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1. 发明申请

US20120289439A1 PROCESS FOR THE MANUFACTURE OF SULPHIDE COMPOUNDS 审中-公开
标题翻译：制备硫化物化合物的方法
公开(公告)号：US20120289439A1
公开(公告)日：2012-11-15
申请号：US13519720
申请日：2011-01-05
申请人： Carolus Matthias Anna Maria Mesters , Joseph Broun Powell , Ronald Jan Schoonebeek , Dean Chien Wang
发明人： Carolus Matthias Anna Maria Mesters , Joseph Broun Powell , Ronald Jan Schoonebeek , Dean Chien Wang
IPC分类号： C01B31/26 , C09K8/58
CPC分类号： C01B32/72 , C01B32/70
摘要： A process for the manufacture of carbon disulphide comprising the following steps reacting carbon dioxide with hydrogen sulphide to form carbonyl sulphide and water; and absorbing at least a portion of the water with a sorbent, leaving a mixture comprising carbonyl sulphide, carbon dioxide, and hydrogen sulphide.
摘要翻译：一种制备二硫化碳的方法，包括以下步骤：使二氧化碳与硫化氢反应形成硫化羰和水; 并用吸附剂吸收至少一部分水，留下包含硫化羰，二氧化碳和硫化氢的混合物。

2. 发明申请

US20090312202A1 PROCESS FOR THE MANUFACTURE OF CARBON DISULPHIDE AND USE OF A LIQUID STREAM COMPRISING CARBON DISULPHIDE FOR ENHANCED OIL RECOVERY 有权
标题翻译：碳纳米管制造工艺及含有碳化硼的液相流动用于增强油的回收利用
公开(公告)号：US20090312202A1
公开(公告)日：2009-12-17
申请号：US12307505
申请日：2007-07-05
申请人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： C01B31/26 , C09K8/60
CPC分类号： C01B32/72 , B01J21/04 , C01B32/50
摘要： The invention provides a process for the manufacture of carbon disulphide by reacting carbon monoxide with elemental sulphur to form carbonyl sulphide and disproportionating the carbonyl sulphide formed into carbon disulphide and carbon dioxide, the process comprising contacting a gaseous stream comprising carbon monoxide with a liquid elemental sulphur phase containing a solid catalyst at a temperature in the range of from 250 to 700° C. to obtain a gaseous phase comprising carbonyl sulphide, carbon disulphide and carbon dioxide. The invention further provides the use of a liquid stream comprising carbon disulphide, carbonyl sulphide and carbon dioxide obtainable by such process for enhanced oil recovery.
摘要翻译：本发明提供了通过使一氧化碳与元素硫反应以形成硫化硫并歧化形成二硫化碳和二氧化碳的硫化羰来制造二硫化碳的方法，该方法包括使包含一氧化碳的气流与液体元素硫在250-700℃的温度下含有固体催化剂的相，得到包含硫化羰，二硫化碳和二氧化碳的气相。本发明进一步提供了包含二硫化碳，硫化羰和二氧化碳的液体流的用途，所述二氧化碳可通过这种方法获得，以提高油的回收率。

3. 发明授权

US08722006B2 Process for the manufacture of carbon disulphide 失效
标题翻译：二硫化碳的制造方法
公开(公告)号：US08722006B2
公开(公告)日：2014-05-13
申请号：US12300748
申请日：2007-05-14
申请人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： C01B31/26
CPC分类号： E21B43/16 , C01B32/70 , C09K8/58
摘要： The invention provides a process for the manufacture of carbon disulphide comprising supplying a molecular oxygen-containing gas and a feedstock comprising a hydrocarbonaceous compound to a reaction zone containing a liquid elemental sulphur phase and reacting, in the liquid sulphur phase, at a temperature in the range of from 300 to 750° C., the hydrocarbonaceous compound with elemental sulphur to form carbon disulphide and hydrogen sulphide and oxidizing at least part of the hydrogen sulphide formed to elemental sulphur and water. The invention further provides the use of a liquid stream comprising carbon disulphide, hydrogen sulphide and carbonyl sulphide obtainable such process for enhanced oil recovery.
摘要翻译：本发明提供一种制造二硫化碳的方法，包括将含分子氧的气体和包含烃类化合物的原料供给到含有液体元素硫相的反应区中，并在液相硫相中在范围为300至750℃，含烃化合物与元素硫形成二硫化碳和硫化氢，并将至少部分硫化氢氧化成元素硫和水。本发明进一步提供了包含二硫化碳，硫化氢和硫化羰的液体流的用途，这种方法可用于提高采油率。

