTION: The electroconductive titanium oxide is characterised in that it contains at least one kind of doping material (D) element selected from the group consisting of group 3A (lanthanoid and actinoid), group 5A, group 3B and group 4B; and the atomic ratio of the content of the doping material to Ti, D/Ti, is within the range of 0.01-0.2, and its shape is granular, fibrous or tabular. In the method of manufacturing the conductive titanium oxide, a mixture water solution of peroxotitanic acid and/or titanium oxide colloid and at least one kind of element of compound for doping material selected from the group consisting of group 3A (lanthanoid and actinoid), group 5A, group 3B and group 4B, is hydrothermally treated in the temperature range of 110-270°C in the presence of an alkali, and then heat-treated at a temperature of 100-700°C under a reducing gas atmosphere, an oxidizing gas atmosphere or an inert gas atmosphere. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种导电性氧化钛及其制造方法,其优选可用于形成导电薄膜等,其与基材的粘合性和透明性优异,作为导电填料。 导电性氧化钛的特征在于,它含有选自3A族(镧系元素和锕系元素),5A族,3B族和4B族的至少一种掺杂材料(D)元素; 并且掺杂材料的含量与Ti,D / Ti的原子比在0.01-0.2的范围内,其形状为粒状,纤维状或片状。 在制造导电性氧化钛的方法中,过氧钛酸和/或氧化钛胶体的混合水溶液和选自由3A族(镧系元素和锕系元素)组成的组中的至少一种用于掺杂材料的化合物元素, 5A,3B组和4B组在碱存在下,在110-270℃的温度范围内进行水热处理,然后在还原气氛下在100-700℃的温度下进行热处理,氧化 气体气氛或惰性气体气氛。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Carbon monoxide oxidizing catalyst and its manufacturing method
    • 一氧化碳氧化催化剂及其制造方法
    • JP2005052718A
    • 2005-03-03
    • JP2003285091
    • 2003-08-01
    • Catalysts & Chem Ind Co Ltd触媒化成工業株式会社
    • TANAKA ATSUSHIKOYANAGI TSUGUO
    • C01B3/40B01J23/58B01J23/66C01G23/00C01G23/047H01M8/06H01M8/10
    • Y02P20/52Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a carbon monoxide oxidizing catalyst capable of keeping high oxidation activity over a long period of time, and its manufacturing method. SOLUTION: The carbon monoxide oxidizing catalyst is characterized in that metal fine particles comprising at least one element, which is selected from the group consisting of Au, Ag, Pd, Pt, Rh, Cu, Ni, Co, Sn, Ti, In, Al, Ta, Sb and Ru, are supported on tubular and/or fibrous titanium oxide particles comprising titanium oxide and/or titanium oxide and an oxide other than titanium oxide and having a composition represented by the formula : Ti a M b O x (wherein a+nb/4 is 1; b is 0 to 0.2; x is 1≤x≤2; M is an element other than Ti; and n is the valency of M). This carbon monoxide oxidizing catalyst is manufactured by mixing a dispersion of tubular and/or fibrous titanium oxide particles with a metal fine particle dispersion and adjusting the pH of the resulting dispersion to 2-5 if necessary to bring tubular and/or fibrous titanium oxide particles and metal fine particles into contact with each other. COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:提供能够长时间保持高氧化活性的一氧化碳氧化催化剂及其制造方法。 一氧化碳氧化催化剂的特征在于,包含选自Au,Ag,Pd,Pt,Rh,Cu,Ni,Co,Sn,Ti中的至少一种元素的金属微粒 In,Al,Ta,Sb和Ru负载在包含氧化钛和/或氧化钛和氧化钛以外的氧化物的管状和/或纤维状氧化钛颗粒上,并且具有由下式表示的组成:Ti (其中a + nb / 4是1; b是0到0.2; x是1≤x≤2; M是一个或多个) 元素,而不是Ti; n是M的化合价)。 该一氧化碳氧化催化剂通过将管状和/或纤维状二氧化钛颗粒的分散体与金属微粒分散体混合并将所得分散体的pH调节至2-5(如果需要)以使管状和/或纤维状氧化钛颗粒 和金属微粒彼此接触。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Photoelectric cell
    • 光电池
    • JP2004178885A
    • 2004-06-24
    • JP2002341914
