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1. 发明申请

US20110207593A1 Expansivity in Low Expansion Silica-Titania Glasses 审中-公开
标题翻译：低膨胀二氧化硅 - 二氧化钛玻璃的膨胀性
公开(公告)号：US20110207593A1
公开(公告)日：2011-08-25
申请号：US13028516
申请日：2011-02-16
申请人： Carlos Duran , Kenneth Edward Hrdina , John Edward Maxon
发明人： Carlos Duran , Kenneth Edward Hrdina , John Edward Maxon
IPC分类号： C03C3/06 , C03C3/076 , C03B19/06 , C03B25/00
CPC分类号： C03B19/1407 , C03B19/1453 , C03B2201/23 , C03B2201/42 , C03C3/06 , C03C3/076 , C03C2201/20
摘要： This disclosure is directed to tailoring and improving the expansivity of low thermal expansion silica-titania glass through changes in the [OH] content and fictive temperature of the glasses. The [OH] concentration in the glass can be in the range of 600-2500 ppm. The fictive temperature, TF is less than 900° C.
摘要翻译：本发明旨在通过玻璃的[OH]含量和假想温度的变化来定制和改善低热膨胀二氧化硅 - 二氧化钛玻璃的膨胀性。玻璃中的[OH]浓度可以在600-2500ppm的范围内。假想温度，TF低于900℃

2. 发明授权

US08596094B2 Synthetic silica glass with uniform fictive temperature 有权
标题翻译：具有均匀假想温度的合成石英玻璃
公开(公告)号：US08596094B2
公开(公告)日：2013-12-03
申请号：US12902238
申请日：2010-10-12
申请人： Carlos Duran , Kenneth Edward Hrdina , Ulrich Wilhelm Heinz Neukirch
发明人： Carlos Duran , Kenneth Edward Hrdina , Ulrich Wilhelm Heinz Neukirch
IPC分类号： C03B13/00 , C03B15/00 , C03B19/00 , C03B25/00 , C03C3/06
CPC分类号： C03B25/02 , C03B19/1453 , C03B2201/07 , C03B2201/075 , C03B2201/22 , C03B2201/23
摘要： A method of making a silica glass having a uniform fictive temperature. The glass article is heated at a target fictive temperature, or heated or cooled at a rate that is less than the rate of change of the fictive temperature, for a time that is sufficient to allow the fictive temperature of the glass to come within 3° C. of the target fictive temperature. The silica glass is then cooled from the target fictive temperature to a temperature below the strain point of the glass at a cooling rate that is greater than the relaxation rate of the glass at the target fictive temperature. The silica glass has a fictive temperature that varies by less than 3° C. after the annealing step. A silica glass made by the method is also described.
摘要翻译：制造具有均匀的假想温度的二氧化硅玻璃的方法。将玻璃制品在目标假想温度下加热，或以低于假想温度变化率的速率加热或冷却一段足以使玻璃的假想温度达到3°的时间 C.目标虚构温度。然后将二氧化硅玻璃从目标假想温度冷却至低于玻璃应变点的温度，其冷却速率大于目标假想温度下玻璃的松弛率。二氧化硅玻璃具有在退火步骤之后变化小于3℃的假想温度。还描述了通过该方法制备的二氧化硅玻璃。