4. 发明申请

US20100028199A1 PROCESS FOR IMPROVING THE SMELL OF ELEMENTAL SULPHUR 审中-公开
标题翻译：改善单质硫酸钠的方法
公开(公告)号：US20100028199A1
公开(公告)日：2010-02-04
申请号：US12444226
申请日：2007-10-03
申请人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： A61L9/00
CPC分类号： C04B28/36 , C01B17/0232 , C01B17/046
摘要： A process for improving the smell of a stream of elemental sulphur comprising an organic polysulphide and/or a thiol, the process comprising the following step: (a) heating the stream of liquid elemental sulphur comprising an organic polysulphide and/or a thiol at a heating temperature in the range of from 360 to 700° C., at a pressure that is sufficient to maintain a liquid elemental sulphur phase to obtain heat-treated elemental sulphur.
摘要翻译：一种用于改善包含有机多硫化物和/或硫醇的元素硫气流的方法，该方法包括以下步骤：（a）在下列步骤中加热包含有机多硫化物和/或硫醇的液体元素硫流：加热温度在360-700℃的范围内，在足以保持液态元素硫相以获得热处理的元素硫的压力下。

5. 发明授权

US08926737B2 Process for producing purified natural gas 有权
标题翻译：纯化天然气生产工艺
公开(公告)号：US08926737B2
公开(公告)日：2015-01-06
申请号：US13131085
申请日：2009-11-26
申请人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek , Eri Ito
发明人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek , Eri Ito
IPC分类号： B01D53/14 , C10L3/10 , B01D53/86
CPC分类号： B01D53/8603 , B01D53/1487 , B01D2257/306 , B01D2258/06 , C10L3/10
摘要： The present invention provides a process for purifying natural gas, comprising removing mercaptans from a natural gas stream by a combination of an amine-based separation unit and a selective oxidation unit to obtain a purified natural gas stream, wherein at least part of the mercaptans are converted into at least elemental sulphur in the selective oxidation unit by selective catalytic oxidation.
摘要翻译：本发明提供天然气净化方法，其包括通过胺基分离单元和选择性氧化单元的组合从天然气流中除去硫醇以获得纯化天然气流，其中至少部分硫醇为通过选择性催化氧化在选择性氧化单元中转化为至少元素硫。

6. 发明授权

US07291320B2 Process for the selective oxidation of hydrogen sulfhide 失效
标题翻译：硫化氢选择性氧化工艺
公开(公告)号：US07291320B2
公开(公告)日：2007-11-06
申请号：US10954043
申请日：2004-09-29
申请人： John Wilhelm Geus , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： John Wilhelm Geus , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： C01B17/04
CPC分类号： C01B17/0469
摘要： A process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide containing feed gas to elemental sulphur, wherein the hydrogen sulphide containing feed gas (3), an inert liquid medium (5), and a molecular-oxygen containing gas (4) are supplied to a reaction zone (1) comprising at least one catalytic zone (2) comprising an oxidation catalyst to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide (8), in which process the oxidation catalyst of each catalytic zone (2) is contacted with hydrogen sulphide and/or molecular-oxygen in the presence of inert liquid medium at a temperature in the range of from 120 to 160° C., under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with the inert liquid medium.
摘要翻译：一种在含硫化氢的进料气体中将硫化氢选择性氧化成元素硫的方法，其中含硫化氢的进料气体（3），惰性液体介质（5）和含分子氧的气体（4）是供应到包含至少一个包含氧化催化剂以形成元素硫的催化剂区域（2）的反应区（1）和贫硫化氢气体（8）的反应区（8），其中每个催化区（2）的氧化催化剂，在惰性液体介质存在下，在120至160℃的温度范围内与硫化氢和/或分子氧接触，使得形成的元素硫基本上为液体形式，并从反应区用惰性液体介质。