    • 2002-11-26
    • Catalysts & Chem Ind Co Ltd触媒化成工業株式会社
    • KOYANAGI TSUGUOKINO KATSUHIRO
    • H01L31/04H01M14/00
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a photoelectric cell with improved ion diffusibility and ion moving speed, that is, ion conductivity, and, therefore, high photoelectric conversion efficiency, without electrolyte liquid leakage and excellent in long-term stability. SOLUTION: The photoelectric cell is formed by arranging a substrate having an electrode layer (1) on its surface with a semiconductor layer (2) adsorbing photosensitizer on the surface of the electrode layer (1) and a substrate having an electrode layer (3) on its surface so that the electrode layer (1) and the electrode layer (3) face each other, and an electrolyte layer is interposed between the semiconductor layer (2) and the electrode layer (3). The electrolyte layer is composed of an electrolyte and silica based particles, and a content of the silica based particles in the electrolyte ranges between 1 to 60 wt%. At least the substrate and the electrode on one side is transparent. The silica based particle has an OH group on the surface, and a volume of the OH group on the surface of the particle ranges between 0.01 to 5 pieces per nm -2 . COPYRIGHT: (C)2004,JPO
    • 要解决的问题:为了提供具有改善的离子扩散性和离子移动速度的光电池,即离子传导性,因此,高的光电转换效率,没有电解液液体泄漏并且具有优异的长期稳定性。 解决方案:通过在其表面上布置具有电极层(1)的基板,在电极层(1)的表面上吸附光敏剂的半导体层(2)和具有电极层 (3),使得电极层(1)和电极层(3)彼此面对,并且在半导体层(2)和电极层(3)之间插入电解质层。 电解质层由电解质和二氧化硅类粒子构成,电解质中二氧化硅系粒子的含量为1〜60重量%。 至少基板和一侧的电极是透明的。 二氧化硅基颗粒在表面上具有OH基团,并且颗粒表面上的OH基团的体积范围为0.01至5个/ nm -2 。 版权所有(C)2004,JPO
    • 10. 发明专利
    • Catalyst for methanating carbon monoxide and method for methanating carbon monoxide by using the same
    • 用于甲氧化一氧化碳的催化剂及其使用方法甲氧化一氧化碳
    • JP2008155147A
    • 2008-07-10
    • JP2006347908
    • 2006-12-25
    • Catalysts & Chem Ind Co Ltd触媒化成工業株式会社
    • MIZUNO TAKAYOSHIKINO KATSUHIROKOYANAGI TSUGUO
    • B01J23/755B01J23/825B01J23/835B01J23/85B01J23/889C01B3/58H01M8/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a catalyst for removing carbon monoxide, which has high CO adsorptivity and the activity and selectivity more excellent than those of the conventional Ni-used methanation catalyst at low temperature and can be supplied at a low price since a noble metal is not used and to provide a method for removing carbon monoxide by using the catalyst. SOLUTION: The catalyst for methanating carbon monoxide is obtained by depositing metal Ni and/or metal Co on a metal oxide carrier and characterized in that the average particle size of the deposited metal Ni and/or metal Co is within 0.5-3 nm and the amount of the deposited metal Ni and/or metal Co is within 5.0-15 wt.% of the catalyst. The catalyst for methanating carbon monoxide further contains one or more metals which are selected from group 4B metals, group 6A metals and group 7A metals and the content of which is within 0.1-5 wt.%. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种除去一氧化碳的催化剂,其具有高的CO吸附性,并且在低温下比常规的Ni使用的甲烷化催化剂的活性和选择性更优异并且可以以低的价格供应 由于不使用贵金属并且提供通过使用催化剂除去一氧化碳的方法。 解决方案:用于甲烷化一氧化碳的催化剂通过在金属氧化物载体上沉积金属Ni和/或金属Co​​获得,其特征在于沉积的金属Ni和/或金属Co​​的平均粒度在0.5-3 并且沉积的金属Ni和/或金属Co​​的量在催化剂的5.0-15重量%内。 用于甲烷化一氧化碳的催化剂还含有一种或多种选自4B族金属,6A族金属和7A族金属的金属,其含量在0.1-5wt。%范围内。 版权所有(C)2008,JPO&INPIT