3. 发明申请

US20110048075A1 TUNING Tzc BY THE ANNEALING OF ULTRA LOW EXPANSION GLASS 有权
标题翻译：通过超低膨胀玻璃的退火调节Tzc
公开(公告)号：US20110048075A1
公开(公告)日：2011-03-03
申请号：US12868934
申请日：2010-08-26
申请人： Carlos Duran , Kenneth Edward Hrdina
发明人： Carlos Duran , Kenneth Edward Hrdina
IPC分类号： C03B25/00 , C03C3/06
CPC分类号： C04B35/14 , C03B25/025 , C03B25/08 , C03C3/06 , C03C3/076 , Y02P40/57
摘要： The disclosure describes a method by which the Tzc of a silica-titania glass article, for example, a EUVL mirror substrate, can be tuned to within a specification range by means of a selected final anneal that shifts Tzc of the article or substrate to the desired Tzc value. In addition, since different mirrors in a set can be specified at different values of Tzc, this process can be on used glass samples or pieces from a single glass boule to make parts with different Tzc values, thus reducing the number of separate boules required to fill an order.
摘要翻译：本公开内容描述了一种通过选择的最终退火将二氧化硅 - 二氧化钛玻璃制品的Tzc（例如EUVL反射镜基板）调谐到规定范围内的方法，该最终退火将制品或基材的Tzc移动到期望的Tzc值。另外，由于可以在不同的Tzc值中指定一组中的不同反射镜，所以该过程可以是来自单个玻璃棒的玻璃样品或碎片以制备具有不同Tzc值的部件，从而减少了需要的单独的毛坯的数量填写订单。

4. 发明申请

US20110207592A1 Low Expansivity, High Transmission Titania Doped Silica Glass 有权
标题翻译：低膨胀率，高透射率二氧化钛掺杂二氧化硅玻璃
公开(公告)号：US20110207592A1
公开(公告)日：2011-08-25
申请号：US13028472
申请日：2011-02-16
申请人： Carlos Duran , Kenneth Edward Hrdina , Michael A. Mueller
发明人： Carlos Duran , Kenneth Edward Hrdina , Michael A. Mueller
IPC分类号： C03C3/06
CPC分类号： C03C3/06 , B82Y10/00 , B82Y40/00 , C03B19/1407 , C03B19/1415 , C03B19/1453 , C03B2201/21 , C03B2201/23 , C03B2201/42 , C03C4/0071 , C03C4/0085 , C03C2201/21 , C03C2201/23 , C03C2201/42 , C03C2203/40 , C03C2203/52 , G03F1/60 , G03F7/0002 , G03F7/70958
摘要： In one embodiment the present disclosure is directed to a silica-titania glass with an internal transmission of >90%/cm at wavelengths from 340 nm to 840 nm. In another embodiment the internal transmission is >93%/cm at wavelengths from 340 nm to 840 nm. In a further embodiment the internal transmission is >95%/cm at wavelengths from 340 nm to 840 nm. In another embodiment the disclosure is directed to a silica-titania glass with an overall transmission through an optic made of the glass is >84% at wavelengths from 340 nm to 840 nm. In another embodiment overall transmission through an optic made of the glass is >86% at wavelengths from 340 nm to 840 nm. In a further embodiment the overall transmission through an optic made of the glass is >88% at wavelengths from 330 nm to 840 nm. In a further embodiment the silica-titania glass has a Ti+3 concentration level [Ti3+] less than 3 ppm by weight.
摘要翻译：在一个实施方案中，本公开涉及在340nm至840nm的波长下具有> 90％/ cm 3的内透射率的二氧化硅 - 二氧化钛玻璃。在另一个实施例中，在340nm至840nm的波长下，内透射率> 93％/ cm。在另一个实施方案中，在340nm至840nm的波长下，内透射率> 95％/ cm。在另一个实施方案中，本公开涉及一种二氧化硅 - 二氧化钛玻璃，其透射率通过玻璃制成的光学器件在340nm至840nm的波长处为> 84％。在另一个实施例中，通过由玻璃制成的光学器件的整个透射在340nm至840nm的波长处为> 86％。在另一实施例中，通过由玻璃制成的光学器件的整体透射在330nm至840nm的波长处为> 88％。在另一个实施方案中，二氧化硅 - 二氧化钛玻璃具有小于3ppm重量的Ti + 3浓度水平[Ti 3+]。