7. 发明授权

US08524189B2 Process for the selective oxidation of hydrogen sulphide 失效
标题翻译：硫化氢选择性氧化的方法
公开(公告)号：US08524189B2
公开(公告)日：2013-09-03
申请号：US13131130
申请日：2009-11-26
申请人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： C01B17/04 , C10L3/10
CPC分类号： B01D53/8612 , B01D2251/10 , B01D2255/20707 , B01D2256/16 , B01D2256/24 , B01D2257/304 , C01B17/0469
摘要： The present invention provides a process for the selective oxidation of hydrogen sulphide contained in a hydrogen sulphide-containing hydrocarbon feed gas to elemental sulphur. The hydrogen sulphide-containing hydrocarbon feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone containing a TiO2-comprising catalyst, wherein elemental sulphur and a gaseous stream depleted in hydrogen sulphide are formed. The gas feeds are contacted with the TiO2 containing catalyst at elevated pressure and at a temperature in the range of from 120 and below 160 ° C., under such conditions that the elemental sulphur formed is essentially in liquid form. At least part of the sulphur dioxide-containing gas is obtained by combusting elemental sulphur to obtain a gaseous mixture of sulphur dioxide and nitrogen and then concentrating the gaseous mixture to provide the sulphur dioxide-containing gas.
摘要翻译：本发明提供了将含硫化氢的烃进料气体中所含的硫化氢选择性氧化成元素硫的方法。将含硫化氢的烃进料气体和含二氧化硫的气体供应到含有TiO 2的催化剂的反应区，其中形成元素硫和贫硫化氢气体。气体进料在升高的压力下和在120℃和低于160℃的温度下，在形成的元素硫基本上是液体形式的条件下与含TiO 2的催化剂接触。通过燃烧元素硫以获得二氧化硫和氮的气体混合物，然后浓缩气体混合物以提供含二氧化硫的气体，获得至少部分含二氧化硫的气体。

8. 发明申请

US20100084315A1 PROCESS FOR TREATING ELEMENTAL SULPHUR FOR SMELL IMPROVEMENT 审中-公开
标题翻译：处理元素硫的方法进行小型改进
公开(公告)号：US20100084315A1
公开(公告)日：2010-04-08
申请号：US12444223
申请日：2007-10-03
申请人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek , Rob Aloysius Maria Van Trier , Guy Lode Magda Maria Verbist
发明人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek , Rob Aloysius Maria Van Trier , Guy Lode Magda Maria Verbist
IPC分类号： C10G27/00
CPC分类号： C04B28/36 , C01B17/0232 , C01B17/0243 , C01B17/905
摘要： A process for treating a stream of elemental sulphur comprising an organic polysulphide and/or a thiol for smell improvement, the process comprising the following steps: (a) providing a molten stream of elemental sulphur comprising an organic polysulphide and/or a thiol at a temperature in the range of from 120 to 160° C.; (b) admixing a liquid unsaturated compound with the stream of molten elemental sulphur in an amount in the range of from 0.01 to 10.0 wt % based on the weight of sulphur to allow the organic polysulphide and/or thiol to react with the unsaturated compound.
摘要翻译：一种用于处理包含有机多硫化物和/或硫醇以改善气味的元素硫流的方法，所述方法包括以下步骤：（a）在一个或多个硫化氢溶液中提供包含有机多硫化物和/或硫醇的元素硫的熔融流温度范围为120〜160℃。（b）将液体不饱和化合物与熔融元素硫流以相对于硫的重量计为0.01至10.0重量％的量混合，以使有机多硫化物和/或硫醇与不饱和化合物反应。

