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1. 发明授权

US07901655B2 Process for producing a gas stream depleted of hydrogen sulphide 失效
标题翻译：生产耗尽硫化氢的气流的方法
公开(公告)号：US07901655B2
公开(公告)日：2011-03-08
申请号：US12770561
申请日：2010-04-29
申请人： Carolus Matthias Anna Maria Mesters , Isaac Cornelis Van Den Born
发明人： Carolus Matthias Anna Maria Mesters , Isaac Cornelis Van Den Born
IPC分类号： C01B17/04 , C01B17/50
CPC分类号： C01B17/54 , B01D53/8612 , C01B17/0469 , C01B17/05
摘要： A process for treating a gas stream comprising H2S that includes the step of selectively oxidizing the H2S of the gas stream within a catalytic zone containing an oxidation catalyst and in the presence of an inert liquid medium and molecular oxygen to form elemental sulfur and a gas stream depleted of H2S. A liquid stream yielded from the catalytic zone and containing the inert liquid medium and liquid elemental sulfur undergoes a separation into a first liquid phase rich in the inert liquid medium and a second liquid phase rich in elemental sulfur. Either at least a part of the liquid stream or at least a part of the second liquid phase, or both, undergoes a combustion to form a fluid stream that comprises sulfur dioxide.
摘要翻译：一种用于处理包含H 2 S的气流的方法，其包括在含有氧化催化剂的催化区内和在惰性液体介质和分子氧的存在下选择性地氧化气流的H 2 S的步骤，以形成元素硫和气流耗尽H2S。从催化区产生的含有惰性液体介质的液体流，液体元素硫经历分离成富含惰性液体介质的第一液相和富含元素硫的第二液相。液态物流或至少一部分第二液相或两者的至少一部分经历燃烧以形成包含二氧化硫的流体物流。

2. 发明申请

US20100209322A1 PROCESS FOR PRODUCING A GAS STREAM DEPLETED OF HYDROGEN SULPHIDE 失效
标题翻译：生产硫化氢废气的工艺
公开(公告)号：US20100209322A1
公开(公告)日：2010-08-19
申请号：US12770561
申请日：2010-04-29
申请人： Carolus Matthias Anna Maria MESTERS , Isaac Cornelis Van Den Born
发明人： Carolus Matthias Anna Maria MESTERS , Isaac Cornelis Van Den Born
IPC分类号： B01D53/52
CPC分类号： C01B17/54 , B01D53/8612 , C01B17/0469 , C01B17/05
摘要： A process for treating a gas stream comprising H2S that includes the step of selectively oxidizing the H2S of the gas stream within a catalytic zone containing an oxidation catalyst and in the presence of an inert liquid medium and molecular oxygen to form elemental sulfur and a gas stream depleted of H2S. A liquid stream yielded from the catalytic zone and containing the inert liquid medium and liquid elemental sulfur undergoes a separation into a first liquid phase rich in the inert liquid medium and a second liquid phase rich in elemental sulfur. Either at least a part of the liquid stream or at least a part of the second liquid phase, or both, undergoes a combustion to form a fluid stream that comprises sulfur dioxide.
摘要翻译：一种用于处理包含H 2 S的气流的方法，其包括在含有氧化催化剂的催化区内和在惰性液体介质和分子氧的存在下选择性地氧化气流的H 2 S的步骤，以形成元素硫和气流耗尽H2S。从催化区产生的含有惰性液体介质的液体流，液体元素硫经历分离成富含惰性液体介质的第一液相和富含元素硫的第二液相。液态物流或至少一部分第二液相或两者的至少一部分经历燃烧以形成包含二氧化硫的流体物流。

3. 发明授权

US07727507B2 Process for producing a gas stream depleted of hydrogen sulphide 失效
标题翻译：生产耗尽硫化氢的气流的方法
公开(公告)号：US07727507B2
公开(公告)日：2010-06-01
申请号：US11887292
申请日：2006-03-28
申请人： Carolus Matthias Anna Maria Mesters , Isaac Cornelis Van Den Born
发明人： Carolus Matthias Anna Maria Mesters , Isaac Cornelis Van Den Born
IPC分类号： C01B17/04 , C01B17/50
CPC分类号： C01B17/54 , B01D53/8612 , C01B17/0469 , C01B17/05
摘要： A process for treating a gas stream comprising H2S that includes the step of selectively oxidizing the H2S of the gas stream within a catalytic zone containing an oxidation catalyst and in the presence of an inert liquid medium and molecular oxygen to form elemental sulfur and a gas stream depleted of H2S. A liquid stream yielded from the catalytic zone and containing the inert liquid medium and liquid elemental sulfur undergoes a separation into a first liquid phase rich in the inert liquid medium and a second liquid phase rich in elemental sulfur. Either at least a part of the liquid stream or at least a part of the second liquid phase, or both, undergoes a combustion to form a fluid stream that comprises sulfur dioxide.
摘要翻译：一种用于处理包含H 2 S的气流的方法，其包括在含有氧化催化剂的催化区内和在惰性液体介质和分子氧的存在下选择性地氧化气流的H 2 S的步骤，以形成元素硫和气流耗尽H2S。从催化区产生的含有惰性液体介质的液体流，液体元素硫经历分离成富含惰性液体介质的第一液相和富含元素硫的第二液相。液态物流或至少一部分第二液相或两者的至少一部分经历燃烧以形成包含二氧化硫的流体物流。

