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    • 7. 发明授权
    • Method for production of additives for lubricating oils
    • 生产润滑油添加剂的方法
    • US07074937B2
    • 2006-07-11
    • US10663159
    • 2003-09-15
    • Ravindranath Mukkamala
    • Ravindranath Mukkamala
    • C07D233/42
    • C07D233/54C07D233/42
    • A method for making a compound of formula (I) wherein bonds a and b are single or double bonds, provided that one of a and b is a single bond and the other is a double bond; one of B1 and B2 is —CHR5—CHR6—C(Y)ZR7 and the other is absent; B3 is hydrogen; Y is O or S; Z is O, S or NR9; R5 is hydrogen or C1–C4 alkyl; R6 is hydrogen or C1–C4 alkyl; R7, R9 are independently hydrogen, alkyl, alkenyl, aryl or aralkyl. The method comprises steps of: (a) preparing an imidazolidinethione having formula by combining a cyanide source, a sulfide salt, and at least one ketone or aldehyde; and (b) adding to the imidazolidinethione, without isolation of the imidazolidinethione, CHR5═CR6—C(O)OR7.
    • 制备式(I)化合物的方法,其中a和b键是单键或双键,条件是a和b之一是单键,另一个是双键; B 1和B 2之一是-CHR 5 -CHR 6 -C(Y)ZR SUP > 7 而另一个则不存在 B 3是氢; Y为O或S; Z是O,S或NR 9; R 5是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; R 9,R 9独立地是氢,烷基,烯基,芳基或芳烷基。 该方法包括以下步骤:(a)通过将氰化物源,硫化物盐和至少一种酮或醛组合而制备具有式的咪唑烷硫酮; 和(b)在不分离咪唑烷硫酮的情况下向咪唑烷硫酮加入CHR 5 -CR 6 -C(O)或者7以上。