5. 发明授权

US08263511B2 High purity fused silica with low absolute refractive index 有权
$High purity fused silica with low absolute refractive index$
标题翻译：具有低绝对折射率的高纯度熔融石英
公开(公告)号：US08263511B2
公开(公告)日：2012-09-11
申请号：US12644563
申请日：2009-12-22
申请人： Carlos Duran , Richard Michael Fiacco , Kenneth Edward Hrdina , Daniel Raymond Sempolinski
发明人： Carlos Duran , Richard Michael Fiacco , Kenneth Edward Hrdina , Daniel Raymond Sempolinski
IPC分类号： C03C3/06 , C03B25/00
CPC分类号： C03B25/02 , C03B19/1453 , C03B2201/03 , C03B2201/04 , C03C3/06 , C03C2201/22 , C03C2201/23
摘要： A fused silica glass article having a low absolute refractive index and low concentrations of hydroxyl groups, halogens, and metal having a low absolute refractive index. The glass article contains less than about 10 ppm protium-containing and deuterium-containing hydroxyl groups by weight and less than about 20 ppm halogens by weight. The silica glass article also has an absolute refractive index (ARI) less than or equal to 1.560820. In one embodiment, the ARI of the fused silica article is achieved by lowering the fictive temperature of the fused silica. A method of lowering the fictive temperature is also described.
摘要翻译：具有低绝对折射率和低浓度羟基，卤素和具有低绝对折射率的金属的熔融石英玻璃制品。玻璃制品含有重量少于约10ppm含氘羟基和重量小于约20ppm的卤素。石英玻璃制品的绝对折射率（ARI）也小于或等于1.560820。在一个实施方案中，熔融二氧化硅制品的ARI通过降低熔融二氧化硅的假想温度来实现。还描述了降低虚构温度的方法。

6. 发明申请

US20110092354A1 SYNTHETIC SILICA GLASS WITH UNIFORM FICTIVE TEMPERATURE 有权
标题翻译：合成二氧化硅玻璃具有均匀的温度
公开(公告)号：US20110092354A1
公开(公告)日：2011-04-21
申请号：US12902238
申请日：2010-10-12
申请人： Carlos Duran , Kenneth Edward Hrdina , Ulrich Wilhelm Heinz Neukirch
发明人： Carlos Duran , Kenneth Edward Hrdina , Ulrich Wilhelm Heinz Neukirch
IPC分类号： C03C3/04 , C03B25/00
CPC分类号： C03B25/02 , C03B19/1453 , C03B2201/07 , C03B2201/075 , C03B2201/22 , C03B2201/23
摘要： A method of making a silica glass having a uniform fictive temperature. The glass article is heated at a target fictive temperature, or heated or cooled at a rate that is less than the rate of change of the fictive temperature, for a time that is sufficient to allow the fictive temperature of the glass to come within 3° C. of the target fictive temperature. The silica glass is then cooled from the target fictive temperature to a temperature below the strain point of the glass at a cooling rate that is greater than the relaxation rate of the glass at the target fictive temperature. The silica glass has a fictive temperature that varies by less than 3° C. after the annealing step. A silica glass made by the method is also described.
摘要翻译：制造具有均匀的假想温度的二氧化硅玻璃的方法。将玻璃制品在目标假想温度下加热，或以低于假想温度变化率的速率加热或冷却一段足以使玻璃的假想温度达到3°的时间 C.目标虚构温度。然后将二氧化硅玻璃从目标假想温度冷却至低于玻璃应变点的温度，其冷却速率大于目标假想温度下玻璃的松弛率。二氧化硅玻璃具有在退火步骤之后变化小于3℃的假想温度。还描述了通过该方法制备的二氧化硅玻璃。