4. 发明申请

US20090232717A1 Process for Producing a Gas Stream Depleted of Hydrogen Sulphide 失效
标题翻译：产生硫化氢消失的气流的方法
公开(公告)号：US20090232717A1
公开(公告)日：2009-09-17
申请号：US11887292
申请日：2006-03-28
申请人： Carolus Matthias Anna Maria Mesters , Isaac Cornelis Van Den Born
发明人： Carolus Matthias Anna Maria Mesters , Isaac Cornelis Van Den Born
IPC分类号： B01D53/52
CPC分类号： C01B17/54 , B01D53/8612 , C01B17/0469 , C01B17/05
摘要： The invention provides a process for producing a gas stream depleted of H2S from a feed gas stream comprising H2S, the process comprising the steps of: (a) selectively oxidizing H2S by supplying the feed gas stream comprising H2S, an inert liquid medium and a molecular-oxygen comprising gas stream to a reaction zone comprising at least one catalytic zone comprising an oxidation catalyst and contacting the oxidation catalyst of each catalytic zone with the feed gas stream and/or the molecular-oxygen comprising gas stream in the presence of inert liquid medium at a temperature in the range of from 120 to 160° C. to form elemental sulphur and the gas stream depleted of H2S, under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with inert liquid medium to obtain a liquid stream comprising inert liquid medium and essentially liquid elemental sulphur; (b) optionally separating the liquid stream obtained in step (a) into a first liquid phase enriched in inert liquid medium and a second liquid phase enriched in liquid elemental sulphur; (c) combusting at least part of the liquid stream obtained in step (a) or at least part of the second liquid phase obtained in step (b) to form a fluid stream comprising sulphur dioxide.
摘要翻译：本发明提供了一种从包含H 2 S的进料气流中产生缺少H 2 S的气流的方法，该方法包括以下步骤：（a）通过供应包含H 2 S，惰性液体介质和分子的进料气流来选择性地氧化H 2 S - 氧气，其包含至少一个包含氧化催化剂的催化区的反应区，所述催化区包含各催化区的氧化催化剂与在惰性液体介质存在下的进料气流和/或含分子氧的气流接触在120至160℃的温度范围内，以在形成的元素硫基本上为液体形式并且用惰性液体介质从反应区中除去的条件下形成元素硫和贫的H 2 S的气流以获得包含惰性液体介质和基本上液体元素硫的液体流; （b）任选地将步骤（a）中获得的液体流分离成富含惰性液体介质的第一液相和富含液体元素硫的第二液相; （c）将步骤（a）中获得的至少部分液体物流或步骤（b）中获得的至少部分第二液相燃烧以形成包含二氧化硫的流体物流。