9. 发明授权

US08097230B2 Process for the manufacture of carbon disulphide and use of a liquid stream comprising carbon disulphide for enhanced oil recovery 有权
标题翻译：用于制造二硫化碳的方法和使用包含二硫化碳的液体流以提高采油率
公开(公告)号：US08097230B2
公开(公告)日：2012-01-17
申请号：US12307505
申请日：2007-07-05
申请人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： C01B31/26
CPC分类号： C01B32/72 , B01J21/04 , C01B32/50
摘要： The invention provides a process for the manufacture of carbon disulphide by reacting carbon monoxide with elemental sulphur to form carbonyl sulphide and disproportionating the carbonyl sulphide formed into carbon disulphide and carbon dioxide, the process comprising contacting a gaseous stream comprising carbon monoxide with a liquid elemental sulphur phase containing a solid catalyst at a temperature in the range of from 250 to 700° C. to obtain a gaseous phase comprising carbonyl sulphide, carbon disulphide and carbon dioxide. The invention further provides the use of a liquid stream comprising carbon disulphide, carbonyl sulphide and carbon dioxide obtainable by such process for enhanced oil recovery.
摘要翻译：本发明提供了通过使一氧化碳与元素硫反应以形成硫化硫并歧化形成二硫化碳和二氧化碳的硫化羰来制造二硫化碳的方法，该方法包括使包含一氧化碳的气流与液体元素硫在250-700℃的温度下含有固体催化剂的相，得到包含硫化羰，二硫化碳和二氧化碳的气相。本发明进一步提供了包含二硫化碳，硫化羰和二氧化碳的液体流的用途，所述二氧化碳可通过这种方法获得，以提高油的回收率。

10. 发明申请

US20110274604A1 PROCESS FOR THE SELECTIVE OXIDATION OF HYDROGEN SULPHIDE 失效
标题翻译：氢硫化物的选择性氧化方法
公开(公告)号：US20110274604A1
公开(公告)日：2011-11-10
申请号：US13131130
申请日：2008-11-26
申请人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
发明人： Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
IPC分类号： B01D53/52
CPC分类号： B01D53/8612 , B01D2251/10 , B01D2255/20707 , B01D2256/16 , B01D2256/24 , B01D2257/304 , C01B17/0469
摘要： The present invention provides a process for the selective oxidation of hydrogen sulphide contained in a hydrogen sulphide-containing hydrocarbon feed gas to elemental sulphur. The hydrogen sulphide-containing hydrocarbon feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone containing a TiO2-comprising catalyst, wherein elemental sulphur and a gaseous stream depleted in hydrogen sulphide are formed. The gas feeds are contacted with the TiO2 containing catalyst at elevated pressure and at a temperature in the range of from 120 and below 160° C., under such conditions that the elemental sulphur formed is essentially in liquid form. At least part of the sulphur dioxide-containing gas is obtained by combusting elemental sulphur to obtain a gaseous mixture of sulphur dioxide and nitrogen and then concentrating the gaseous mixture to provide the sulphur dioxide-containing gas.
摘要翻译：本发明提供了将含硫化氢的烃进料气体中所含的硫化氢选择性氧化成元素硫的方法。将含硫化氢的烃进料气体和含二氧化硫的气体供应到含有TiO 2的催化剂的反应区，其中形成元素硫和贫硫化氢气体。气体进料在升高的压力下和在120℃和低于160℃的温度下，在形成的元素硫基本上是液体形式的条件下与含TiO 2的催化剂接触。通过燃烧元素硫以获得二氧化硫和氮的气体混合物，然后浓缩气体混合物以提供含二氧化硫的气体，获得至少部分含二氧化硫的气体。

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