7. 发明授权

US08541325B2 Low expansivity, high transmission titania doped silica glass 有权
标题翻译：低膨胀性，高透射二氧化钛掺杂石英玻璃
公开(公告)号：US08541325B2
公开(公告)日：2013-09-24
申请号：US13028472
申请日：2011-02-16
申请人： Carlos Duran , Kenneth Edward Hrdina , Michael A Mueller
发明人： Carlos Duran , Kenneth Edward Hrdina , Michael A Mueller
IPC分类号： C03C3/06
CPC分类号： C03C3/06 , B82Y10/00 , B82Y40/00 , C03B19/1407 , C03B19/1415 , C03B19/1453 , C03B2201/21 , C03B2201/23 , C03B2201/42 , C03C4/0071 , C03C4/0085 , C03C2201/21 , C03C2201/23 , C03C2201/42 , C03C2203/40 , C03C2203/52 , G03F1/60 , G03F7/0002 , G03F7/70958
摘要： In one embodiment the present disclosure is directed to a silica-titania glass with an internal transmission of >90%/cm at wavelengths from 340 nm to 840 nm. In another embodiment the internal transmission is >93%/cm at wavelengths from 340 nm to 840 nm. In a further embodiment the internal transmission is >95%/cm at wavelengths from 340 nm to 840 nm. In another embodiment the disclosure is directed to a silica-titania glass with an overall transmission through an optic made of the glass is >84% at wavelengths from 340 nm to 840 nm. In another embodiment overall transmission through an optic made of the glass is >86% at wavelengths from 340 nm to 840 nm. In a further embodiment the overall transmission through an optic made of the glass is >88% at wavelengths from 330 nm to 840 nm. In a further embodiment the silica-titania glass has a Ti+3 concentration level [Ti3+] less than 3 ppm by weight.
摘要翻译：在一个实施方案中，本公开涉及在340nm至840nm的波长下具有> 90％/ cm 3的内透射率的二氧化硅 - 二氧化钛玻璃。在另一个实施例中，在340nm至840nm的波长下，内透射率> 93％/ cm。在另一个实施方案中，在340nm至840nm的波长下，内透射率> 95％/ cm。在另一个实施方案中，本发明涉及一种二氧化硅 - 二氧化钛玻璃，其透射率通过玻璃制成的光学透镜在340nm至840nm的波长处> 84％。在另一个实施例中，通过由玻璃制成的光学器件的整个透射在340nm至840nm的波长处为> 86％。在另一实施例中，通过由玻璃制成的光学器件的整体透射在330nm至840nm的波长处为> 88％。在另一个实施方案中，二氧化硅 - 二氧化钛玻璃具有小于3ppm重量的Ti + 3浓度水平[Ti 3+]。

8. 发明授权

US08713969B2 Tuning Tzc by the annealing of ultra low expansion glass 有权
标题翻译：通过超低膨胀玻璃的退火调整Tzc
公开(公告)号：US08713969B2
公开(公告)日：2014-05-06
申请号：US12868934
申请日：2010-08-26
申请人： Carlos Duran , Kenneth Edward Hrdina
发明人： Carlos Duran , Kenneth Edward Hrdina
IPC分类号： C03B25/00
CPC分类号： C04B35/14 , C03B25/025 , C03B25/08 , C03C3/06 , C03C3/076 , Y02P40/57
摘要： The disclosure describes a method by which the Tzc of a silica-titania glass article, for example, a EUVL mirror substrate, can be tuned to within a specification range by means of a selected final anneal that shifts Tzc of the article or substrate to the desired Tzc value. In addition, since different mirrors in a set can be specified at different values of Tzc, this process can be on used glass samples or pieces from a single glass boule to make parts with different Tzc values, thus reducing the number of separate boules required to fill an order.
摘要翻译：本公开内容描述了一种通过选择的最终退火将二氧化硅 - 二氧化钛玻璃制品的Tzc（例如EUVL反射镜基板）调谐到规定范围内的方法，该最终退火将制品或基材的Tzc移动到期望的Tzc值。另外，由于可以在不同的Tzc值中指定一组中的不同反射镜，所以该过程可以是来自单个玻璃棒的玻璃样品或碎片以制备具有不同Tzc值的部件，从而减少了需要的单独的毛坯的数量填写订单。