5. 发明申请

US20120094337A1 PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM 审中-公开
标题翻译：生产纯化合成气流的方法
公开(公告)号：US20120094337A1
公开(公告)日：2012-04-19
申请号：US13260770
申请日：2010-03-30
申请人： Isaac Cornelis Van Den Born , Gijsbert Jan Van Heeringen , Cornelis Jacobus Smit , Alex Frederik Woldhuis
发明人： Isaac Cornelis Van Den Born , Gijsbert Jan Van Heeringen , Cornelis Jacobus Smit , Alex Frederik Woldhuis
IPC分类号： C12P1/04 , C12P7/00 , H02K7/18 , C12P3/00 , C09K8/60 , C12P7/04 , C12P7/54
CPC分类号： C01B3/16 , B01D53/1425 , B01D53/1462 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/504 , C01B3/52 , C01B17/0408 , C01B17/05 , C01B2203/0415 , C01B2203/0475 , C01B2203/0485 , Y02C10/06 , Y02P20/152 , Y02P20/52
摘要： The invention provides a process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising contacting it with a water gas shift catalyst in a shift reactor to obtain a shifted synthesis gas stream enriched in H2S and in CO2. H2S and CO2 are removed from the shifted synthesis gas stream by contacting it with an absorbing liquid to obtain semi-purified synthesis gas and an absorbing liquid rich in H2S and CO2. At least part of the absorbing liquid rich in H2S and CO2 is heated to obtain heated absorbing liquid rich in H2S and CO2 followed by de-pressurising the heated absorbing liquid rich in H2S and CO2 in a flash vessel to thereby obtain a flash gas rich in CO2 and absorbing liquid rich in H2S. The absorbing liquid rich in H2S is contacted at elevated temperature with a stripping gas to thereby transfer H2S to the stripping gas to obtain regenerated absorbing liquid and stripping gas rich in H2S. The H2S in the stripping gas rich in H2S is converted to elemental sulphur and the H2S from the semi-purified synthesis gas is removed therefrom by contacting this gas stream in a H2S-removal zone with an aqueous alkaline washing liquid to obtain a H2S-depleted synthesis gas stream and a sulphide-comprising aqueous stream. The sulphide-comprising aqueous stream is contacted with sulphide-oxidizing bacteria in the presence of oxygen in a bioreactor to obtain a sulphur slurry and a regenerated aqueous alkaline washing liquid.
摘要翻译：本发明提供了一种从原料合成气流生产纯化的合成气流的方法，包括使其与变换反应器中的水煤气变换催化剂接触，以获得富含H 2 S和CO 2的转移的合成气流。通过使其与吸收液体接触，从移动的合成气流中除去H 2 S和CO 2，以获得富含H 2 S和CO 2的半纯化合成气体和吸收液体。将富含H 2 S和CO 2的至少一部分吸收液体加热以获得富含H 2 S和CO 2的加热吸收液体，然后在闪蒸容器中对富含H 2 S和CO 2的加热的吸收液体进行减压，从而获得富含 CO2和吸收富H2S的液体。富含H 2 S的吸收液体在高温下与汽提气体接触，从而将H 2 S转移到汽提气体中，得到再生的吸收液体和富含H 2 S的汽提气体。富含H 2 S的汽提气中的H 2 S被转化为元素硫，并且通过使H2S去除区中的气流与碱性洗涤液接触，从而将半纯化合成气中的H 2 S从其中除去，从而获得H2S-贫化合成气流和含硫化物的水流。含硫化物的水流在生物反应器中在氧的存在下与硫化物氧化细菌接触以获得硫浆料和再生的碱性碱性洗涤液。

6. 发明授权

US06755980B1 Process to remove solid slag particles from a mixture of solid slag particles and water 有权
标题翻译：从固体渣粒和水的混合物中除去固体渣粒的方法
公开(公告)号：US06755980B1
公开(公告)日：2004-06-29
申请号：US10089028
申请日：2002-03-26
申请人： Isaac Cornelis Van Den Born , Johannes Gerardus Maria Schilder
发明人： Isaac Cornelis Van Den Born , Johannes Gerardus Maria Schilder
IPC分类号： B01D3700
CPC分类号： C10J3/52 , C10J3/00 , C10J2300/1696
摘要： Process to remove solid slag particles from a mixture of solid slag particles and water present in a quench zone, which quench zone is part of a process for the preparation of synthesis gas by partial combustion of finely dispersed solid carbon-containing fuel with an oxygen-containing gas, by a) discharging of the mixture from the quench zone to a first vessel, (b) discharging slag particles from the first vessel to a second vessel and discharging water poor in solid slag from a second vessel, which second vessel is located below and fluidly connected to said first vessel by means of an open connecting conduit provided with pumping means and is further provided with closed means to discharge slag from its lower end, (c) fluidly closing the first vessel from the second vessel, (d) opening of the means to discharge slag from the second vessel to remove slag from the second vessel to a lower pressure zone, and (e) closing the means to discharge slag from the second vessel and repeating steps (a) to (e).
摘要翻译：从固体渣颗粒和存在于骤冷区中的水的混合物中除去固体渣颗粒的方法，该骤冷区是用于通过部分燃烧细分散的固体含碳燃料与氧气的部分方法来制备合成气的方法的一部分，（a）将混合物从骤冷区排出到第一容器，（b）将渣粒从第一容器排放到第二容器中，并从第二容器所位于的第二容器中排出固体渣中的不良物质（c）从第二容器流体地封闭第一容器，（d）将第一容器从第二容器流体封闭，打开从第二容器排出炉渣以将渣从第二容器排出到较低压力区的装置，以及（e）关闭从第二容器排出炉渣的装置并重复脚趾（a）至（e）。

7. 发明申请

US20120096770A1 PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM 审中-公开
标题翻译：生产纯化合成气流的方法
公开(公告)号：US20120096770A1
公开(公告)日：2012-04-26
申请号：US13260754
申请日：2010-03-30
申请人： Isaac Cornelis Van Den Born , Gijsbert Jan Van Heeringen , Cornelis Jacobus Smit , Alex Frederik Woldhuis
发明人： Isaac Cornelis Van Den Born , Gijsbert Jan Van Heeringen , Cornelis Jacobus Smit , Alex Frederik Woldhuis
IPC分类号： C10J3/46
CPC分类号： C01B3/58 , B01D53/002 , B01D53/1425 , B01D53/1462 , B01D53/22 , B01D53/77 , B01D53/84 , B01D53/869 , B01D2251/304 , B01D2251/306 , B01D2251/604 , B01D2251/606 , B01D2251/80 , B01D2251/95 , B01D2257/304 , B01D2257/308 , B01D2257/408 , B01D2257/504 , C01B3/16 , C01B3/501 , C01B3/506 , C01B3/52 , C01B2203/0415 , C01B2203/0435 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , Y02A50/2358 , Y02C10/02 , Y02C10/06 , Y02C10/10 , Y02E20/18 , Y02P20/13 , Y02P20/152
摘要： A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide,HCN and/or COS, the process comprising the steps of: (a) removing HCN and/or COS by contacting the feed synthesis gas stream with a water gas shift catalyst in a shift reactor in the presence of steam/water to react at least part of the carbon monoxide to carbon dioxide, and to obtain a synthesis gas stream depleted in HCN and/or in COS; (b) removing hydrogen sulphide in the synthesis gas stream depleted in HCN and/or in COS by contacting this gas stream in a H2S-removal zone with an aqueous alkaline washing liquid to obtain a H2S-depleted synthesis gas stream and a sulphide-comprising aqueous stream; (c) contacting the sulphide-comprising aqueous stream with ulphide-oxidizing bacteria in the presence of oxygen in a bioreactor to obtain a sulphur slurry and a regenerated aqueous alkaline washing liquid; (d) removing carbon dioxide from the H2S-depleted synthesis gas stream, to obtain the purified synthesis gas stream and a gas stream enriched in CO2.
摘要翻译：一种从原料合成气流生产纯化合成气流的方法，除了主要成分一氧化碳和氢气外，还包括硫化氢，HCN和/或COS，该方法包括以下步骤：（a）除去HCN和/或COS 通过在蒸汽/水的存在下在转移反应器中使进料合成气流与水煤气变换催化剂接触，使至少一部分一氧化碳与二氧化碳反应，并获得消耗在HCN和/或在COS中（b）通过将H2S去除区中的该气流与碱性洗涤液的水溶液接触，除去在HCN和/或COS中的合成气流中的硫化氢，从而获得含H2S的合成气流和含硫化物水流; （c）在氧气存在下在生物反应器中使含硫化物的水流与硫化氢 - 氧化细菌接触，以获得硫浆料和再生碱性水洗碱液; （d）从除去H2S的合成气流中除去二氧化碳，以获得纯化的合成气流和富含CO 2的气流。

8. 发明授权

US07540891B2 System and method for stripping toxigas from a powder 有权
标题翻译：从粉末中分离毒素的系统和方法
公开(公告)号：US07540891B2
公开(公告)日：2009-06-02
申请号：US10577478
申请日：2004-10-29
申请人： Isaac Cornelis Van Den Born , Johannes Gerardus Maria Schilder
发明人： Isaac Cornelis Van Den Born , Johannes Gerardus Maria Schilder
IPC分类号： C10H1/00
CPC分类号： C10J3/84 , C10J3/466 , C10J3/526 , C10J3/54 , C10J3/56 , C10J2200/09
摘要： A system and method for removal of a toxic gas from a powder contaminated with the toxic gas. The system comprises: a source of the contaminated powder; a stripper assembly for stripping at least part of the toxic gas from a batch load of the contaminated powder; connecting means for fluidly connecting the source with the stripper assembly for transporting the contaminated powder from the source to the stripper assembly. The stripper assembly may comprise two or more stripper vessels, and the connecting means is arranged to selectively connect the source to one or more of the stripper vessels. Gravity-driven transport of the contaminated powder from the source of the contaminated powder to the stripper assembly may be established. The source may comprise a gasifier and a depressurising chamber.
摘要翻译：从有毒气体污染的粉末中除去有毒气体的系统和方法。该系统包括：污染粉末源; 汽提器组件，用于从受污染粉末的批量负载中汽提至少一部分有毒气体; 用于将源与剥离器组件流体连接的连接装置，用于将污染的粉末从源输送到汽提器组件。汽提器组件可以包括两个或更多个汽提器容器，并且连接装置被布置成选择性地将源连接到一个或多个剥离器容器。污染粉末从污染粉末源的重力驱动运输可以建立到汽提器组件。源可以包括气化器和减压室。

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