9. 发明申请

US20100162759A1 HIGH PURITY FUSED SILICA WITH LOW ABSOLUTE REFRACTIVE INDEX 有权
标题翻译：具有低绝对折射率的高纯度二氧化硅
公开(公告)号：US20100162759A1
公开(公告)日：2010-07-01
申请号：US12644563
申请日：2009-12-22
申请人： Carlos Duran , Richard Michael Fiacco , Kenneth Edward Hrdina , Daniel Raymond Sempolinski
发明人： Carlos Duran , Richard Michael Fiacco , Kenneth Edward Hrdina , Daniel Raymond Sempolinski
IPC分类号： C03B27/012 , C03C3/04
CPC分类号： C03B25/02 , C03B19/1453 , C03B2201/03 , C03B2201/04 , C03C3/06 , C03C2201/22 , C03C2201/23
摘要： A fused silica glass article having a low absolute refractive index and low concentrations of hydroxyl groups, halogens, and metal having a low absolute refractive index. The glass article contains less than about 10 ppm protium-containing and deuterium-containing hydroxyl groups by weight and less than about 20 ppm halogens by weight. The silica glass article also has an absolute refractive index (ARI) less than or equal to 1.560820. In one embodiment, the ARI of the fused silica article is achieved by lowering the fictive temperature of the fused silica. A method of lowering the fictive temperature is also described.
摘要翻译：具有低绝对折射率和低浓度羟基，卤素和具有低绝对折射率的金属的熔融石英玻璃制品。玻璃制品含有重量少于约10ppm含氘羟基和重量小于约20ppm的卤素。石英玻璃制品的绝对折射率（ARI）也小于或等于1.560820。在一个实施方案中，熔融二氧化硅制品的ARI通过降低熔融二氧化硅的假想温度来实现。还描述了降低虚构温度的方法。

10. 发明授权

US07806920B2 Sigmoid valve and method for its percutaneous implantation 失效
标题翻译：乙状血管及其经皮植入法
公开(公告)号：US07806920B2
公开(公告)日：2010-10-05
申请号：US11524836
申请日：2006-09-21
申请人： Carlos Duran
发明人： Carlos Duran
IPC分类号： A61F2/06
CPC分类号： A61F2/2475 , A61F2/2412 , A61F2/2415 , A61F2/2418 , A61F2/2433 , A61F2/2436 , A61F2220/0075
摘要： A multi-leaflet valve adapted to serve as a prosthesis for diseased native valve of a mammal is incorporated in self-expandable or inflatable endovascular stents or stents to form a combination which is introduced on a catheter with a guide wire into the circulatory system of the mammal to replace the diseased native valve. Once the combination is at the desired location the stent is caused to expand and affix itself to the patient's vessel wall. The prosthetic valve has the shape of a truncated cone that has an inflow and an outflow orifice with leaflets forming the outflow orifice and forming a plurality of commissures. A first flexible circular support is affixed in a substantially circular fashion around the truncated cone in proximity of the inflow orifice, and a second flexible circular support is affixed at the location of the commissures to form a circle around the truncated cone in proximity of the outflow orifice. The circular supports maintain the shape of the valve during the surgical implantation procedure and thereafter.
摘要翻译：适合用作哺乳动物患病自然瓣膜的假体的多瓣叶瓣被并入自膨胀或可充气的血管内支架或支架中，以形成一种组合，该组合被引导到具有导丝的导管上进入循环系统哺乳动物代替患病的天然瓣膜。一旦组合在期望的位置，支架被扩张并将其固定在患者的血管壁上。假体瓣膜具有截锥形的形状，其具有形成流出孔并形成多个连合的流入口和流出孔。第一柔性圆形支撑件以围绕流入孔的截头圆锥体的大致圆形方式固定，并且第二柔性圆形支撑件固定在连合处的位置处以在流出物附近形成围绕截锥体的圆孔。圆形支撑件在手术植入程序期间及之后保持阀的形状。

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